Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

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+-+-3 APPARATUS 47-0-0- 510/ 20-6O.C- 0.50 0.080 0.160AmDs1Q240Fig. 34. Effect ofcurrent and mean pressure (torr) on output foralow-pressure lamp. Fromref. 11 5.T-I,voltageregulatorFig. 35. Circuits for medium- and high-pressure lamps. Key to (b): T1-10 amp Variac; TZ-59G37General Electric transformer; L,, L,-7h, 1.5 amp dc; C,, C,, C,-8 pf, 1500 DCWV; X-seleniumrectifiers (Federal Telephone and Radio Corp. 131H24AX1); R,-50000 R, 150 W; R,-500 R,100 W rheostat. (a) From ref. 9; (b) from ref. 127.References pp. 104-111
48 EXPERIMENTAL METHODS FOR SLOW REACTIONSScale inchesI , ,Fig. 36. Point source, high-pressure mercury arc, 200 W. From ref. 9.Other lampsResonance lamps of the alkali metals, zinc and cadmium have been constructed.Laidler13' shows how Hg, Zn and Cd lamps may be put to very good use to placelimits on bond energies and to determine the mechanisms of some photo-sensitisedreactions. However, none of these lamps has been used extensively and havelimited (or no) photochemical use.Intermittent radiationIt might be useful at this point to consider a very important photochemicaltechnique, that involving intermittent radiation. This may be used to determinethe average life-times of active intermediates in reactions, e.g. radical polymerisation,and rate coefficients for elementary processes, e.g. radical abstraction reac-
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COMPREHENSIVE CHEMICAL KINETICS
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P.O.ELSEVIER PUBLISHING COMPANY335
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Contributors to Volume 1L. BATTDepa
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Page 11 and 12: XCONTENTS4.3 Gas chromatography ...
Page 13: XI1CONTENTS4.6 Magnetic measurement
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Chapter 2Experimental Methods for t
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114 EXPERIMENTAL METHODS FOR FAST R
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;,124 EXPERIMENTAL METHODS FOR FAST
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178 REFERENCES46 M. EIGEN AND L. DE
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Chapter 3Experimental Methods for t
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182 EXPERIMENTAL METHODS FOR HETERO
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~~~ ._190 EXPERIMENTAL METHODS FOR
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192 EXPERIMENT A L MET H 0 D S F 0
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194 EXPERIMENT A L MET H o D s F o
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206 EXPERXMENTAL METHODS FOR HETERO
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222 EXPERIMENT A L METHODS F 0 R HE
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230 EXPERIMENT A L METHOD s FOR HET
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236 EXPERIMENT A L METHOD s FOR HE
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242 EXPERIMENT A L ME TH 0 D S FOR
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248 EXPERIMENT A L METHOD s F o R H
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254 EXPERIMENTAL MET HODS FOR HETER
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258 EXPERIMENT A L METHODS F 0 R HE
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266 EXPERIMENT A L MET H o D s F o
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270 EXPERIMENTAL MET HODS FOR HE TE
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274 EXPERIMENT A L METHOD s FOR HE
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280 DETECTION AND ESTIMATION OF INT
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344 TREATMENT OF EXPERIMENTAL DATAf
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346 TREATMENT OF EXPERIMENTAL DATAp
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348 TREATMENT OF EXPERIMENTAL DATAg
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350 TREATMENT OF EXPERIMENTAL DATAT
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358 TREATMENT OF EXPERIMENTAL DATA(
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362 TREATMENT OF EXPERIMENTAL DATAI
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364 TREATMENT OF EXPERIMENTAL DATAv
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366 TREATMENT OF EXPERIMENTAL DATAW
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370 TREATMENT OF EXPERIMENTAL DATAc
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372 TREATMENT OF EXPERIMENTAL DATAw
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376 TREATMENT OF EXPERIMENTAL DATAF
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380 TREATMENT OF EXPERIMENTAL DATAe
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384 TREATMENT OF EXPERIMENTAL DATAt
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388 TREATMENT OF EXPERIMENTAL DATAs
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41 2 TREATMENT OF EXPERIMENTAL DATA
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41 8 TREATMENT OF EXPERIMENTAL DATA
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420 TREATMENT OF EXPERIMENTAL DATAA
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IndexAabsorption cross section, che
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424 INDEXbenzyl chloride, matrix ph
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426 INDEXchlorine (contdj—, react
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428 INDEXdeuterium oxide, addition
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430 INDEXentropy change, in radical
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432 INDEXfrequency of oscillation,
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434 INDEXhydrogen atoms (contdj—,
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436 INDEXisotopes (contd.J—, use
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438 INDEXmethyl radicals, chain ter
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440 INDEXoctadiene, ESR determinati
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442 INDEXphotoelectric measurement,
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444 INDEXrad, definition of, 66radi
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446 INDEXSchmidt number, and mass t
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448 INDEXTtailing reducer, in gas c
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450 INDEXviscosity, and diffusion c
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Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

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