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FIRST STEPS TOWARD SPACE - Smithsonian Institution Libraries

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NUMBER 10 45<br />

and myself, the aim of the research had switched<br />

toward the study of monopropellants. Also, the research<br />

was now financially supported by a new<br />

sponsor, the Italian Air Force. It had new headquarters,<br />

the laboratories of the Istituto di Aeronautica<br />

Generale of the School of Aeronautical<br />

Engineering of the University of Rome. We also<br />

welcomed to our program a new, very competent,<br />

collaborator, the Doctor of Chemistry Riccardo M.<br />

Corelli, later Professor of Aeronautical Technology<br />

at the same school.<br />

I remember quite distinctly how the first idea of<br />

the monopropellant was born during an evening<br />

stroll under the trees of Via Nomentana. My father<br />

was wondering about the possibilities of controlling<br />

solid propellant burning by introducing it in the<br />

combustion chamber as a slurry of fine solid-propellant<br />

particles in suspension (but not solution) in a<br />

liquid. The discussion centered on the way combustion<br />

of such a mixture could take place. I remember<br />

how, in what was a sudden illumination for my<br />

still unexperienced mind, I realized the meaning<br />

of thermochemical calculations which, independently<br />

of the burning mechanism, allow a simple<br />

prediction of the composition and state of the gases<br />

resulting from the combustion of any mixture of<br />

chemicals as soon as the temperature is sufficiently<br />

high.<br />

In practice, abandoning the not very practical<br />

FIGURE 18.—Monopropellant gasification apparatus.<br />

idea of a solid propellant slurry, we chose to work<br />

with a liquid explosive, desensitized by dilution<br />

with an inert solvent. The most easily available and<br />

one of the most effective liquid explosives being<br />

trinitroglycerine, we decided to try it despite its<br />

bad reputation. However, we also considered other<br />

substances, such as dinitroglycerin or dinitroglycol.<br />

We performed a limited number of tests with these<br />

substances. It was known that a relatively small fraction<br />

(30 percent) of an organic solvent such as<br />

methanol could practically make trinitroglycerin<br />

insensitive to shock. Dr. Corelli carefully checked<br />

this and other statements in the literature on the<br />

subject, with a small amount of the explosive prepared<br />

in our laboratory. After this I felt sufficiently<br />

confident to carry personally on a night train from<br />

Turin to Rome a few liters of the mixture which<br />

had been prepared for us at the powder plants of<br />

Avigliana. This was, of course, a flagrant violation<br />

to the official regulations concerning the transportation<br />

of explosive materials, and I shudder today<br />

at the responsibility I was taking. However, it was<br />

the only way to avoid the endless red-tape involved<br />

in legal shipment.<br />

Gasification tests were conducted in the apparatus<br />

shown in Figure 18. The monopropellant m<br />

contained in the tank b was pressurized, through<br />

the separating piston p by the gas of bottle a. The

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