Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

INDEX 433—, test for, 2, 11, 30heterogeneous reactions, and very low pressureflow system, 25—, study using molecular beam, 176hexaphenylethane, dissociation of, 309HNO radicals, see nitroxyl radicalhomogeneity of rate coefficients, 377-386,412-414hot atoms, from nuclear recoil processes, 65,61—, in reactions, 283hot radicals, effects of, 3, 5—, production of by CH 8 insertion, 77, 305—, reactions of, 16, 63, 64, 283HSe and HS radicals, study by ESR, 313hydrated electron, see electronhydrates, decomposition of, 247hydrazine, decomposition in fiow system, 26—, photolysis of, 294—, reaction + H, study using o-p H 2 , 317hydrazoic acid, flash photolysis of, 294—, matrix photolysis of, 334—, pyrolysis of, 333, 334hydrocarbons, adsorption on Ir, study by fieldemission, 204—, adsorption on metal films, 197—, determination by gas chromatography, 80,81—, determination by gas titration, 78—, exchange with D a over catalysts, 235—, flames of, diffusion, study by spectroscopy,290—, —, study using separated burner, 281—, glasses of, for radical trapping, 310, 311—, oxidation of, and anti-knock, 120, 121—, —, effect of HBr on, 76—, —, photosensitisation of, 77—, —, study by adiabatic compression, 127hydrogen, adsorption on Ni, conductivity andcontamination, 211—, —, molecular beam study, 175, 176—, adsorption on vessel walls, 11—, as carrier gas, in gas chromatography, 79,82, 83, 85, 234—, —, in mirror detection of radicals, 314—, as driver gas in shock tube, 124, 127—, chemisorption on metals and oxides, 190—, determination of, by absorption* 71—. —. by gas chromatography, 80, 237—, —, in ultra high vacuum work, ,197—» diffusion flame of, spectroscopy and, 290—, diffusion through vessel walls, 10, 11—, efficiency in energy transfer, 17 . •, -—, exchange with D t over catalysts, 235, "241—» from CH,CHO decomposition, 3—, from CtU 9 photolysis, 63—, ortho-para conversion, and catalytic studies,235-237—, and radical detection, 71, 316, 317reaction -f Br„ rate expression for, 396reaction + CI a , differential calorimetryand, 101—, effect of NO on, 76reaction 4- CO, and thermal conductivity,97reaction + D a , radiation induced, 70reaction + O a , effect of inert additives, 17—, effect of S/V ratio, 11—, excited OH from, 286—, explosion limits, 18-20—, flame, determination of electron concentration,329-, —, determination of H in, 171, 172,302—, —, determination of O in, 318—, radon induced, 64—, sensitised, 76—, study by shock tube, 127, 128reaction + OH, ESR study, 313reduction by for cleaning surfaces, 181thermal conductivity of, 82hydrogen arc, for absorption spectroscopy, 292hydrogenation, catalytic in solution, 251hydrogen atoms, addition to C 8 H 6 , 73detection by metallic mirrors, 315determination by calorimetry, 325, 326— gas titration, 78, 320, 321— mass spectrometry, 300— optical pumping, 96— optical spectroscopy, 290— pressure measurement, 324— thermal conductivity, 325determination in flames, 171, 172, 302,317-319determination using D g » D a O and p-H%,317— MoOa, 315— uv spectroscopy, 89, 90dimerisation, 91, 319from C 3 H 8 radiolysis, 70from reactions of hydrated electron, 123hot, reaction + HI, 283reaction + Cl„ 55, 90, 288reaction + glass, 11reaction + HC1, 90reaction -j- N 8 H 4 and olefins, and o-p H»»317reaction + NO, 2, 78, 321reaction + NO a , 78, 292, 320reaction + O s , 282reaction + OH+Na, 319