2 Homometallic Alkoxides

597
[W(OC6H3Ph- 1-C6H4⊳2⊲PMePh2⊳2] OC6H3Ph- 1 6-coord. W, trans O, cis P
-C6H4 1.88 (1)
1.87 (1)
141
144
xxxii
xxiii
[W(OC6H3Ph- 1-C6H4⊳2⊲py⊳2] OC6H3Ph- 1 6-coord. W, trans O, cis py
-C6H4 1.91 (1)
1.93 (1)
142
144
xxxiv
[W(OC6H3Ph- 1-C6H4⊳2⊲ 2- C2H4⊳⊲PMePh2⊳]
OC6H3Ph- 1 octahedral W, trans O, cis C
-C6H4 1.867 (5)
1.870 (5)
144
142
xxxv
[W(O)⊲OC6H3Ph- 1-C6H4⊳⊲PMePh2⊳3] OC6H3Ph- 1-C6H4 1.88 (1)
141 xxxvi
1.87 (1)
[W⊲OC6H3Ph- 6 -C6H5⊳⊲OAr⊳⊲PMePh2⊳] OC6H3Ph2-2,6 2.001 (6) 127 xxxii
OC6H3Ph- 6 -C6H5 2.033 (6) 118 xxxiii
[W⊲OC6H3Ph- 6 -C6H5⊳(OAr)(dppm)] OC6H3Ph2-2,6 2.038 (5) 119 xxxvii
OC6H3Ph- 6 -C6H5 1.986 (5) 127 xxxiv
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xxvii M.B. O’Regan, M.G. Vale, J.F. Payack, and R.R. Schrock, Inorg. Chem., 31, 1112 (1992).
xxviii M.B. O’Regan, A.H. Liu, W.C. Finch, R.R. Schrock, and W.M. Davis, J. Am. Chem. Soc., 112, 4331 (1990).
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xxxi D. Rabinovich, R. Zelman, and G. Parkin, J. Am. Chem. Soc., 114, 4611 (1992).
xxxii J.L. Kerschner, I.P. Rothwell, J.C. Huffman, and W.E. Streib, Organometallics, 7, 1871 (1988).
xxxiii J.L. Kerschner, P.E. Fanwick, I.P. Rothwell, and J.C. Huffman, Organometallics, 8, 1431 (1989).
xxxiv C.E. Kriley, P.E. Fanwick, and I.P. Rothwell, J. Am. Chem. Soc., 116, 5225 (1994).
xxxv P.E. Fanwick, I.P. Rothwell, and C.E. Kriley, Polyhedron, 15, 2403 (1996).
xxxvi J.L. Kerschner, C.E. Kriley, P.E. Fanwick, and I.P. Rothwell, Acta Crystallog. C, 50, 1193 (1994).
xxxvii J.L. Kerschner, P.E. Fanwick, and I.P. Rothwell, J. Am. Chem. Soc., 110, 8235 (1988).
144
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