2 Homometallic Alkoxides

692 Index
gas-phase photoelectron spectroscopy 473
germanium 124, 125, 131
germanium alkoxides 31, 32, 36, 55, 72,
114, 115, 130, 132, 248–249
heterometallic 364, 365–366
homoleptic 243
homometallic 28
germanium aryloxides 645–646
germanium derivatives 473
germanium ethoxide 18, 72
germanium phenoxide 72
germanium tetra-alkoxides 74
germylene aryloxides 636
glasses
ceramics and 674–675
precursors for 31, 671
glycols 106, 123–125, 675
gold, nanoclusters 679
gold alkoxides 327–328, 331
gold aryloxides 630, 631
Grignard reagent 141, 516, 537, 574
group 1 metals see alkali metals
group 2 metals see alkaline earth metals
group 3 and the f-block metals, reactions
with alcohols 16–17
group 3 metal alkoxides 69
group 3 metal aryloxides 518–533,
521–532
group 3 metals 22–23, 24–26
group 4 metal alkoxides 52, 61, 84
group 4 metal aryloxides 538–563
group 4 metal tetraethoxides 55
group 4 metals 474, 509
group 5 metal alkoxides 66, 85–88
group 5 metal aryloxides 563
group 5 metals 468, 474, 477
alkylidene and alkylidyne compounds
615
group 6 metal alkoxides 68, 88
group 6 metal aryloxides 612–614
group 6 metals, alkylidene and alkylidyne
compounds 615
group 7 metal aryloxides 614–616
group 9 metal aryloxides 617–619
group 10 metal aryloxides 619–626
group 11 metal aryloxides 626–631
group 12 metal alkoxides 58–60, 80–81
group 12 metal aryloxides 631
group 13 metal alkoxides 69, 88–92
group 13 metal aryloxides 631–636
group 14 metal alkoxides 72–73, 74
group 14 metal aryloxides 636
group 14 metal tetraethoxides 55
group 15 metal alkoxides 73
group 15 metal aryloxides 636–650
group 16 metal alkoxides 73
H
hafnium 73, 188, 274–275, 338, 357, 560
hafnium alkoxides 32, 37, 65, 66, 102, 274,
276–279
boiling points of 64
heterometallic 358–360
synthesis of 37
hafnium aryloxides 560
hafnium cadmium complexes 357
hafnium copper(II) complexes 357
hafnium isopropoxide 274
hafnium lithium alkoxides 334
hafnium tetra-alkoxides 102
halide alkoxides 96, 106
halogens, reactions with metal alkoxides
130
heteroalkoxoniobates, stability of 212
heterobimetallic alkoxides 21, 22, 26, 28,
29, 30, 186, 197, 201
synthesis of 26, 192–193
heterobimetallic diethanolaminate derivatives
199–200
heterocumulenes 137, 483–484
heterometal alkoxides, single-source
precursors 221
heterometallic alkoxides 1, 54, 116,
183–228, 386
properties of 201–222
structures of 333–367
synthesis of 195–197
heterometallic chloride alkoxides, synthesis
of 193–195
heterometallic diethanolaminate alkoxides,
synthesis of 199–200
heterometallic glycolate alkoxides, synthesis
of 197–199
heterometallic oxo-alkoxides 387, 393, 396,
404
heterometallic triethanolaminate alkoxide
derivatives, synthesis of 200
heteropolymetallic alkoxide precursors,
synthesis of single-source 222
heteropolymetallic alkoxides, synthesis of
205
heterotantalates, stability of 212
heterotetrametallic alkoxides 195–197
heterotrimetallic alkoxides 195–197, 207,
216, 221, 333
hexa-alkoxometallates 213, 216, 219–220
hexa-alkoxoniobates 203, 211
hexa-tantalates 203, 211
hexafluoro-tert-butoxo (hftb) 230, 254, 258,
286, 672
hexatantalate derivatives, properties of
211–213
holmium see also cerium; dysprosium;
erbium; europium; gadolinium;