2 Homometallic Alkoxides

591
[Mo(Hdi-OAr) 2]
6-coord. Mo, only one aryloxide bound,
both N deprotonated and bound
⊲2-HOC6H4⊳NC6H4N⊲2-OC6H4⊳ 1.982 (6)
1.967 (5)
132
129
xxvii
[Mo(di-OAr)(O) 2] fCH2NH⊲CH2-2-OC6H3But two molecules, 6-coord. Mo, trans OAr
-6⊳g2 1.946 (10)
1.948 (10)
137
139
xxviii
1.909 (10)
134
1.951 (10)
125
[Mo(di-OAr)(O) 2]
6-coord. Mo, trans OAr
fCH2NMe⊲CH2-2-OC6H4⊳g2 1.934 (1) 137 xxix
[Mo(di-OAr)(O) 2]
6-coord. Mo, trans OAr
fN⊲CH2-2-OC6H4⊳2⊲CH2CH2NMe2⊳g 1.953 (3)
1.967 (2)
127
120
xxix
[Mo(di-OAr)(O) 2]
6-coord. Mo, trans OAr
fN⊲CH2-2-OC6H4But-4⊳2⊲CH2CH2NMe2⊳g 1.977 (5)
1.954 (5)
130
127
xxix
[Mo(di-OAr)(O) 2]
6-coord. Mo, trans OAr
fN⊲CH2-2-OC6H4⊳2⊲CH2py⊳g 1.941 (2)
1.970 (2)
131
131
xxix
[Mo(di-OAr)(O) 2]
6-coord. Mo, trans OAr
fCH2NMe⊲2-OC6H4⊳g2 1.970 (2)
1.956 (2)
120
122
xxix
xviiiC.A. Kipke, W.E. Cleland Jr, S.A. Roberts, and J.H. Enemark, Acta Crystallog. C, 45, 870 (1989).
xixJ. Sundermeyer, K. Weber, H. Werner, N. Mahr, G. Bringmann, and O. Schupp, J. Organomet. Chem., 444, C37 (1993).
xxT.W. Coffindaffer, I.P. Rothwell, and J.C. Huffman, J. Chem. Soc., Chem. Comm., 1249 (1983).
xxiE.C. Walborsky, D.E. Wigley, E. Roland, J.C. Dewan, and R.R. Schrock, Inorg. Chem., 26, 1615 (1987).
xxiiJ.L. Kerschner, P.E. Fanwick, and I.P. Rothwell, J. Am. Chem. Soc., 109, 5840 (1987).
xxiiiJ.L. Kerschner, J.S. Yu, P.E. Fanwick, I.P. Rothwell, and J.C. Huffman, Organometallics, 8, 1414 (1989).
xxivJ.L. Kerschner, E.M. Torres, P.E. Fanwick, I.P. Rothwell, and J.C. Huffman, Organometallics, 8, 1424 (1989).
xxvM.H. Chisholm, I.P. Parkin, K. Folting, E.B. Lubkovsky, and W.E. Streib, J. Chem. Soc., Chem. Comm., 1673 (1991).
xxviS.A. Roberts, G.P. Darsey, W.E. Cleland Jr, and J.H. Enemark, Inorg. Chim. Acta, 154, 95 (1988).
xxviiS.F. Gheller, T.W. Hambley, M.R. Snow, K.S. Murray, and A.G. Wedd, Aust. J. Chem., 37, 911 (1984).
xxviiiP. Subramanian, J.T. Spence, R. Ortega, and J.H. Enemark, Inorg. Chem., 23, 2564 (1984).
xxixC.J. Hinshaw, G. Peng, R. Singh, J.T. Spence, J.H. Enemark, M. Bruck, J. Kristofzski, S.L. Merbs, R.B. Ortega, and P.A. Wexler, Inorg. Chem.,
28, 4483 (1989).