2 Homometallic Alkoxides

593
[W2⊲OAr⊳6⊲HNMe2⊳2] OC6F5 1.917 (8) 157 vi
nearly eclipsed, anti-N atoms, W 6C
2 core 1.95 (1)
1.992 (9)
[W(OAr)Cl5] trans-[W(OAr) 2Cl4]
mer-[W(OAr) 3Cl3]
Mixed aryloxy halides
OC6H3Me2-2,6
OC6H3Me2-2,6
OC6H3Pr
1.82 (2)
1.860 (5)
180
180
vii
vii
i 2-2,6 1.832 (2)
1.848 (2)
173
156
viii
1.836 (2)
167
cis-[W(OAr⊳2Cl4] OC6H3Ph2-2,6 1.824 (6)
1.855 (7)
142
149
viii
cis-[W(OAr) 2Cl4] OC6H3Ph2-2,6 1.851 (3)
1.840 (3)
144
148
ix
cis-[W(OAr) 2Cl4] OC6H3Pri 2-2,6 1.814 (8)
1.786 (9)
169
177
x
trans-[W(OAr) 4Cl2] OC6H51.83 (1)
1.90 (1)
155
166
xi
1.82 (1)
155
1.72 (1)
155
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vii N. Kanehisa, Y. Kai, N. Kasai, H. Yasuda, Y. Nakayama, and A. Nakamura, Bull. Chem. Soc. Jpn., 65, 1197 (1992).
viii F. Quignard, M. Leconte, J.-M. Basset, Leh-Yeh Hsu, J.J. Alexander, and S.G. Shore, Inorg. Chem., 26, 4272 (1987).
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134