FIRST STEPS TOWARD SPACE - Smithsonian Institution Libraries
FIRST STEPS TOWARD SPACE - Smithsonian Institution Libraries
FIRST STEPS TOWARD SPACE - Smithsonian Institution Libraries
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NUMBER 10 45<br />
and myself, the aim of the research had switched<br />
toward the study of monopropellants. Also, the research<br />
was now financially supported by a new<br />
sponsor, the Italian Air Force. It had new headquarters,<br />
the laboratories of the Istituto di Aeronautica<br />
Generale of the School of Aeronautical<br />
Engineering of the University of Rome. We also<br />
welcomed to our program a new, very competent,<br />
collaborator, the Doctor of Chemistry Riccardo M.<br />
Corelli, later Professor of Aeronautical Technology<br />
at the same school.<br />
I remember quite distinctly how the first idea of<br />
the monopropellant was born during an evening<br />
stroll under the trees of Via Nomentana. My father<br />
was wondering about the possibilities of controlling<br />
solid propellant burning by introducing it in the<br />
combustion chamber as a slurry of fine solid-propellant<br />
particles in suspension (but not solution) in a<br />
liquid. The discussion centered on the way combustion<br />
of such a mixture could take place. I remember<br />
how, in what was a sudden illumination for my<br />
still unexperienced mind, I realized the meaning<br />
of thermochemical calculations which, independently<br />
of the burning mechanism, allow a simple<br />
prediction of the composition and state of the gases<br />
resulting from the combustion of any mixture of<br />
chemicals as soon as the temperature is sufficiently<br />
high.<br />
In practice, abandoning the not very practical<br />
FIGURE 18.—Monopropellant gasification apparatus.<br />
idea of a solid propellant slurry, we chose to work<br />
with a liquid explosive, desensitized by dilution<br />
with an inert solvent. The most easily available and<br />
one of the most effective liquid explosives being<br />
trinitroglycerine, we decided to try it despite its<br />
bad reputation. However, we also considered other<br />
substances, such as dinitroglycerin or dinitroglycol.<br />
We performed a limited number of tests with these<br />
substances. It was known that a relatively small fraction<br />
(30 percent) of an organic solvent such as<br />
methanol could practically make trinitroglycerin<br />
insensitive to shock. Dr. Corelli carefully checked<br />
this and other statements in the literature on the<br />
subject, with a small amount of the explosive prepared<br />
in our laboratory. After this I felt sufficiently<br />
confident to carry personally on a night train from<br />
Turin to Rome a few liters of the mixture which<br />
had been prepared for us at the powder plants of<br />
Avigliana. This was, of course, a flagrant violation<br />
to the official regulations concerning the transportation<br />
of explosive materials, and I shudder today<br />
at the responsibility I was taking. However, it was<br />
the only way to avoid the endless red-tape involved<br />
in legal shipment.<br />
Gasification tests were conducted in the apparatus<br />
shown in Figure 18. The monopropellant m<br />
contained in the tank b was pressurized, through<br />
the separating piston p by the gas of bottle a. The