2 Homometallic Alkoxides

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Figure 5.3 Ba2Ti4⊲ 3-O⊳⊲ 3-O⊳6⊲ - O⊳2O10⊲OH⊳7 core structure of [Ba2Ti4⊲ 3- O⊳⊲ 3-OMe⊳6⊲ -OMe⊳2⊲OMe⊳10⊲MeOH⊳7] (Me groups omitted). Metal Oxo-alkoxides 399 ligands. 82 The bridging and chelating CH3OC2H4O ligands with the -oxo ligands generate a twelve-coordination for the barium atoms. Finally it is noteworthy that barium and cerium(IV) form the mixed ligand hexanuclear compound [Ba4Ce⊲ 6-O⊳⊲ 3-OPr i ⊳8⊲OPr i ⊳2⊲Bu t COCHCOBu t ⊳4]. 125 The 6oxo atom is encapsulated in an octahedron of metals (trans-Ce2). 5.3 Scandium, Yttrium, Lanthanide, and Actinide-containing Oxo-alkoxides (Including Heterometallic Compounds) (Table 5.3) 5.3.1 Scandium, Yttrium, and Lanthanides Evans and co-workers have determined the structure of several interesting yttrium oxoalkoxides. The cyclopentadienyl yttrium oxide-methoxide [⊲C5H5⊳5Y5⊲ 5-O⊳⊲ 3- OMe⊳4⊲ -OMe⊳4] 108 has the square pyramidal Y5O9 core structure, which was subsequently found in the pentanuclear species [M5⊲ 5-O⊳⊲ 3-OR⊳4⊲ -OR⊳4⊲OR⊳5](MD Sc, Y, lanthanides) which have the cyclopentadienyl groups replaced by terminal alkoxo ligands. The giant centrosymmetrical molecule [Y14⊲ 4-O⊳2⊲ 3-Cl⊳2⊲ 3-OBu t ⊳4⊲ - Cl⊳8⊲ -OBu t ⊳14⊲OBu t ⊳10⊲thf⊳4] appears to be constructed of three units A–C. The outer unitAconsistsof the familiar trinuclear [Y3⊲ 3-Cl⊳⊲ 3-OBu t ⊳⊲ -OBu t ⊳3⊲OBu t ⊳3Cl⊲thf⊳2] which is linked to the next unit B [Y3⊲ 3-O⊳⊲ 3-OBu t ⊳⊲ -OBu t ⊳2⊲ -Cl⊳⊲ -OBu t ⊳2Cl] which in turn is linked to the central mononuclear unit C [Y⊲OBu t ⊳2Cl]. A is linked by its terminal chloride to one Y in B which is also linked by its 3-O to the Y in C. The whole molecule consists of the sequence ABCCBA with both C groups being chloride bridged to the terminal chlorides in the B units and by chloride bridges to each other. 109 The trinuclear anion [⊲C5H5⊳6Y3⊲ 3-O⊳⊲ -OMe⊳2] has also been reported. 110 The tetranuclear complex [Y4⊲ 4-O⊳⊲ 5-OBu t ⊳⊲ -OBu t ⊳3⊲ -Cl⊳3⊲OBu t ⊳3⊲thf⊳3] which has threefold symmetry can be considered as comprising the trinuclear anion [Y3⊲ 3-O⊳⊲ 3- OBu t ⊳⊲ -OBu t ⊳3⊲OBu t ⊳3Cl3] 3 on top of which the cation [Y⊲thf⊳3] 3 is clamped by
400 Table 5.3 Scandium, yttrium, lanthanide, and actinide-containing oxo-alkoxides (including heterometallic compounds) Metal Oxo M–oxo bond Mx–oxo Compound coord. coord. lengths ( ˚A) bond angles ( Ž ) Reference [Li8K2⊲O⊳⊲OBu t ⊳8⊲tmeda⊳2] 3, 4 (Li) 8 3-coord. Li, 1.895 (av.) Li2O, 61.2–151.3 94 tmeda D Me2NC2H4NMe2 4 (K) 4-coord. Li, 2.195 (av.) [Li4Ti4⊲ 5-O⊳2⊲ -O⊳2⊲OPr i ⊳12] 4 (Li) 5, 5 2.039 (av.) 5, 87.3–174.0 95 5, 6 (Ti) 1.864 (av.) 2, 107.0 [Na2Mo4⊲O⊳6⊲ -O⊳2⊲OPr i ⊳12] 5 (Na) t, , 1.722 (Mo), 2.256 (Na) MoONa, 144.5 96 6(Mo) Mo(O) 2, 1.691 (3) MoO, 1.715 (3) [Na2W2⊲O⊳2⊲OEt⊳14] 6, 6 t WO, 1.72 (2) – 97 [Na4Zr6⊲O⊳2⊲OEt⊳24] 5 (Na) 5 NaO, 2.666, 3.018 (6) NaOZr, 89.4, 163.1 98 6 (Zr) ZrO, 2.169, 2.169, 2.186 (5) Zr2O, 104.3 (av.) [K4Sb2⊲ 6-O⊳⊲OBu t ⊳8⊲thf⊳4] 6 (K) 6 SbO, 2.004 (5) Sb2O, 107.1 99 5 (Sb) KO, 3.047 (8) SbOK, 91.8–97.2, 161.1 K2O, 69.3–80.9, 156.1 [K4Sb4⊲ 4-O⊳2⊲OPr i ⊳12] 6 (K) 4 SbO, 1.982 (5) Sb2O, 105.8 99 5 (Sb) KO, 2.693 (5) SbOK, 104.3–105.2 K2O, 130.1 [Mg 2 Mo2⊲O⊳2⊲OMe⊳10⊲MeOH⊳4] 6, 6 t MoO, 1.685 (4) – 100 [Ca6⊲ 4-O⊳2⊲ 3-OEt⊳4⊲OEt⊳4⊲EtOH⊳6] 6 4 CaO, 2.402–2.529 (5) – 101 [H3Ba6⊲ 5-O⊳⊲OBu t ⊳11⊲OCEt2CH2O⊳⊲thf⊳3] 6, 5 5 BaO, 2.74–2.86 (1) – 102 av. 2.79 [H4Ba6⊲ 6-O⊳⊲OC2H4OMe⊳14] 8 6 BaO, 2.90–2.93 – 103 [Ba5⊲ 5-O⊳⊲hfip⊳8⊲hfipH⊳⊲thf⊳4⊲H2O⊳] 6, 7 5 BaO 2.87 (3) – 104 hfip D OCH⊲CF3⊳2 [Ba2Y4⊲ 6-O⊳⊲ 3-OEt⊳8⊲Bu t COCHCOBu t ⊳6] 7, 7 6 BaO, 3.027 (2) – 105 [Ba2Ti4⊲ 3-O⊳⊲ 3-OMe⊳6⊲ - OMe⊳2⊲OMe⊳10⊲MeOH⊳7] 9(Ba) 6(Ti) 3 YO, 2.363, 2.378 (3) BaO, 2.615, 2.706 (6) TiO, 1.695 (6) Ba2O, 102.6 22
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Alkoxo and Aryloxo Derivatives of M
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1 Introduction In 1978 the book ent
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1 INTRODUCTION 2 Homometallic Alkox
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Homometallic Alkoxides 5 to complet
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Table 2.1 (Continued) Homometallic
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Homometallic Alkoxides 15 reactivit
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Homometallic Alkoxides 17 By contra
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Homometallic Alkoxides 19 2.3 React
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Homometallic Alkoxides 21 has been
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Homometallic Alkoxides 23 obtain on
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y Evans and co-workers: 160,161 Hom
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Homometallic Alkoxides 27 The heter
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Homometallic Alkoxides 29 not conve
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Homometallic Alkoxides 31 In view o
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2.7.2 Steric Factors Homometallic A
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Homometallic Alkoxides 35 (b) When
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Homometallic Alkoxides 37 2.8 Trans
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Homometallic Alkoxides 39 with orga
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2.9.1.1 Alkoxides of Be, Mg, Ca, Sr
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MfN⊲SiMe3⊳2g2thfx C2HOR, Cpy !C
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Homometallic Alkoxides 45 2.10 Misc
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Zr⊲CH2Bu t ⊳4 C 4RfOH benzene !
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2.10.5 By Insertion of Oxygen into
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Homometallic Alkoxides 51 First hom
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O M R M OR M OR RO M (M = Tl; R = M
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Homometallic Alkoxides 55 3. Nuclea
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Homometallic Alkoxides 57 explain t
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Decomposition (%) 100 80 60 40 20 0
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Table 2.6 Volatilities of tetravale
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Homometallic Alkoxides 63 deduced t
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Table 2.10 Vapour pressure of Ti, Z
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Homometallic Alkoxides 67 Table 2.1
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3.2.10 Alkoxides of Later 3d Metals
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Homometallic Alkoxides 71 Table 2.1
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Homometallic Alkoxides 73 affected
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Homometallic Alkoxides 75 the range
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Homometallic Alkoxides 77 several c
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Homometallic Alkoxides 81 In toluen
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Bu t O Bu t O Bu t O Th O O Bu O t
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Homometallic Alkoxides 85 1H NMR st
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Homometallic Alkoxides 87 septet wa
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Homometallic Alkoxides 89 experimen
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Table 2.21 1 H NMR spectra of Al4(O
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Homometallic Alkoxides 93 3.5 Elect
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Homometallic Alkoxides 95 ligand fi
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Homometallic Alkoxides 97 susceptib
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10 −1 /xM 12 10 −200 −100 0 [
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Homometallic Alkoxides 101 alkoxide
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Homometallic Alkoxides 103 fragment
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Homometallic Alkoxides 105 The mass
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Homometallic Alkoxides 107 [Al⊲OP
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Homometallic Alkoxides 109 Under ca
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4.3.2 Phenol-Alcohol Exchange React
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4.4 Reactions with Alkanolamines Ho
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Homometallic Alkoxides 115 R D Pr i
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Homometallic Alkoxides 117 La(OPr i
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Homometallic Alkoxides 119 with the
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Homometallic Alkoxides 121 about 1.
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Homometallic Alkoxides 123 concentr
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Homometallic Alkoxides 125 and othe
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Homometallic Alkoxides 127 Interest
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OH Monofunctional bidentate HC N R
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Homometallic Alkoxides 131 metal al
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Homometallic Alkoxides 133 which yi
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shown in Eq. (2.286): O Mo2(OEt)6 H
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Homometallic Alkoxides 137 Phenyl i
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Homometallic Alkoxides 139 The 1990
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Eqs (2.312)-(2.315): where R D l-ad
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Homometallic Alkoxides 143 On the b
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Homometallic Alkoxides 145 The form
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Homometallic Alkoxides 147 On furth
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4.16 Interactions Between Two Diffe
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4Mo2(OPr i )6 + 18CO (excess) Homom
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isolobality of CR 0 and W⊲OR⊳3
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W2(OR)8 (R = CH2Bu t ) + CO + H2C C
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Homometallic Alkoxides 157 43. J.S.
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Homometallic Alkoxides 159 122. P.N
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Homometallic Alkoxides 161 201. A.
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Homometallic Alkoxides 163 281. R.C
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Homometallic Alkoxides 165 358. L.A
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Homometallic Alkoxides 167 430. M.R
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Homometallic Alkoxides 169 521. I.
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Homometallic Alkoxides 171 N.I. Koz
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Homometallic Alkoxides 177 876. J.
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Homometallic Alkoxides 179 966. H.
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Homometallic Alkoxides 181 1054. M.
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184 Alkoxo and Aryloxo Derivatives
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236 Table 4.1 (Continued) M-O Bond
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244 Table 4.3 Alkoxides of aluminiu
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248 Table 4.4 Alkoxides of germaniu
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256 Table 4.6 Alkoxides of scandium
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264 Table 4.7 Alkoxides of lanthani
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276 Table 4.9 Alkoxides of titanium
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278 Table 4.9 (Continued) Bond leng
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300 Table 4.11 Alkoxides of chromiu
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302 Table 4.11 (Continued) Metal M-
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316 Table 4.11 (Continued) Metal M-
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322 Table 4.12 Alkoxides of mangane
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332 Table 4.16 Alkoxides of zinc, c
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340 Table 4.17 (Continued) Coordina
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Page 349 and 350: 348 Table 4.18 Bimetallic alkoxides
Page 351 and 352: 350 Table 4.18 (Continued) Coordina
Page 355 and 356: 354 Table 4.19 Heterometallic alkox
Page 357 and 358: 356 Alkoxo and Aryloxo Derivatives
Page 395 and 396: 394 Table 5.2 Chemical shifts from
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Page 403 and 404: 402 Table 5.3 (continued) Metal Oxo
Page 407 and 408: 406 Table 5.4 Titanium and zirconiu
Page 421 and 422: 420 Table 5.6 Chromium sub-group me
Page 445 and 446: 1 INTRODUCTION 6 Metal Aryloxides T
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Cl S N N OH O Cl Me 3C NH HN OH HO
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N OH N OH Me 3C Me3C HO HO N N OH H
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Metal Aryloxides 455 2Ln C 3Hg⊲C6
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Metal Aryloxides 457 Mixed halo, ar
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product metal aryloxide 1e,1f (Eqs
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Metal Aryloxides 461 Eqs 6.39 and 6
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O Mg Mg OAr O Metal Aryloxides 463
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3.7 From Metal Hydrides Metal Arylo
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Metal Aryloxides 467 Two other impo
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Metal Aryloxides 469 Table 6.1 Meta
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Table 6.3 W-OAr distances for vario
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Metal Aryloxides 473 At first it is
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Zr−O distance (Å) V−O distance
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Metal Aryloxides 477 as expected ar
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Metal Aryloxides 479 whereas R D Me
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where OAr = O But But H3C H3C O Ta
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PPh 2 Ph P Pt OAr PPh2 where OAr =
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6 SURVEY OF METAL ARYLOXIDES 6.1 Sp
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487 Na2[V(O) 2(OAr) 2]2.4H2O.DMF 6-
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489 [Tc(O)(OAr)(di-OAr)] 8-quin 2.0
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491 [Ni3⊲OAr⊳6][ClO4].EtOH 8-qu
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493 [Pt(OAr⊳2](tcnq) sq. planar P
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495 [Al(OAr) 3].MeOH 8-quin 1.850 (
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497 [Sb(OAr) 2⊲S2COEt⊳] pentago
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499 [Tc(O)(OAr)(N-salicylideneDD-gl
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Metal Aryloxides 501 A contribution
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503 Table 6.8 Metal bi-phenolates B
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505 Table 6.9 Metal binaphtholates
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507 [TiCl2(di-OAr)]2 two tetrahedra
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Metal Aryloxides 509 co-workers hav
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511 [Li⊲ 2-OAr⊳]3 planar Li3O3
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513 Table 6.11 Sodium aryloxides Bo
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Table 6.12 Potassium aryloxides Met
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Table 6.15 Magnesium aryloxides Met
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519 Table 6.18 Barium aryloxides Bo
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521 Table 6.19 Group 3 metal and la
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523 [Me4N]La2Na2⊲ 4-OAr⊳⊲ 3-O
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525 [Nd⊲OC6H3Ph- 6-C6H5⊳⊲OC6H
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527 [⊲THF⊳Li⊲ 2-OAr⊳2Sm⊲C
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529 [Eu⊲ 2-OAr⊳4⊲OAr⊳2⊲ 3
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531 [Yb(OAr) 3⊲THF⊳2].THF squar
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Metal Aryloxides 533 carbon atoms a
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535 [Cp Ł Th(OAr)⊲CH2SiMe3⊳2]
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Metal Aryloxides 537 amido compound
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539 Table 6.21 Titanium aryloxides
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541 [Ti2⊲ 2-OAr⊳2(OAr) 2Cl4]2 e
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543 [Ti(OAr) 2⊲NMe2⊳2] tetrahed
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545 [Ti(OAr) 3Bu t ] tetrahedral Ti
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547 [⊲ArO⊳2Ti⊲ 2-ButNDCC4Et4C
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549 [Cp⊲C5H3Me-Pri-1,2)Ti(OAr)Cl]
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551 [CpTi(OAr) 2⊲HPPh⊳] OC6H3Pr
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553 [Ti⊲di-OAr⊳Cl2].THF 6-coord
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555 Table 6.22 Zirconium aryloxides
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557 [Zr(Ind-OAr) 2] 1-indenylphenox
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559 [Cp2Zr(OAr)] 18-electron Zr, tw
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Metal Aryloxides 561 The thermal st
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Metal Aryloxides 563 can only arise
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565 1.839 (2) 138 1.854 (2) 140 [(t
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567 [V(OAr) 3-N-Li(THF) 3] tetrahed
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569 [V(O)(di-OAr)] 6-coord. V, both
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571 cis,mer-[Nb(OAr) 2Cl3(THF)] dis
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573 [Nb⊲OC6H3Ph- 4-C6H7⊳⊲OAr
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575 Table 6.26 Tantalum aryloxides
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577 [(THF)(ArO) 3Ta⊲DNND⊳Ta(OAr
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579 [Ta(OAr) 2Cl2⊲CH2C6H5⊳] tbp
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581 [Ta(OAr) 2Cl⊲ 6-C6Me6⊳] OC6
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583 [Ta(OAr)⊲OC6H3Pri- 2-CMeDCH2
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585 [f(TMEDA)Na⊲ 2-OAr⊳2g2Cr] 4
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587 Table 6.28 Molybdenum aryloxide
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589 [Mo2⊲OAr⊳5⊲NMe2⊳⊲HNMe
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591 [Mo(Hdi-OAr) 2] 6-coord. Mo, on
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593 [W2⊲OAr⊳6⊲HNMe2⊳2] OC6F
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595 [W(OAr) 2⊲DNBu t ⊳2] OC6H3P
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597 [W(OC6H3Ph- 1-C6H4⊳2⊲PMePh2
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599 [W⊲OC6HPh3- 1-C6H4-c-C5H8C- O
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601 [⊲OC⊳3Mn⊲C4H4N⊳Mn⊲CO3
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603 Table 6.32 Simple aryloxides of
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607 [NEt4]3fFe6⊲ 4-S⊳4⊲OAr⊳
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609 [Ru(OAr) 2(CO)(py-CMeO-4)] cis-
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Table 6.35 Simple aryloxides of osm
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Metal Aryloxides 613 states, e.g. [
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Bu t O Bu t (6-I) Bu t Bu t O Metal
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6.2.10 Group 9 Metal Aryloxides Met
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Table 6.38 Simple aryloxides of iri
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Metal Aryloxides 621 Table 6.39 (Co
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623 [Pd(OAr)⊲C6H3fCH2NMe2g2-2,6)]
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Metal Aryloxides 625 Table 6.41 Sim
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629 [(RNC) 2Cu⊲ 2-OAr⊳2Cu(CNR)
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Metal Aryloxides 631 The two-coordi
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Table 6.45 (Continued) Metal Arylox
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Table 6.47 Simple aryloxides of mer
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637 Table 6.48 Aluminium aryloxides
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639 [⊲ArO⊳2Al⊲ -OAr⊳2Mg(THF
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641 [Al(OAr) 2⊲i-Bu⊳] trigonal
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643 [Al(OAr)Cl(Me)⊲NH2But⊳] OC6
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645 Table 6.49 Gallium aryloxides B
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647 Table 6.50 Indium aryloxides Bo
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Metal Aryloxides 649 Table 6.53 Tin
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651 Table 6.56 Bismuth aryloxides B
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REFERENCES Metal Aryloxides 653 1.
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Metal Aryloxides 655 56. Y. Nakayam
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Metal Aryloxides 657 123. T.W. Coff
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Metal Aryloxides 659 202. A. Bell,
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Metal Aryloxides 661 268. K. Ishiha
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Metal Aryloxides 663 341. B.S. Kali
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Metal Aryloxides 665 405. P.N. Rile
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Metal Aryloxides 667 483. Y. Hayash
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Metal Aryloxides 669 561. A.P. Shre
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688 Index alkoxometallate(IV) ligan
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690 Index cerium oxo-isopropoxide 3
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692 Index gas-phase photoelectron s
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694 Index lead tert-butoxide 386 Le
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696 Index metal-hydrogen bonds clea
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698 Index oxo-alkoxides 384, 385, 3
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700 Index sodium hydroxide 142 sodi
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702 Index titanium dichloride dieth
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704 Index X X-ray Absorption Near E
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2 Homometallic Alkoxides

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