2 Homometallic Alkoxides

589
[Mo2⊲OAr⊳5⊲NMe2⊳⊲HNMe2⊳2] OC6F5 2.027 (7)
2.003 (7)
2.009 (5)
1.965 (7)
1.995 (6)
[fHB(mppz) 3 gMo(OAr)(NO)Cl] OC6H5 1.903 (4) 137 xi
6-coord. Mo, OAr trans to N(pz)
[NEt4][Mo(OAr) 2] OC6H4-⊲2-CH2NC6H4S⊳ 2.030 (7) 125 xii
6-coord. Mo, trans N 2.016 (8) 129
Oxo and imido aryloxides
[Mo(OAr) 2⊲O⊳2] OC6HPh2-2,6-Me 2-3,5 1.843 (2) 134 xiii
tetrahedral Mo, two molecules 1.866 (3)
1.844 (2)
1.868 (3)
[Mo(OAr) 2⊲O⊳2] OC6H4⊲pyrazolyl⊳-2 1.957 (3) 128 xiv
6-coord. Mo, cis di-oxo
[H2NMe2]2[Mo2⊲ 2-O⊳2⊲O⊳2⊲OAr⊳4] OC6F5 2.035 (8)
2.012 (8)
[(pyrazolylborate)Mo(O)(OAr) 2 ] OC6H4Me-4 1.954 (3)
1.928 (3)
[Mo(OAr) 2fNB⊲Me2⊳pzg⊲O⊳] OC6H4Cl-4 1.959 (3)
1.934 (3)
vi B. Kamenar and M. Penavic, J. Chem. Soc., Dalton Trans., 356 (1977).
vii N. Perchenek and A. Simon, Z. Anorg. Allg. Chem., 619, 103 (1993).
viii T.W. Coffindaffer, I.P. Rothwell, and J.C. Huffman, Inorg. Chem., 22, 2906 (1983).
ix T.W. Coffindaffer, I.P. Rothwell, and J.C. Huffman, Inorg. Chem., 23, 1433 (1984).
x T.W. Coffindaffer, I.P. Rothwell, and J.C. Huffman, Inorg. Chem., 24, 1643 (1985).
xi M. Cano, J.V. Heras, A. Monge, E. Pinilla, C.J. Jones, and J.A. McCleverty, J. Chem. Soc., Dalton Trans., 1555 (1994).
xii O.A. Rajan, J.T. Spence, C. Leman, M. Minelli, M. Sato, J.H. Enemark, P.M.H. Kroneck, and K. Sulger, Inorg. Chem., 22, 3065 (1983).
xiii L.E. Turner, P.E. Fanwick, and I.P. Rothwell, unpublished results.
xiv T.N. Sorrell, D.J. Ellis, and E.H. Cheesman, Inorg. Chim. Acta, 113, 1 (1986).
xv R.G. Abbott, F.A. Cotton, and L.R. Falvello, Inorg. Chem., 29, 514 (1990).
xvi Chaung-Sheng J. Chang, T.J. Pecci, M.D. Carducci, and J.H. Enemark, Inorg. Chem., 32, 4106 (1993).
xvii Chaung-Sheng J. Chang, T.J. Pecci, M.S. Carducci, and J.H. Enemark, Acta Crystallog. C, 48, 1096 (1992).
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