Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

INDEX 435—, matrix of for trapped radicals, 332inert packing, in catalytic reactor, 233inert particles, for flamevelocity measurement,171inert support, for catalysts, 221infrared emission, from vibrationaliy excitedspecies, 287infrared spectroscopy, absorption, 216-219—, and analysis, 89, 90inhibitors, study of effect of, apparatus for,14, 15—, quenching reactions by, 281initial concentration ratio, and determinationof reaction orders, 351-353, 358-360—, and integrated rate expressions, 386, 387initiation, in CH 3 CHO decomposition, 3—, in H 2 -hCl 2 +O a reaction, 101—, surface, of chain reactions, 11integral reactors, for catalytic flow system, 231integrated rate expressions, 361, 387intensity of products, and angle from crossedmolecular beams, 174intensity of radiation, determination of, 55—, of Hg lamps, 41, 44-47, 49, 52, 53—, of pulsed illumination, 51interference filters, for radiation, 58interferometry, 102, 103—, and solid state reactions, 261intermediates, and relaxation times, 131, 132—, determination of by mass spectroscopy,294-308—, — by optical spectroscopy, 284-294—, types of in reactions, 280-284intermittent radiation, 48-51interstitial atoms in solids, ESR study, 310iodide ions, exchange with surface monolayer,270iodine, as radical trap, 74, 316—, as scavenger in radiolysis, 70—, determination of by spectroscopy, 89—, dissolution of metals by, 253—, reaction + CH 8 , 74—, reaction + CH 4 , 89iodine atoms, reaction + silica, 11—, study by ESR, 313iodostearic acid, surface monolayer, exchangewith I-, 270ion bombardment, to clean surfaces, 182, 184,185, 199, 216—, to produce films, 183 *ion gauge, for pressure measurement, 186,194,197, 203—, for topatron, 242ionic strength, effect on rate coefficient, 406,407ionisation chamber, for determination of £-rad'mtion, 238—, in dosimetry, 68, 69—, of mass spectrometer, radical removal atwalls, 297ionisation cross-section, and concentrations bymass spectrometer, 299ionisation detector, in molecular beam studies,173ionisation in flames, 284ionisation potentials, and ions in flames, 284—, and molecular beam detectors, 173—, and radical determination mass spectrometrically,296, 297ionising electrode method, for surface potentials,268ion-molecule reactions, 284, 306—, and radical determination mass spectrometrically,297—, mass spectrometer for, 95ion-pair formation, study by ultrasonic absorption,142, 149ion-pair yield, in radiolysis, 67ions, as intermediates, 283, 284—, determination by mass spectroscopy, 306-308—, in aqueous solution, reactions of, 113—, in gas, determination of, 328-331—, in radiolysis, 6, 63, 64—, positive, production of, 65—, reaction -f hydrated electron, 122, 123ion-source, in mass spectrometer, 93, 94iridium, filament of in ion gauge, 197—, hydrocarbon adsorption on, 204—, preparation of films of, 183iridium oxide, chemical transport of, 248iron, carbon precipitation in, 255, 260, 263—, chemisorption on, 190—, cleaning surface of, 181, 184, 185—, dissolution in aq. HC1, 253—, preparation of film of, 183—, skeletal catalyst, preparation of, 221isolation method, for determining reactionorders, 2isomerisation, cis-trans, catalysed by radicals,72—, of butenes, study using microcatalyticreactor, 234—, of methyl salicylate and fluorescencequenching, 155isoprene, polymerisation of, processing data,: : 409-418isotopes, analysis by mass spectroscopy, 95—, exchange of between gas and solid, 248,249