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Glass Melting Technology: A Technical and Economic ... - OSTI

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simplify heat exchange technique through adaptive fluid beds <strong>and</strong> use of special silos. Tecogen<br />

Inc. developed a fluidized bed batch preheater system for the Gas Research Institute in the<br />

1980s. GRI then developed a raining bed batch/cullet preheater with a counter-flow heat<br />

exchange system. Corning <strong>and</strong> Tecogen, supported by DOE, developed a raining bed batch <strong>and</strong><br />

cullet preheater in the late 1990s.<br />

Since the mid 1980s, a number of batch, cullet or mixed batch plus cullet preheaters have been<br />

introduced into glass manufacturing. Batch/cullet preheat temperatures of 482-932˚F (250–<br />

500˚C) <strong>and</strong> energy savings of 12 to 18 percent have been realized. Worldwide, 13 batch/cullet<br />

preheaters were installed, nine of these in Germany. European manufacturers have shown more<br />

interest in preheating systems because they have been faced with higher energy costs. Batch <strong>and</strong><br />

cullet preheaters have been developed <strong>and</strong> installed by GEA/Interprojekt (direct preheating),<br />

Zippe (indirect preheating), <strong>and</strong> Sorg (direct preheating). A combined direct cullet preheater <strong>and</strong><br />

electrostatic precipitator has been developed <strong>and</strong> installed by Edmeston. The Nienburger<br />

process, in which exhaust gases <strong>and</strong> mixed agglomerated batch are in direct contact in a hopper,<br />

has had the most success of all the preheating technologies tried. A combination preheater <strong>and</strong><br />

particulate capture variation to preheat loose batch-containing cullet is under development by<br />

BOC Gases.<br />

When evaluating a preheating technology for application to a glass furnace, a number of issues<br />

must be considered.<br />

• Does the unit preheat batch or cullet or mixed batch <strong>and</strong> cullet? Preheating of batch or cullet<br />

separately reduces the economic benefits <strong>and</strong> complicates the material h<strong>and</strong>ling systems.<br />

• Does the unit constrain the batch/cullet ratio? <strong>Glass</strong> makers need to be flexible with batch/cullet<br />

ratios to meet constantly changing requirements of manufacturing.<br />

• Does the unit increase pollution loading in exhaust gases, such as increased dust?<br />

Manufacturers in few countries will allow emissions to increase above current levels.<br />

• Does the unit treat exhaust gases to best st<strong>and</strong>ards for particulate <strong>and</strong> SOx emissions? If not, an<br />

expensive post-process abatement device must be installed on the exhaust gas h<strong>and</strong>ling system.<br />

IV.8.1. E-batch (BOC Gases, 2001)<br />

Electrostatic batch preheating technology, or "E-Batch," uses the waste heat from furnace<br />

exhaust gases for preheating batch <strong>and</strong> cullet to provide a simpler <strong>and</strong> lower-cost means of<br />

melting glass than conventional air-fuel furnaces when they are fitted with air pollution control<br />

systems. Developed by BOC Gases in 2001, the technology is unique in two ways. (1) It is<br />

designed to be integrated with oxy-fuel-fired furnaces. (2) It incorporates exhaust gas cleaning to<br />

the most stringent regulatory levels. The proprietary electrostatic mechanism (patent pending),<br />

which retains batch in the unit with occurrence of virtually no batch entrainment, is the key<br />

feature of E-Batch technology. (Alex<strong>and</strong>er, Jeffrey C., “Electrostatic batch preheating<br />

technology: E-Batch,” Ceramic Engineering <strong>and</strong> Science Proceedings, 22[1], 37-53 (2001))<br />

In this system, particulate matter is precipitated from the furnace exhaust gases <strong>and</strong> deposited<br />

onto the batch surface. As a result, cooled outlet gases are recirculated to temper the hot furnace<br />

gases to about 1148 ˚ F (620 ˚ C). The E-Batch design has a low enough pressure drop to operate<br />

under natural draft from a stack that is appropriately designed. Cleaned, cooled gases are<br />

discharged into the atmosphere through the stack, in which the pressure is controlled by a<br />

74

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