2 Homometallic Alkoxides

487
Na2[V(O) 2(OAr) 2]2.4H2O.DMF
6-coord V, Na phenoxide bridges
8-quin 1.966 (2)
1.967 (3)
121
121
xii
[NBu4][V(O) 2⊲OAr⊳2].H2O
6-coord. V
8-quin 1.98 (1) 122 xii
[⊲OAr⊳2(O)V⊲ -O⊳V(OAr) 2(O)] 8-quin 1.926 (6)
1.892 (6)
120
122
xiii
[V(O)(OAr)fPhC(O)DCHCMeDN–NDCPhOg]
6 coord. V, N(quin) trans to oxo
8-quin 1.852 (2) 123 xiv
[V(O)(OAr) 2⊲OPr i ⊳] 8-quin 1.925 (2) 121 xv
[V(O)(OAr)(azc)].MeOH
azc D ⊲2-OC6H3Me-4⊳NDN⊲2-C6H4COO⊳
1.902 (2) 122
8-quin 1.892 (4) 122 xvi
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