Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

INDEX 441329explosion limits, 18-20flame, determination of electrons in,—, —, determination ol H in, 302—, radon induced, 64—, sensitisation of, 76'reaction -f N, 167reaction + radicals, rotating cryostatstudy, 336singlet, reaction + olefins, 322, 323sticking coefficient of and surface contamination,187oxygen-17, NMR line broadening and solvent exchange,149oxygen-18, exchange with 16 0 at catalyst surfaces,237, 238oxygen atoms, determination by calorimetry,326— by effusion gauge, 328— by gas titration, 78, 320, 321— by mass spectroscopy, 300, 305— by pressure measurement, 318— by uv spectroscopy, 89, 90— of in flames, 302, 318diffusion into metals, 245ESR study of, 313excited, from flash photolysis of O a , 322production of known concentrations of,322reaction + Br, and Cl 2 , 313reaction + C 8 H 2 , C a D 2 and C,D 4 , ionsfrom, 307reaction + H a O, 322reaction + NO and NO a , 91, 289, 320reaction -f N 2 0, 318reaction + O t and O s , mass spectroscopicstudy, 283, 303reaction -f SO,, 91removal by Hg mirror, 326Zeeman energy levels of, 312oxygen pressure, effect on le O- 18 0 exchangerate on catalyst, 237, 238ozone, as actinometer, 61—, determination by IR spectroscopy, 90—, flash photolysis of, 293, 322—, reaction + H, 282, 303—, reaction + N,*, O, O a *. OH*, 283, 303,305, 323—, reaction + NO, 289palladium, chemisorption on, 190—, cleaning surface of, 181—, preparation of film of, 183parallel reactions, 398, 399particle accelerators, 64, 65, 121Paschen-Back effect, in gas phase ESR, 312peak area and height, in gas chromatography,88Peclot number, and mass transfer in solution,252pellet, for determination of effective diffusivity,226, 227pellet size, and mass transfer to catalyst, 223neo-pentane, bromination of, steady state in, 4perfluoroethane, as energy transfer agent, 70periodic flash photolysis, see flash photolysisperoxides, determination by gas chromatography,323—, determination by polarography, 96—, determination in combustion systems, 280,281—, from singlet 0 8 + olefins, 323peroxy radicals, chain termination by, 11—, reaction + HBr, 76perturbation methods for fast reactions, 113phase shift, to determine lifetime of fluorescentstate, 152, 153phase transformations, detection of, 256, 260phenol, as radical trap, 74phenyl a-naphthylamine, effect on reactionof octadecene + O s , 310phenyl radicals, reaction -f C^ and I a , 316phosphoric acid, coating for vessel in isothermalcalorimetry, 99phosphorus, radioactive, production of, 67photocells, and fluorescence quenching, 152—, as actinometers, 62, 63—, use in flash photolysis, 119, 120, 286—, use in photoelectric emission studies, 201—, use in shock tube studies, 128—, use in T-jump method, 134, 135—, use in ultrasonic absorption studies, 141,142—, use with beam microbalances, 199photochemical reactions, 5—, and Hg lamps, 42—, in matrices, 332photochemical systems, 34-63—, complications in, 5— f furnace for, 9—, reaction vessels for, 27photocurrent, measurement of, 201photoelectric amplifier, for galvanometer, 59,60photoelectric emission, and photocells, 62—, for studying adsorption, 201, 202