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Glass Melting Technology: A Technical and Economic ... - OSTI

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The modular design of the device makes for easy access to condensates for cleaning, but caused<br />

problems during operation. The Zippe indirect preheating device is in operation on furnaces in<br />

Europe, particularly in glass container furnaces in Germany, Switzerl<strong>and</strong> <strong>and</strong> the Netherl<strong>and</strong>s.<br />

(Barton, 1993) (Zippe B-H, <strong>Glass</strong>, 67[5] (1990)<br />

IV.8.6. Electrified Cullet Bed (Edmeston, Sweden, 1990)<br />

The Electrified Granulate Bed (EGB), a hybrid filter system, uses the cullet bed as a filter for<br />

waste gases. The system combines an electrostatic precipitator that removes dust with a direct<br />

cullet preheater. The hot waste gas enters the top of the system <strong>and</strong> passes through an ionizing<br />

stage, imparting an electrical charge to the dust particles. The gas then passes into a bed of<br />

granular cullet, which is polarized by a high-voltage electrode immersed in the cullet bed. The<br />

charged dust particles are attracted to the cullet, where they are deposited. The cullet is<br />

constantly being added at the top of a shaft from which it is removed at the bottom. The<br />

preheated cullet (up to 752 ˚ F [400 ˚ C]) <strong>and</strong> the attached particulates are charged into the<br />

furnace.<br />

In 1994, the Irish <strong>Glass</strong> Bottle Co., along with the British <strong>Glass</strong> Manufacturers Confederation<br />

<strong>and</strong> Edmeston GmbH, received a Thermie grant from the European Commission to develop this<br />

innovative cullet preheating process. The system developed by this group incorporated an<br />

electrostatic principle to collect furnace particulate onto the cullet that was fed to the furnace.<br />

Like the Zippe system, this device requires a separate cullet bin. Since the exhaust gases must be<br />

passed through a bed of cullet about 12 to 18 in. thick, the cullet must be of a reasonable size to<br />

minimize the pressure drop through the bed. Cullet preheat temperatures above 1292 ˚F (700 ˚C)<br />

have been realized, <strong>and</strong> particulate is recaptured with the system. A second unit installed on a<br />

new oxy-fuel furnace at Leone Industries in the United States has met New Source Performance<br />

St<strong>and</strong>ards (NSPS) st<strong>and</strong>ards for particulate control. (McGrath, J.M., “Preheating cullet while<br />

using the cullet ed as a filter for waste gases in the Edmeston heat transfer/emission control<br />

system,” <strong>Glass</strong> <strong>Technology</strong>, 37[5], 146-150 (1996))<br />

IV.9. Non-conventional melting systems<br />

Methods of combining melting <strong>and</strong> refining in non-conventional melting systems have been<br />

explored extensively both in the United States <strong>and</strong> Europe. Attempts to design innovative glass<br />

melting processes for melting <strong>and</strong> refining have generally segmented the melting process into<br />

distinct steps that incorporate driven systems to increase dissolution of s<strong>and</strong> particles <strong>and</strong> initial<br />

gaseous evolution from raw materials.<br />

Combined melting-refining systems explored over the past 25 years include the Rapid <strong>Melting</strong><br />

<strong>and</strong> Refining (RAMAR) by Owens Illinois; Fusion et Affinage Rapide (FAR) system by Saint-<br />

Gobain; Fusion et Affinage Rapide Electrique (FARE) system by Saint-Gobain; <strong>and</strong> the PPG P-<br />

10 system. (See details of these technologies below.)<br />

Since traditional glass melters rely on natural convection for internal melt movement, the melters<br />

are very “fragile.” Critical convection patterns are strongly affected by minor changes in inputs,<br />

largely changing product quality. More robust melters are needed to allow a stirred chemical<br />

reactor in which convection is controlled directly. Controlled stirring forces can counteract the<br />

forces created by thermal <strong>and</strong> compositional gradients <strong>and</strong> by release of gases. Owens-Illinois<br />

80

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