Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

INDEX 427—, changes on adsorption, determination of,211-216—, in study of NaCl+F 2 , 249—, to determine ions and electrons in flames,328, 329—, to follow concentration in flow method,162—, J to follow concentration in relaxationstudies, 133—, to follow mirror removal by radicals, 314—, to follow Si0 2 +HF reaction, 253confidence limits, for rate coefficients, 377,382, 385—, —, of isoprene polymerisation, 413, 415,418consecutive reactions, 399conservation relations, for passage of shockwave, 125contact angle, and determination of film pressure,265contact potential, and adsorption studies, 205-207contact resistance, and conductivity measurements,212contamination, and ambient pressure, 187—, and conductivity of films, 211—, and Langmuir trough method, 207cool flames, see flamescopper, chemisorption on, 190—, cleaning surface of, 185—, preparation of films of, 183—, reaction 4- S, 254copper-beryllium alloy spring, for microbalance,198copper float, for Langmuir trough, 266copper ions, H 2 0 exchange by NMR, 149copper oxide, adsorbed C a H 4 , extinction coefficientof, 217copper reaction vessel, for gaseous titrations,78copper salts, use in determination of H andOH in flames, 319counters, for radiation determination, 238,239,254coupling, of moments in gaseous ESR studies,312cross-sections, of scattering in molecularbeams, 175cryostat, rotating, for studying trapped radicals,335, 336crystal defects, study by ESR, 310 -cumulative chemisorption, on semiconductors,214cuprous oxide, chemisorption on, 190Curie point, and solid state reactions, 261Curie-Weiss law, 208current-voltage curves in polarography, 159,160cut-offs, Hg, 6, 7cyanogen, flames of, determination of electronsin, 330—, flash photolysis of, 293cyanogen azide, matrix photolysis of, 335cyanogen bromide, flash photolysis of, 293cyanogen iodide, flash photolysis of, 293cyclobutane, decomposition of, energy transferin, 17cyclohexane, radiolysis of, 70cycloidal mass spectrometer, 244cyclone reaction vessel, 28cyclopentane, as radical trap, 74cyclopropane, determination by gas chromatography,80—, isomerisation of, energy transfer in, 17cyclopropanone, hot from CH 8 +CH s CO, 305cyclotron resonance method, to determineelectrons and ions, 329, 330cylindrical reaction vessels, 2, 11—, and diffusion, 22Ddead space, in static systems, 12, 30Debye-Sears effect, and fluorescence quenching,153—, and ultrasonic absorption, 141decomposition flames, 16Sdefects in solids, study by ESR, 310degassing of vacuum systems, 10degrees of freedom, and results for isoprenepolymerisation, 413, 415, 417, 418—, and standard error, 376, 377, 382, 385density, and thermal gradients in vessels, 11,12—, gas balance, see gas density balancedepletive chemisorption, on semiconductors,214desorption, flash, see flash desorptiondesorption spectrometer, 196, 197detectors, for gas chromatography, 82-85—, for molecular beam studies, 172, 173deuterium, adsorption on Ni, molecular beamstudy, 176—, arc using, for absorption spectroscopy, 292—, catalytic exchange, study using omegatron,241—, determination by gas chromatography, 237—, determination of H by, 317—, efficiency in energy transfer, 17—, exchange with H 8 , radiation induced, 70—, use of in catalytic reactions, 235