2 Homometallic Alkoxides

601
[⊲OC⊳3Mn⊲C4H4N⊳Mn⊲CO3⊲OAr⊳]
picrate chelated to one Mn; pyrrole -bound
to one Mn and -bound to the other
[Mn4⊲ -OAr⊳6][ClO4]2.3MeCN.2Et2O
chain structure with two O between each
pair of Mn atoms
[Mn4⊲ -OAr⊳6][BPh4]2.2MeCN.2.5Et2O
chain structure with two O between each
pair of Mn atoms
[Mn2⊲ -OAr⊳3⊲MeCN⊳][PF6]2.Et2O
edge-shared bis-octahedron, MeCN
trans to -O
OC6H2⊲NO2⊳3-2,4,6 1.989 (8) 127 viii
2-OC6H4⊲2 0 -1,10-phen)-2 2.084 (8)–2.176 (8) ix
2-OC6H4⊲2 0 -bipy⊳-2 2.073 (7)–2.162 (7) x
2-OC6H4⊲2 0 -bipy⊳-2 2.088 (4), 2143 (4)
2.239 (4), 1.924 (4)
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ix J.C. Jeffery, P. Thornton, and M.D. Ward, Inorg. Chem., 33, 3612 (1994).
x D.A. Bardwell, J.C. Jeffery, and M.D. Ward, J. Chem. Soc., Dalton Trans., 3071 (1995).
x