Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

INDEX 431filament, in flash desorption, 191, 194, 196in mass spectrometer, 243, 244—, problems with, 239, 240—, pyrolysis on, 297in photoemission, 202in semiconduction determination, 214, 215in space charge limited diode, 204in static condenser method for contactpotential, 205film area, and reaction at liquid surfaces, 264film balance, 265-268film pressure, and reaction at liquid surfaces,264—, determination of, 264-267films, evaporated, as anode in photoemission,202—, —, as anode in space charge limited diode,204, 205—, —, determination of conductivity of, 211—215—» —, in condenser method for contact potentials,205-207—, —, preparation of, 182-184filters, for radiation, 57, 58flame ionisation detector, in gas chromatography,83, 84flames, cool, of aldehydes, emission from, 286—, —, —, products of, 281—, —, mass spectrometry study of, 281, 305—, diffusion, 116—, —, absorption spectroscopy of, 290—, excited species in, 282, 286-289—, intermediates in, determination by absorptionspectroscopy, 290, 302, 303—, —, determination using additives, 317-319—, ions and electrons in, determination of,328-331—, ions in, 284, 307, 308—, premixed, 117—, separated burner for, 281—, study by ESR, 313—, use for study of fast reactions, 116, 167-172flash desorption, 195, 196flash filament technique, 189, 191-197flash lamp, heating for T-jump, 135flash photolysis, 5, 88, 113, 118-121, 285, 286,292—, and ESR, 314—, and pulsed illumination, 51—, and study of excited species, 293, 294—, and time-of-flight mass spectrometer, 305—, periodic, 121—, using laser, 55float, for Langmuir trough, 266, 267flow control and measurement, 29flow rate, and size of combustion zone, 168flow systems, 23-30—, and catalysis, 231-233—, atom concentration measurement in, 324-326—, comparison with static systems, 30—, for ESR studies, 91, 313—, for fast reactions, 116—, —, in gas, 166, 167—, —, in solution, 162-166—, for flash filament technique, 192—, for isothermal calorimetry, 98—, for mirror detection of radicals, 314—, for wo-WO exchange, 237, 238—, for o~p H 2 conversion on catalyst, 236fluidised bed reactor, for catalysis, 233fluorescence, and concentration of excited molecules,115, 290—, of aminopyrenes, 156fluorescence quenching, 152-157fluorescence transformation, 154, 155fluorine, as radical trap, 74, 75—, efficiency in energy transfer, 17—, radioactive, production of, 67—, reaction + CH a , 74—, use in gas titration, 78fluorine atoms, reaction + hydrocarbons, 75—, study by ESR, 313fluorine azide, matrix photolysis of, 335fluorine oxide, decomposition of, energy transferin, 17fluorobenzene, as sensitiser, 77fluorocarbons, determination by gas chromatography,81forcing function, in relaxation method, 137formaldehyde, determination of, colorimetrically,71—, —, mass spectrometrically, 281, 302—, emission from in cool flames, 286—, from flames, 281formic acid, determination by IR spectroscopy,90formyl radicals, decomposition of, 15—, trapped, preparation of, 332Fowler-Nordheim equation, 203fractional life method for determination ofreaction order, 353-356, 359fraction of reaction, and determination of reactionorder, 351-353, 358, 408, 420, 421—, and fractional life, 354, 355, 359—, and isoprene polymerisation, 411, 412—, and weighting, 371free radicals, see radicals