2 Homometallic Alkoxides

More documents

Recommendations

Info

616 Alkoxo and Aryloxo Derivatives of Metals The structurally characterized compound fac,cis-[Re(OC6H4Me-4)(CO)3(PPh3)2] is produced by addition of 4-methylphenol to the corresponding methyl compound. 466 The insertion chemistry of this and related alkoxides has been discussed (Section 5.2). 6.2.9 Group 8 Metal Aryloxides As with other first row d-block metals, the aryloxide bond is an important component of many coordination compounds of iron formed with polydentate ligands. Simple aryloxide ligands have been applied mainly to the synthesis of binary compounds and adducts, as supporting ligands in (typically sulfur) cluster compounds and as the axial group in iron porphyrin compounds (Table 6.33). Treatment of the diethyl [FeEt2(bipy)2] with phenols HOC6H4X-4 was found to yield the corresponding bis(aryloxides). 467 Kinetic studies supported a pathway involving initial dissociation of bipy, coordination of phenol, and then elimination of ethane. The homoleptic iron(II) aryloxide [(ArO)Fe( 2-OAr)2Fe(OAr)] (OAr D OC6H2But 3-2,4,6) was obtained from the corresponding bis(trimethylsilyl)amide. 457 Treatment of FeCl3 with LiOAr in EtOH was found to produce the iron(III) anions [Fe(OAr)4] (Eq. 6.31, OAr D OC6HMe4- 2,3,5,6; OC6H2Cl3-2,4,6). 109 The bonding in these anions was of interest as a model for tyrosine binding. Interestingly the anions undergo reversible one-electron reductions at 1.32 V and 0.45 V (vs SCE) respectively, showing how substituents on the phenoxide ring can influence metal-based redox processes. A large number of high-spin, five-coordinate Fe(III) complexes [(porphyrin)Fe(OAr)] have been isolated and studied. 468,469 Cyclic voltammetric studies show that the Fe(II)/Fe(III) couple lies at a significantly negative potential. 470 A reasonable correlation between the reduction potential and Hammett -values for p-substituents on the aryloxide ligand was found. The high-spin Fe(II) anion [(porphyrin)Fe(OPh)] has been isolated and structurally characterized. 471 At low temperatures formation of low-spin adducts occurs with ligands such as pyridine and 1-methylimidazole. 472 The reaction of [(porphyrin)Fe(Ar)] compounds with O2 has been investigated. Initial insertion into the Fe–Ar bond was believed to be followed by rapid homolysis. 142 The aryloxide chemistry of ruthenium473 and osmium474 porphyrin compounds has also been investigated. Aryloxide ligands also play an important role in the area of biologically relevant iron–sulfur cluster chemistry. 475–477 Thecubiccluster[Fe4( 2-S)4(OAr)4] 2 shows significant spin delocalization onto the phenoxide nucleus. 478 The first and second reduction potentials for the [Fe4( 2-S)4] 2C core were found to undergo significant negative shifts (more difficult to reduce) upon replacing arenethiolates by aryloxide ligands. An important class of rhombic dodecahedral clusters [Fe6( 4-S)4(OAr)4] 3 has been isolated and extensively studied. 479,480 Ruthenium chemistry typically finds aryloxide ligands attached to the metal in low oxidation states. The extensive number of carbonyl aryloxide compounds reported for this metal exemplifies this (Table 6.34). The cluster compound [(H)2Ru6(CO)16( 2-O- 2-C6H4)] and derivatives contain the metallated phenoxide bridging two metal centres 6 as well as -bound to another.
6.2.10 Group 9 Metal Aryloxides Metal Aryloxides 617 Aryloxide coordination compounds of Co(II) andCo(III) typically adopt octahedral geometries (Table 6.36). In a number of these derivatives the metal coordination sphere is completed by chelation of ortho-substituents on the aryloxide, e.g. in [Co(OC6H2Cl3- 2,4,6)2L2] (LD imidazole, L2 D TMEDA) compounds where Co–Cl interactions are present. 481,482 The complex [Co(OPh)(PPh3)3] 483 is tetrahedral while treatment of Table 6.36 Simple aryloxides of cobalt Bond Bond length ( ˚A) angle ( Ž ) Compound Aryloxide M–O M–O–Ar Ref. [Co(OAr)⊲PPh3⊳3] tetrahedral Co [Co(OAr)⊲PPh3⊳3] tbp Co, axial O and P [Co(OAr) 2⊲N -methylimidazole⊳2] 6-coord. Co, Cl bound [Co(OAr) 2(TMEDA)] 6-coord. Co, trans-O, Cl bound [Co(OAr) 2⊲N-methylimidazole⊳2] 6-coord. Co, trans O(Ar), cis N [Co(OAr) 3] 6-coord. Co, mer-N3O3 [Co(OAr) 2][PF6].MeCN cis-CoO2N4 core [HCo(OAr)⊲O2CMe⊳⊲PMe3⊳2] metallated formyl phenoxide [ClCo(OAr)⊲O2CMe⊲PMe3⊳2] metallated formyl phenoxide [BrCo(OAr)⊲O2CMe⊳⊲PMe3⊳2] metallated formyl phenoxide [ICo(OAr) 2⊲O2CMe⊳⊲PMe3⊳2] metallated formyl phenoxide OC6H5 1.900 (9) 138 i OC6H2Me-4-Bu t - 2.001 (2) 120 ii 6-PPh2-2 OC6H2Cl3-2,4,6 1.898 (8) 131 iii 1.889 (8) 133 OC6H2Cl3-2,4,6 1.919 (3) 130 iv 1.929 (3) 129 OC6H4⊲NO2⊳-2 1.972 (2) 132 v 1.978 (2) 127 OC6H4⊲20py⊳-2 1.83 (1) 121 vi 1.885 (9) 117 1.83 (1) 121 2-OC6H4⊲20-bipy⊳-2 1.886 (4) 120 vii 1.869 (3) 125 OC6H2But-6-Me- 4- 1-CO 1.981 (3) 111 viii OC6H2But-6-Me- 4- 1-CO 1.977 (2) 113 ix OC6H2But-6-Me- 4- 1-CO 1.978 (4) 113 ix OC6H2But-6-Me- 4- 1-CO 1.965 (2) 110 ix iY. Hayashi, T. Yamamoto, A. Yamamoto, S. Komiya, and Y. Kushi, J. Am. Chem. Soc., 108, 385 (1986). iiH.-F. Klein, A. Brand, and G. Cordier, Z. Naturforsch. B, 53, 307 (1998). iiiM.B. Cingi, A.M.M. Lanfredi, A. Tiripicchio, J. Reedijk, and R. van Landschoot, Inorg. Chim. Acta, 39, 181 (1980). ivM. Basturkmen, D. Kisakurek, W.L. Driessen, S. Gorter, and J. Reedijk, Inorg, Chim. Acta, 271, 19 (1988). vR.G. Little, Acta Crystallogr. B, 35, 2398 (1979). viP. Ganis, A. Saporito, A. Vitagliano, and G. Valle, Inorg. Chim. Acta, 142, 75 (1988). viiJ.C. Jeffery, E. Schatz, and M.D. Ward, J. Chem. Soc., Dalton Trans., 1921 (1992). viiiH.-F. Klein, S. Haller, Hongjian Sun, Xiaoyan Li, T. Jung, C. Rohr, U. Florke, and H.-J. Haupt, Z. Naturforsch. B, 53, 587 (1998). ixH.-F. Klein, S. Haller, Hongjian Sun, Xiaoyan Li, T. Jung, C. Rohr, U. Florke, and H.-J. Haupt, Z. Naturforsch. B, 53, 856 (1998).
Page 1 and 2:
Alkoxo and Aryloxo Derivatives of M
Page 3 and 4:
1 Introduction In 1978 the book ent
Page 5 and 6:
1 INTRODUCTION 2 Homometallic Alkox
Page 7 and 8:
Homometallic Alkoxides 5 to complet
Page 9 and 10:
Table 2.1 (Continued) Homometallic
Page 11 and 12:
Page 13 and 14:
Page 15 and 16:
Page 17 and 18:
Homometallic Alkoxides 15 reactivit
Page 19 and 20:
Homometallic Alkoxides 17 By contra
Page 21 and 22:
Homometallic Alkoxides 19 2.3 React
Page 23 and 24:
Homometallic Alkoxides 21 has been
Page 25 and 26:
Homometallic Alkoxides 23 obtain on
Page 27 and 28:
y Evans and co-workers: 160,161 Hom
Page 29 and 30:
Homometallic Alkoxides 27 The heter
Page 31 and 32:
Homometallic Alkoxides 29 not conve
Page 33 and 34:
Homometallic Alkoxides 31 In view o
Page 35 and 36:
2.7.2 Steric Factors Homometallic A
Page 37 and 38:
Homometallic Alkoxides 35 (b) When
Page 39 and 40:
Homometallic Alkoxides 37 2.8 Trans
Page 41 and 42:
Homometallic Alkoxides 39 with orga
Page 43 and 44:
2.9.1.1 Alkoxides of Be, Mg, Ca, Sr
Page 45 and 46:
MfN⊲SiMe3⊳2g2thfx C2HOR, Cpy !C
Page 47 and 48:
Homometallic Alkoxides 45 2.10 Misc
Page 49 and 50:
Zr⊲CH2Bu t ⊳4 C 4RfOH benzene !
Page 51 and 52:
2.10.5 By Insertion of Oxygen into
Page 53 and 54:
Homometallic Alkoxides 51 First hom
Page 55 and 56:
O M R M OR M OR RO M (M = Tl; R = M
Page 57 and 58:
Homometallic Alkoxides 55 3. Nuclea
Page 59 and 60:
Homometallic Alkoxides 57 explain t
Page 61 and 62:
Decomposition (%) 100 80 60 40 20 0
Page 63 and 64:
Table 2.6 Volatilities of tetravale
Page 65 and 66:
Homometallic Alkoxides 63 deduced t
Page 67 and 68:
Table 2.10 Vapour pressure of Ti, Z
Page 69 and 70:
Homometallic Alkoxides 67 Table 2.1
Page 71 and 72:
3.2.10 Alkoxides of Later 3d Metals
Page 73 and 74:
Homometallic Alkoxides 71 Table 2.1
Page 75 and 76:
Homometallic Alkoxides 73 affected
Page 77 and 78:
Homometallic Alkoxides 75 the range
Page 79 and 80:
Homometallic Alkoxides 77 several c
Page 81 and 82:
Page 83 and 84:
Homometallic Alkoxides 81 In toluen
Page 85 and 86:
Bu t O Bu t O Bu t O Th O O Bu O t
Page 87 and 88:
Homometallic Alkoxides 85 1H NMR st
Page 89 and 90:
Homometallic Alkoxides 87 septet wa
Page 91 and 92:
Homometallic Alkoxides 89 experimen
Page 93 and 94:
Table 2.21 1 H NMR spectra of Al4(O
Page 95 and 96:
Homometallic Alkoxides 93 3.5 Elect
Page 97 and 98:
Homometallic Alkoxides 95 ligand fi
Page 99 and 100:
Homometallic Alkoxides 97 susceptib
Page 101 and 102:
10 −1 /xM 12 10 −200 −100 0 [
Page 103 and 104:
Homometallic Alkoxides 101 alkoxide
Page 105 and 106:
Homometallic Alkoxides 103 fragment
Page 107 and 108:
Homometallic Alkoxides 105 The mass
Page 109 and 110:
Homometallic Alkoxides 107 [Al⊲OP
Page 111 and 112:
Homometallic Alkoxides 109 Under ca
Page 113 and 114:
4.3.2 Phenol-Alcohol Exchange React
Page 115 and 116:
4.4 Reactions with Alkanolamines Ho
Page 117 and 118:
Homometallic Alkoxides 115 R D Pr i
Page 119 and 120:
Homometallic Alkoxides 117 La(OPr i
Page 121 and 122:
Homometallic Alkoxides 119 with the
Page 123 and 124:
Homometallic Alkoxides 121 about 1.
Page 125 and 126:
Homometallic Alkoxides 123 concentr
Page 127 and 128:
Homometallic Alkoxides 125 and othe
Page 129 and 130:
Homometallic Alkoxides 127 Interest
Page 131 and 132:
OH Monofunctional bidentate HC N R
Page 133 and 134:
Homometallic Alkoxides 131 metal al
Page 135 and 136:
Homometallic Alkoxides 133 which yi
Page 137 and 138:
shown in Eq. (2.286): O Mo2(OEt)6 H
Page 139 and 140:
Homometallic Alkoxides 137 Phenyl i
Page 141 and 142:
Homometallic Alkoxides 139 The 1990
Page 143 and 144:
Eqs (2.312)-(2.315): where R D l-ad
Page 145 and 146:
Homometallic Alkoxides 143 On the b
Page 147 and 148:
Homometallic Alkoxides 145 The form
Page 149 and 150:
Homometallic Alkoxides 147 On furth
Page 151 and 152:
4.16 Interactions Between Two Diffe
Page 153 and 154:
4Mo2(OPr i )6 + 18CO (excess) Homom
Page 155 and 156:
isolobality of CR 0 and W⊲OR⊳3
Page 157 and 158:
W2(OR)8 (R = CH2Bu t ) + CO + H2C C
Page 159 and 160:
Homometallic Alkoxides 157 43. J.S.
Page 161 and 162:
Homometallic Alkoxides 159 122. P.N
Page 163 and 164:
Homometallic Alkoxides 161 201. A.
Page 165 and 166:
Homometallic Alkoxides 163 281. R.C
Page 167 and 168:
Homometallic Alkoxides 165 358. L.A
Page 169 and 170:
Homometallic Alkoxides 167 430. M.R
Page 171 and 172:
Homometallic Alkoxides 169 521. I.
Page 173 and 174:
Homometallic Alkoxides 171 N.I. Koz
Page 175 and 176:
Page 177 and 178:
Page 179 and 180:
Homometallic Alkoxides 177 876. J.
Page 181 and 182:
Homometallic Alkoxides 179 966. H.
Page 183 and 184:
Homometallic Alkoxides 181 1054. M.
Page 185 and 186:
184 Alkoxo and Aryloxo Derivatives
Page 187 and 188:
Page 189 and 190:
Page 191 and 192:
Page 193 and 194:
Page 195 and 196:
Page 197 and 198:
Page 199 and 200:
Page 201 and 202:
Page 203 and 204:
Page 205 and 206:
Page 207 and 208:
Page 209 and 210:
Page 211 and 212:
Page 213 and 214:
Page 215 and 216:
Page 217 and 218:
Page 219 and 220:
Page 221 and 222:
Page 223 and 224:
Page 225 and 226:
Page 227 and 228:
Page 229 and 230:
Page 231 and 232:
Page 233 and 234:
Page 235 and 236:
Page 237 and 238:
236 Table 4.1 (Continued) M-O Bond
Page 239 and 240:
Page 241 and 242:
Page 243 and 244:
Page 245 and 246:
244 Table 4.3 Alkoxides of aluminiu
Page 247 and 248:
Page 249 and 250:
248 Table 4.4 Alkoxides of germaniu
Page 251 and 252:
Page 253 and 254:
Page 255 and 256:
Page 257 and 258:
256 Table 4.6 Alkoxides of scandium
Page 259 and 260:
Page 261 and 262:
Page 263 and 264:
Page 265 and 266:
264 Table 4.7 Alkoxides of lanthani
Page 267 and 268:
Page 269 and 270:
Page 271 and 272:
Page 273 and 274:
Page 275 and 276:
Page 277 and 278:
276 Table 4.9 Alkoxides of titanium
Page 279 and 280:
278 Table 4.9 (Continued) Bond leng
Page 281 and 282:
Page 283 and 284:
Page 285 and 286:
Page 287 and 288:
Page 289 and 290:
Page 291 and 292:
Page 293 and 294:
Page 295 and 296:
Page 297 and 298:
Page 299 and 300:
Page 301 and 302:
300 Table 4.11 Alkoxides of chromiu
Page 303 and 304:
302 Table 4.11 (Continued) Metal M-
Page 305 and 306:
Page 307 and 308:
Page 309 and 310:
Page 311 and 312:
Page 313 and 314:
Page 315 and 316:
Page 317 and 318:
316 Table 4.11 (Continued) Metal M-
Page 319 and 320:
Page 321 and 322:
Page 323 and 324:
322 Table 4.12 Alkoxides of mangane
Page 325 and 326:
Page 327 and 328:
Page 329 and 330:
Page 331 and 332:
Page 333 and 334:
332 Table 4.16 Alkoxides of zinc, c
Page 335 and 336:
Page 337 and 338:
Page 339 and 340:
Page 341 and 342:
340 Table 4.17 (Continued) Coordina
Page 343 and 344:
Page 345 and 346:
Page 347 and 348:
Page 349 and 350:
348 Table 4.18 Bimetallic alkoxides
Page 351 and 352:
Page 353 and 354:
Page 355 and 356:
354 Table 4.19 Heterometallic alkox
Page 357 and 358:
Page 359 and 360:
Page 361 and 362:
Page 363 and 364:
Page 365 and 366:
Page 367 and 368:
Page 369 and 370:
Page 371 and 372:
Page 373 and 374:
Page 375 and 376:
Page 377 and 378:
Page 379 and 380:
Page 381 and 382:
Page 383 and 384:
Page 385 and 386:
Page 387 and 388:
Page 389 and 390:
Page 391 and 392:
Page 393 and 394:
Page 395 and 396:
394 Table 5.2 Chemical shifts from
Page 397 and 398:
Page 399 and 400:
Page 401 and 402:
400 Table 5.3 Scandium, yttrium, la
Page 403 and 404:
402 Table 5.3 (continued) Metal Oxo
Page 405 and 406:
Page 407 and 408:
406 Table 5.4 Titanium and zirconiu
Page 409 and 410:
Page 411 and 412:
Page 413 and 414:
Page 415 and 416:
Page 417 and 418:
Page 419 and 420:
Page 421 and 422:
420 Table 5.6 Chromium sub-group me
Page 423 and 424:
Page 425 and 426:
Page 427 and 428:
Page 429 and 430:
Page 431 and 432:
Page 433 and 434:
Page 435 and 436:
Page 437 and 438:
Page 439 and 440:
Page 441 and 442:
Page 443 and 444:
Page 445 and 446:
1 INTRODUCTION 6 Metal Aryloxides T
Page 447 and 448:
Metal Aryloxides 447 or both of the
Page 449 and 450:
R1 OH O R2 R3NH2 −H2O Scheme 6.3
Page 451 and 452:
Cl S N N OH O Cl Me 3C NH HN OH HO
Page 453 and 454:
N OH N OH Me 3C Me3C HO HO N N OH H
Page 455 and 456:
Metal Aryloxides 455 2Ln C 3Hg⊲C6
Page 457 and 458:
Metal Aryloxides 457 Mixed halo, ar
Page 459 and 460:
product metal aryloxide 1e,1f (Eqs
Page 461 and 462:
Metal Aryloxides 461 Eqs 6.39 and 6
Page 463 and 464:
O Mg Mg OAr O Metal Aryloxides 463
Page 465 and 466:
3.7 From Metal Hydrides Metal Arylo
Page 467 and 468:
Metal Aryloxides 467 Two other impo
Page 469 and 470:
Metal Aryloxides 469 Table 6.1 Meta
Page 471 and 472:
Table 6.3 W-OAr distances for vario
Page 473 and 474:
Metal Aryloxides 473 At first it is
Page 475 and 476:
Zr−O distance (Å) V−O distance
Page 477 and 478:
Metal Aryloxides 477 as expected ar
Page 479 and 480:
Metal Aryloxides 479 whereas R D Me
Page 481 and 482:
where OAr = O But But H3C H3C O Ta
Page 483 and 484:
PPh 2 Ph P Pt OAr PPh2 where OAr =
Page 485 and 486:
6 SURVEY OF METAL ARYLOXIDES 6.1 Sp
Page 487 and 488:
487 Na2[V(O) 2(OAr) 2]2.4H2O.DMF 6-
Page 489 and 490:
489 [Tc(O)(OAr)(di-OAr)] 8-quin 2.0
Page 491 and 492:
491 [Ni3⊲OAr⊳6][ClO4].EtOH 8-qu
Page 493 and 494:
493 [Pt(OAr⊳2](tcnq) sq. planar P
Page 495 and 496:
495 [Al(OAr) 3].MeOH 8-quin 1.850 (
Page 497 and 498:
497 [Sb(OAr) 2⊲S2COEt⊳] pentago
Page 499 and 500:
499 [Tc(O)(OAr)(N-salicylideneDD-gl
Page 501 and 502:
Metal Aryloxides 501 A contribution
Page 503 and 504:
503 Table 6.8 Metal bi-phenolates B
Page 505 and 506:
505 Table 6.9 Metal binaphtholates
Page 507 and 508:
507 [TiCl2(di-OAr)]2 two tetrahedra
Page 509 and 510:
Metal Aryloxides 509 co-workers hav
Page 511 and 512:
511 [Li⊲ 2-OAr⊳]3 planar Li3O3
Page 513 and 514:
513 Table 6.11 Sodium aryloxides Bo
Page 515 and 516:
Table 6.12 Potassium aryloxides Met
Page 517 and 518:
Table 6.15 Magnesium aryloxides Met
Page 519 and 520:
519 Table 6.18 Barium aryloxides Bo
Page 521 and 522:
521 Table 6.19 Group 3 metal and la
Page 523 and 524:
523 [Me4N]La2Na2⊲ 4-OAr⊳⊲ 3-O
Page 525 and 526:
525 [Nd⊲OC6H3Ph- 6-C6H5⊳⊲OC6H
Page 527 and 528:
527 [⊲THF⊳Li⊲ 2-OAr⊳2Sm⊲C
Page 529 and 530:
529 [Eu⊲ 2-OAr⊳4⊲OAr⊳2⊲ 3
Page 531 and 532:
531 [Yb(OAr) 3⊲THF⊳2].THF squar
Page 533 and 534:
Metal Aryloxides 533 carbon atoms a
Page 535 and 536:
535 [Cp Ł Th(OAr)⊲CH2SiMe3⊳2]
Page 537 and 538:
Metal Aryloxides 537 amido compound
Page 539 and 540:
539 Table 6.21 Titanium aryloxides
Page 541 and 542:
541 [Ti2⊲ 2-OAr⊳2(OAr) 2Cl4]2 e
Page 543 and 544:
543 [Ti(OAr) 2⊲NMe2⊳2] tetrahed
Page 545 and 546:
545 [Ti(OAr) 3Bu t ] tetrahedral Ti
Page 547 and 548:
547 [⊲ArO⊳2Ti⊲ 2-ButNDCC4Et4C
Page 549 and 550:
549 [Cp⊲C5H3Me-Pri-1,2)Ti(OAr)Cl]
Page 551 and 552:
551 [CpTi(OAr) 2⊲HPPh⊳] OC6H3Pr
Page 553 and 554:
553 [Ti⊲di-OAr⊳Cl2].THF 6-coord
Page 555 and 556:
555 Table 6.22 Zirconium aryloxides
Page 557 and 558:
557 [Zr(Ind-OAr) 2] 1-indenylphenox
Page 559 and 560:
559 [Cp2Zr(OAr)] 18-electron Zr, tw
Page 561 and 562:
Metal Aryloxides 561 The thermal st
Page 563 and 564:
Metal Aryloxides 563 can only arise
Page 565 and 566: 565 1.839 (2) 138 1.854 (2) 140 [(t
Page 567 and 568: 567 [V(OAr) 3-N-Li(THF) 3] tetrahed
Page 569 and 570: 569 [V(O)(di-OAr)] 6-coord. V, both
Page 571 and 572: 571 cis,mer-[Nb(OAr) 2Cl3(THF)] dis
Page 573 and 574: 573 [Nb⊲OC6H3Ph- 4-C6H7⊳⊲OAr
Page 575 and 576: 575 Table 6.26 Tantalum aryloxides
Page 577 and 578: 577 [(THF)(ArO) 3Ta⊲DNND⊳Ta(OAr
Page 579 and 580: 579 [Ta(OAr) 2Cl2⊲CH2C6H5⊳] tbp
Page 581 and 582: 581 [Ta(OAr) 2Cl⊲ 6-C6Me6⊳] OC6
Page 583 and 584: 583 [Ta(OAr)⊲OC6H3Pri- 2-CMeDCH2
Page 585 and 586: 585 [f(TMEDA)Na⊲ 2-OAr⊳2g2Cr] 4
Page 587 and 588: 587 Table 6.28 Molybdenum aryloxide
Page 589 and 590: 589 [Mo2⊲OAr⊳5⊲NMe2⊳⊲HNMe
Page 591 and 592: 591 [Mo(Hdi-OAr) 2] 6-coord. Mo, on
Page 593 and 594: 593 [W2⊲OAr⊳6⊲HNMe2⊳2] OC6F
Page 595 and 596: 595 [W(OAr) 2⊲DNBu t ⊳2] OC6H3P
Page 597 and 598: 597 [W(OC6H3Ph- 1-C6H4⊳2⊲PMePh2
Page 599 and 600: 599 [W⊲OC6HPh3- 1-C6H4-c-C5H8C- O
Page 601 and 602: 601 [⊲OC⊳3Mn⊲C4H4N⊳Mn⊲CO3
Page 603 and 604: 603 Table 6.32 Simple aryloxides of
Page 607 and 608: 607 [NEt4]3fFe6⊲ 4-S⊳4⊲OAr⊳
Page 609 and 610: 609 [Ru(OAr) 2(CO)(py-CMeO-4)] cis-
Page 611 and 612: Table 6.35 Simple aryloxides of osm
Page 613 and 614: Metal Aryloxides 613 states, e.g. [
Page 615: Bu t O Bu t (6-I) Bu t Bu t O Metal
Page 619 and 620: Table 6.38 Simple aryloxides of iri
Page 621 and 622: Metal Aryloxides 621 Table 6.39 (Co
Page 623 and 624: 623 [Pd(OAr)⊲C6H3fCH2NMe2g2-2,6)]
Page 625 and 626: Metal Aryloxides 625 Table 6.41 Sim
Page 629 and 630: 629 [(RNC) 2Cu⊲ 2-OAr⊳2Cu(CNR)
Page 631 and 632: Metal Aryloxides 631 The two-coordi
Page 633 and 634: Table 6.45 (Continued) Metal Arylox
Page 635 and 636: Table 6.47 Simple aryloxides of mer
Page 637 and 638: 637 Table 6.48 Aluminium aryloxides
Page 639 and 640: 639 [⊲ArO⊳2Al⊲ -OAr⊳2Mg(THF
Page 641 and 642: 641 [Al(OAr) 2⊲i-Bu⊳] trigonal
Page 643 and 644: 643 [Al(OAr)Cl(Me)⊲NH2But⊳] OC6
Page 645 and 646: 645 Table 6.49 Gallium aryloxides B
Page 647 and 648: 647 Table 6.50 Indium aryloxides Bo
Page 649 and 650: Metal Aryloxides 649 Table 6.53 Tin
Page 651 and 652: 651 Table 6.56 Bismuth aryloxides B
Page 653 and 654: REFERENCES Metal Aryloxides 653 1.
Page 655 and 656: Metal Aryloxides 655 56. Y. Nakayam
Page 657 and 658: Metal Aryloxides 657 123. T.W. Coff
Page 659 and 660: Metal Aryloxides 659 202. A. Bell,
Page 661 and 662: Metal Aryloxides 661 268. K. Ishiha
Page 663 and 664: Metal Aryloxides 663 341. B.S. Kali
Page 665 and 666: Metal Aryloxides 665 405. P.N. Rile
Page 667 and 668:
Metal Aryloxides 667 483. Y. Hayash
Page 669 and 670:
Metal Aryloxides 669 561. A.P. Shre
Page 671 and 672:
Page 673 and 674:
Page 675 and 676:
Page 677 and 678:
Page 679 and 680:
Page 681 and 682:
Page 683 and 684:
Page 685 and 686:
Page 687 and 688:
688 Index alkoxometallate(IV) ligan
Page 689 and 690:
690 Index cerium oxo-isopropoxide 3
Page 691 and 692:
692 Index gas-phase photoelectron s
Page 693 and 694:
694 Index lead tert-butoxide 386 Le
Page 695 and 696:
696 Index metal-hydrogen bonds clea
Page 697 and 698:
698 Index oxo-alkoxides 384, 385, 3
Page 699 and 700:
700 Index sodium hydroxide 142 sodi
Page 701 and 702:
702 Index titanium dichloride dieth
Page 703:
704 Index X X-ray Absorption Near E
show all

2 Homometallic Alkoxides

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?