2 Homometallic Alkoxides

599
[W⊲OC6HPh3- 1-C6H4-c-C5H8C- O⊳⊲OAr⊳⊲ 2-c-C5H8CDO⊳] OC6HPh4-2,3,5,6
OC6HPh3- 1 [W(O)(OAr) 2fOCPh⊲C6H4⊳CHPh2g]
-C6H4-c-C5H8C-O
OC6HPh4-2,3,5,6
1.819 (9)
1.942 (9)
1.911 (5)
1.845 (4)
[W3⊲di-OAr⊳3⊲ -O⊳3⊲O⊳3] S⊲2-OC6H4⊳2 1.90 (1)
2.02 (1)
1.87 (1)
1.99 (1)
1.84 (1)
1.87 (1)
[W2⊲ 2-H⊳⊲ 2-NMe2⊳(di-OAr)(di-
OAr-H)⊲NMe2⊳⊲HNMe2⊳]
CH2⊲2-OC6H3But one cyclometallated di-OAr
-6-Me-4⊳2
CH⊲2-OC6H3Bu
1.939 (7)
1.998 (7)
t-6-Me-4⊳2 1.967 (7)
1.984 (7)
xxxviii M.A. Lockwood, P.E. Fanwick, and I.P. Rothwell, unpublished results.
xxxix M.A. Lockwood, P.E. Fanwick, and I.P. Rothwell, Polyhedron, 14, 3363 (1995).
xl J.L. Kerschner, E.M. Torres, P.E. Fanwick, I.P. Rothwell, and J.C. Huffman, Organometallics, 8, 1424 (1989).
xli D.J. Darensbourg, K.M. Sanchez, and J.H. Reibenspies, Inorg. Chem., 27, 3269 (1988).
xlii D.J. Darensbourg, B.L. Mueller, C.J. Bischoff, S.S. Chojnacki, and J.H. Reibenspies, Inorg. Chem., 30, 2418 (1991).
xliii D.J. Darensbourg, B.L. Mueller, and J.H. Reibenspies, J. Organomet. Chem., 451, 83 (1993).
xliv D.J. Darensbourg, K.M. Sanchez, J.H. Reibenspies, and A.L. Rheingold, J. Am. Chem. Soc., 111, 7094 (1989).
xlv M.A. Lockwood, P.E. Fanwick, and I.P. Rothwell, J. Chem. Soc., Chem. Commun., 2013 (1996).
xlvi P. Berges, W. Hinrichs, A. Holzmann, J. Wiese and G. Klar, J. Chem. Res., 10, 201 (1986).
xlvii M.H. Chisholm, I.P. Parkin, K. Folting, E.B. Lubkovsky, and W.E. Streib, J. Chem. Soc., Chem. Commun., 1673 (1991).
xlviii M.H. Chisholm, J-H. Huang, J.C. Huffman, and I.P. Parkin, Inorg. Chem., 36, 1642 (1997).
151
141
149
172
124
129
140
131
134
131
149
148
121
120
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xlv
xlvi
xlvii
xlviii