2 Homometallic Alkoxides

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429 Table 5.7 Manganese sub-group metal-containing oxo-alkoxides (including heterometallic compounds) Metal Oxo M–Oxo bond Mx–Oxo Compound coord. coord. lengths ( ˚A) bond angles ( Ž ) Reference ⊲NEt4⊳2[Mn10⊲ 6-O⊳2f⊲OCH2⊳3CMeg6Cl8] 6 6 MnO, 1.95–2.54 (2) ( 6) av. 2.37 – 88 [Mn8Sb4⊲ 5-O⊳4⊲ 3-OEt⊳2⊲ -OEt⊳18] 5, 6 5 MnO, 2.23–2.38 ( 5) av. 2.30, – 25 SbO, 1.96, 1.97 ( 5) ⊲AsPh4⊳[Tc⊲O⊳⊲OC2H4S⊳2] 5 t TcO, 1.662 (5) (t) – 74 [Tc⊲O⊳⊲OC2H4O⊳Cl⊲phen⊳] phen D orthophenanthroline 6 t TcO, 1.661 (4) (t) – 75 [Re2⊲O⊳2⊲ -O⊳⊲ -OMe⊳2⊲OMe⊳4] 6 t, ReO, 1.690, 1.703 (12) (t) ReO, 1.916, 1.917 (13) ( ) Re2O, 83.8 76 [fMeRe⊲O⊳⊲OC2H4O⊳⊲py⊳g2⊲ -O⊳] 6 t, ReO, 1.691 (8) (t) ReO, 1.859 (1) ( ) 180 86 [MeRe⊲O⊳2⊲OC2Me4O⊳] 5 t ReO, 1.657, 1.702 (2) (t) – 86 [Re⊲O⊳fOCMe⊲CF3⊳2g3⊲thf⊳2] 6 t ReO, 1.681 (4) (t) – 174 [Re⊲O⊳fOCMe⊲CF3⊳2g3⊲CHCH:CPh2⊳⊲thf⊳] 6 t ReO, 1.674 (7) (t) – 174 t D terminal.
430 Alkoxo and Aryloxo Derivatives of Metals Figure 5.20 Structure of [Mn10⊲ 6- O⊳2f⊲OCH2⊳3CMeg6Cl8] 2 ( D Mn, ž D 6-oxo, D O in ligand, D Cl; H atoms omitted). The heterometallic oxo-ethoxide [Mn8Sb4⊲ 5-O⊳4⊲ 3-OEt⊳2⊲ -OEt⊳18] also contains 5-oxo ligands with 4 octahedral and 4 five-coordinated Mn atoms and 4 fivecoordinated Sb(III) atoms which have the electron lone pair in the vacant octahedral position. 25 5.7.2 Technetium and Rhenium Technetium is represented by two oxo-alkoxides, the five-coordinated anion [Tc⊲O⊳⊲OC2H4S⊳2] , 74 and the octahedral neutral species [Tc⊲O⊳⊲OC2H4O⊳Cl⊲phen⊳]. 75 The binuclear rhenium(VI) oxo-methoxide [Re2⊲O⊳2⊲ -O⊳⊲ -OMe⊳2⊲OMe⊳4] (Re–Re, 2.559 ˚A) has the confacial bi-octahedral structure, 76 whilst in the centrosymmetrical molecule [⊲C5H5N⊳⊲OC2H4O⊳MeRe⊲O⊳⊲ -O⊳Re⊲O⊳Me⊲OC2H4O⊳⊲C5H5N⊳] the octahedra share a common -oxo apex and the mononuclear Re(VII) [MeRe⊲O⊳2⊲OC2Me4O⊳] has a distorted TBP structure. 86 Examples of distorted octahedral Re(V) are found in the mononuclear species fac-[Re⊲O⊳fOCMe⊲CF3⊳2g3⊲thf⊳2] and syn,mer-[Re⊲O⊳fOCMe⊲CF3⊳2g3⊲CHCH ž žCPh2⊳⊲thf⊳]. 174 5.8 Iron Sub-group Metal-containing Oxo-alkoxides (Including Heterometallic Compounds) (Table 5.8) 5.8.1 Iron The structures of several iron oxo-alkoxides have been reported, one of the first being the oxo-bridged octahedral Fe(III) complex [⊲LFe⊳2 -O], where L is the pentadentate iminoalkoxo ligand MeCfCH2N ž žCMeCH2C⊲CF3⊳2⊲CH2NH2⊳. 87 The 6oxo ligand is featured in the hexanuclear anions [Fe6⊲ 6-O⊳f⊲OCH2⊳3CMeg6] 2 , 175 [Fe6⊲ 6-O⊳⊲ -OMe⊳12⊲OMe⊳6] 2 , 176 and [Fe6⊲ 6-O⊳⊲ -OMe⊳3f⊲OCH2⊳3CMeg3Cl6] 2 . 91 Each complex has either the [Fe6O19] 2 or [Fe6O13Cl6] 2 framework comparable with other metal oxo-alkoxides or polyoxoanions.
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Alkoxo and Aryloxo Derivatives of M
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1 Introduction In 1978 the book ent
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1 INTRODUCTION 2 Homometallic Alkox
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Homometallic Alkoxides 5 to complet
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Table 2.1 (Continued) Homometallic
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Homometallic Alkoxides 15 reactivit
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Homometallic Alkoxides 17 By contra
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Homometallic Alkoxides 19 2.3 React
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Homometallic Alkoxides 21 has been
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Homometallic Alkoxides 23 obtain on
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y Evans and co-workers: 160,161 Hom
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Homometallic Alkoxides 27 The heter
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Homometallic Alkoxides 29 not conve
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Homometallic Alkoxides 31 In view o
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2.7.2 Steric Factors Homometallic A
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Homometallic Alkoxides 35 (b) When
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Homometallic Alkoxides 37 2.8 Trans
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Homometallic Alkoxides 39 with orga
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2.9.1.1 Alkoxides of Be, Mg, Ca, Sr
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MfN⊲SiMe3⊳2g2thfx C2HOR, Cpy !C
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Homometallic Alkoxides 45 2.10 Misc
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Zr⊲CH2Bu t ⊳4 C 4RfOH benzene !
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2.10.5 By Insertion of Oxygen into
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Homometallic Alkoxides 51 First hom
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O M R M OR M OR RO M (M = Tl; R = M
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Homometallic Alkoxides 55 3. Nuclea
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Homometallic Alkoxides 57 explain t
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Decomposition (%) 100 80 60 40 20 0
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Table 2.6 Volatilities of tetravale
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Homometallic Alkoxides 63 deduced t
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Table 2.10 Vapour pressure of Ti, Z
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Homometallic Alkoxides 67 Table 2.1
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3.2.10 Alkoxides of Later 3d Metals
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Homometallic Alkoxides 71 Table 2.1
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Homometallic Alkoxides 73 affected
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Homometallic Alkoxides 75 the range
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Homometallic Alkoxides 77 several c
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Homometallic Alkoxides 81 In toluen
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Bu t O Bu t O Bu t O Th O O Bu O t
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Homometallic Alkoxides 85 1H NMR st
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Homometallic Alkoxides 87 septet wa
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Homometallic Alkoxides 89 experimen
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Table 2.21 1 H NMR spectra of Al4(O
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Homometallic Alkoxides 93 3.5 Elect
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Homometallic Alkoxides 95 ligand fi
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Homometallic Alkoxides 97 susceptib
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10 −1 /xM 12 10 −200 −100 0 [
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Homometallic Alkoxides 101 alkoxide
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Homometallic Alkoxides 103 fragment
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Homometallic Alkoxides 105 The mass
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Homometallic Alkoxides 107 [Al⊲OP
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Homometallic Alkoxides 109 Under ca
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4.3.2 Phenol-Alcohol Exchange React
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4.4 Reactions with Alkanolamines Ho
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Homometallic Alkoxides 115 R D Pr i
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Homometallic Alkoxides 117 La(OPr i
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Homometallic Alkoxides 119 with the
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Homometallic Alkoxides 121 about 1.
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Homometallic Alkoxides 123 concentr
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Homometallic Alkoxides 125 and othe
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Homometallic Alkoxides 127 Interest
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OH Monofunctional bidentate HC N R
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Homometallic Alkoxides 131 metal al
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Homometallic Alkoxides 133 which yi
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shown in Eq. (2.286): O Mo2(OEt)6 H
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Homometallic Alkoxides 137 Phenyl i
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Homometallic Alkoxides 139 The 1990
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Eqs (2.312)-(2.315): where R D l-ad
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Homometallic Alkoxides 143 On the b
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Homometallic Alkoxides 145 The form
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Homometallic Alkoxides 147 On furth
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4.16 Interactions Between Two Diffe
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4Mo2(OPr i )6 + 18CO (excess) Homom
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isolobality of CR 0 and W⊲OR⊳3
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W2(OR)8 (R = CH2Bu t ) + CO + H2C C
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Homometallic Alkoxides 157 43. J.S.
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Homometallic Alkoxides 159 122. P.N
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Homometallic Alkoxides 161 201. A.
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Homometallic Alkoxides 163 281. R.C
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Homometallic Alkoxides 165 358. L.A
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Homometallic Alkoxides 167 430. M.R
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Homometallic Alkoxides 169 521. I.
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Homometallic Alkoxides 171 N.I. Koz
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Homometallic Alkoxides 177 876. J.
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Homometallic Alkoxides 179 966. H.
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Homometallic Alkoxides 181 1054. M.
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184 Alkoxo and Aryloxo Derivatives
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236 Table 4.1 (Continued) M-O Bond
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244 Table 4.3 Alkoxides of aluminiu
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248 Table 4.4 Alkoxides of germaniu
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256 Table 4.6 Alkoxides of scandium
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264 Table 4.7 Alkoxides of lanthani
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276 Table 4.9 Alkoxides of titanium
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278 Table 4.9 (Continued) Bond leng
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300 Table 4.11 Alkoxides of chromiu
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302 Table 4.11 (Continued) Metal M-
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316 Table 4.11 (Continued) Metal M-
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322 Table 4.12 Alkoxides of mangane
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332 Table 4.16 Alkoxides of zinc, c
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340 Table 4.17 (Continued) Coordina
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348 Table 4.18 Bimetallic alkoxides
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354 Table 4.19 Heterometallic alkox
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Page 379 and 380: 378 Alkoxo and Aryloxo Derivatives
Page 395 and 396: 394 Table 5.2 Chemical shifts from
Page 401 and 402: 400 Table 5.3 Scandium, yttrium, la
Page 403 and 404: 402 Table 5.3 (continued) Metal Oxo
Page 407 and 408: 406 Table 5.4 Titanium and zirconiu
Page 421 and 422: 420 Table 5.6 Chromium sub-group me
Page 429: 428 Alkoxo and Aryloxo Derivatives
Page 445 and 446: 1 INTRODUCTION 6 Metal Aryloxides T
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Page 449 and 450: R1 OH O R2 R3NH2 −H2O Scheme 6.3
Page 451 and 452: Cl S N N OH O Cl Me 3C NH HN OH HO
Page 453 and 454: N OH N OH Me 3C Me3C HO HO N N OH H
Page 455 and 456: Metal Aryloxides 455 2Ln C 3Hg⊲C6
Page 457 and 458: Metal Aryloxides 457 Mixed halo, ar
Page 459 and 460: product metal aryloxide 1e,1f (Eqs
Page 461 and 462: Metal Aryloxides 461 Eqs 6.39 and 6
Page 463 and 464: O Mg Mg OAr O Metal Aryloxides 463
Page 465 and 466: 3.7 From Metal Hydrides Metal Arylo
Page 467 and 468: Metal Aryloxides 467 Two other impo
Page 469 and 470: Metal Aryloxides 469 Table 6.1 Meta
Page 471 and 472: Table 6.3 W-OAr distances for vario
Page 473 and 474: Metal Aryloxides 473 At first it is
Page 475 and 476: Zr−O distance (Å) V−O distance
Page 477 and 478: Metal Aryloxides 477 as expected ar
Page 479 and 480: Metal Aryloxides 479 whereas R D Me
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where OAr = O But But H3C H3C O Ta
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PPh 2 Ph P Pt OAr PPh2 where OAr =
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6 SURVEY OF METAL ARYLOXIDES 6.1 Sp
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487 Na2[V(O) 2(OAr) 2]2.4H2O.DMF 6-
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489 [Tc(O)(OAr)(di-OAr)] 8-quin 2.0
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491 [Ni3⊲OAr⊳6][ClO4].EtOH 8-qu
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493 [Pt(OAr⊳2](tcnq) sq. planar P
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495 [Al(OAr) 3].MeOH 8-quin 1.850 (
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497 [Sb(OAr) 2⊲S2COEt⊳] pentago
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499 [Tc(O)(OAr)(N-salicylideneDD-gl
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Metal Aryloxides 501 A contribution
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503 Table 6.8 Metal bi-phenolates B
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505 Table 6.9 Metal binaphtholates
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507 [TiCl2(di-OAr)]2 two tetrahedra
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Metal Aryloxides 509 co-workers hav
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511 [Li⊲ 2-OAr⊳]3 planar Li3O3
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513 Table 6.11 Sodium aryloxides Bo
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Table 6.12 Potassium aryloxides Met
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Table 6.15 Magnesium aryloxides Met
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519 Table 6.18 Barium aryloxides Bo
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521 Table 6.19 Group 3 metal and la
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523 [Me4N]La2Na2⊲ 4-OAr⊳⊲ 3-O
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525 [Nd⊲OC6H3Ph- 6-C6H5⊳⊲OC6H
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527 [⊲THF⊳Li⊲ 2-OAr⊳2Sm⊲C
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529 [Eu⊲ 2-OAr⊳4⊲OAr⊳2⊲ 3
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531 [Yb(OAr) 3⊲THF⊳2].THF squar
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Metal Aryloxides 533 carbon atoms a
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535 [Cp Ł Th(OAr)⊲CH2SiMe3⊳2]
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Metal Aryloxides 537 amido compound
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539 Table 6.21 Titanium aryloxides
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541 [Ti2⊲ 2-OAr⊳2(OAr) 2Cl4]2 e
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543 [Ti(OAr) 2⊲NMe2⊳2] tetrahed
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545 [Ti(OAr) 3Bu t ] tetrahedral Ti
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547 [⊲ArO⊳2Ti⊲ 2-ButNDCC4Et4C
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549 [Cp⊲C5H3Me-Pri-1,2)Ti(OAr)Cl]
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551 [CpTi(OAr) 2⊲HPPh⊳] OC6H3Pr
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553 [Ti⊲di-OAr⊳Cl2].THF 6-coord
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555 Table 6.22 Zirconium aryloxides
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557 [Zr(Ind-OAr) 2] 1-indenylphenox
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559 [Cp2Zr(OAr)] 18-electron Zr, tw
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Metal Aryloxides 561 The thermal st
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Metal Aryloxides 563 can only arise
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565 1.839 (2) 138 1.854 (2) 140 [(t
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567 [V(OAr) 3-N-Li(THF) 3] tetrahed
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569 [V(O)(di-OAr)] 6-coord. V, both
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571 cis,mer-[Nb(OAr) 2Cl3(THF)] dis
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573 [Nb⊲OC6H3Ph- 4-C6H7⊳⊲OAr
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575 Table 6.26 Tantalum aryloxides
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577 [(THF)(ArO) 3Ta⊲DNND⊳Ta(OAr
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579 [Ta(OAr) 2Cl2⊲CH2C6H5⊳] tbp
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581 [Ta(OAr) 2Cl⊲ 6-C6Me6⊳] OC6
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583 [Ta(OAr)⊲OC6H3Pri- 2-CMeDCH2
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585 [f(TMEDA)Na⊲ 2-OAr⊳2g2Cr] 4
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587 Table 6.28 Molybdenum aryloxide
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589 [Mo2⊲OAr⊳5⊲NMe2⊳⊲HNMe
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591 [Mo(Hdi-OAr) 2] 6-coord. Mo, on
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593 [W2⊲OAr⊳6⊲HNMe2⊳2] OC6F
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595 [W(OAr) 2⊲DNBu t ⊳2] OC6H3P
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597 [W(OC6H3Ph- 1-C6H4⊳2⊲PMePh2
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599 [W⊲OC6HPh3- 1-C6H4-c-C5H8C- O
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601 [⊲OC⊳3Mn⊲C4H4N⊳Mn⊲CO3
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603 Table 6.32 Simple aryloxides of
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607 [NEt4]3fFe6⊲ 4-S⊳4⊲OAr⊳
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609 [Ru(OAr) 2(CO)(py-CMeO-4)] cis-
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Table 6.35 Simple aryloxides of osm
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Metal Aryloxides 613 states, e.g. [
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Bu t O Bu t (6-I) Bu t Bu t O Metal
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6.2.10 Group 9 Metal Aryloxides Met
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Table 6.38 Simple aryloxides of iri
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Metal Aryloxides 621 Table 6.39 (Co
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623 [Pd(OAr)⊲C6H3fCH2NMe2g2-2,6)]
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Metal Aryloxides 625 Table 6.41 Sim
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629 [(RNC) 2Cu⊲ 2-OAr⊳2Cu(CNR)
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Metal Aryloxides 631 The two-coordi
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Table 6.45 (Continued) Metal Arylox
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Table 6.47 Simple aryloxides of mer
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637 Table 6.48 Aluminium aryloxides
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639 [⊲ArO⊳2Al⊲ -OAr⊳2Mg(THF
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641 [Al(OAr) 2⊲i-Bu⊳] trigonal
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643 [Al(OAr)Cl(Me)⊲NH2But⊳] OC6
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645 Table 6.49 Gallium aryloxides B
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647 Table 6.50 Indium aryloxides Bo
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Metal Aryloxides 649 Table 6.53 Tin
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651 Table 6.56 Bismuth aryloxides B
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REFERENCES Metal Aryloxides 653 1.
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Metal Aryloxides 655 56. Y. Nakayam
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Metal Aryloxides 657 123. T.W. Coff
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Metal Aryloxides 659 202. A. Bell,
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Metal Aryloxides 661 268. K. Ishiha
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Metal Aryloxides 663 341. B.S. Kali
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Metal Aryloxides 665 405. P.N. Rile
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Metal Aryloxides 667 483. Y. Hayash
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Metal Aryloxides 669 561. A.P. Shre
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688 Index alkoxometallate(IV) ligan
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690 Index cerium oxo-isopropoxide 3
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692 Index gas-phase photoelectron s
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694 Index lead tert-butoxide 386 Le
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696 Index metal-hydrogen bonds clea
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698 Index oxo-alkoxides 384, 385, 3
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700 Index sodium hydroxide 142 sodi
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702 Index titanium dichloride dieth
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704 Index X X-ray Absorption Near E
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2 Homometallic Alkoxides

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