2 Homometallic Alkoxides

549
[Cp⊲C5H3Me-Pri-1,2)Ti(OAr)Cl] two molecules
OC6H3Me2-2,6 1.883 (3)
1.870 (3)
147
145
lxiv
[(ansa-Cp)Ti(OAr) 2 ]
2,3-bis(3-methyl-cyclopentadienyl)butane
2-naphtholato 1.903 (6) 146 lxv
[(ansa-Cp)Ti(OAr) 2 ].cyclohexane
2,3-bis(3-methyl-cyclopentadienyl)butane
2-naphtholato 1.895 (5) 154 lxv
[(ansa-Cp)Ti(OAr) 2 ]
1,10-(hexamethyltrisilane-1,3-diyl)-bis-Cp OC6H4Cl-4 1.911 (7)
1.906 (6)
138
138
lxvi
[Cp2TifO- 6-Ar-Cr(CO) 3g2] OC6H4Me-4 1.941 (6)
1.912 (5)
132
144
lxvii
[Cp2TifO- 6-Ar-Cr(CO) 3gBr]
[Cp(Cp-ArO)TiCl]
[(Cp-ArO)Ti⊲CH2Ph⊳2]
OC6H4Me-4
c-C5H4⊲CEt2C6H4O-2⊳
OC6H3Me-4-⊲
1.903 (6)
1.879 (6)
143
136
lxvii
lxviii
5 [CpTi(OAr) 3]
-C5Me4⊳-2
OC6H3Pr
1.851 (7) 127 lxix
i 2-2,6 1.80 (2)
1.79 (2)
152
145
lxx
1.80 (2) 163
livJ.E. Hill, P.E. Fanwick, and I.P. Rothwell, Organometallics, 9, 2211 (1990).
lvL.D. Durfee, P.E. Fanwick, I.P. Rothwell, K. Folting, and J.C. Huffman, J. Am. Chem. Soc., 109, 4720 (1987).
lviL.D. Durfee, J.E. Hill, P.E. Fanwick, and I.P. Rothwell, Organometallics, 9, 75 (1990).
lviiM.G. Thorn, P.E. Fanwick, and I.P. Rothwell, Organometallics, 18, 4442 (1999).
lviiiYang Qingchuan, Jin Xianglin, Xu Xiaojie, Li Genpei, Tang Youqi, and Chen Shoushan, Sci. Sin., Ser. B (Engl. Ed.), 25, 356 (1982).
lixB.S. Kalirai, J.-D. Foulon, T.A. Hamor, C.J. Jones, P.D. Beer, and S.P. Fricker, Polyhedron, 10, 1847 (1991).
lxB. Cetinkaya, P.B. Hitchcock, M.F. Lappert, S. Torroni, J.L. Atwood, W.E. Hunter, and M.J. Zaworotko, J. Organomet. Chem., 188, C31 (1980).
lxiC. Lecomte, Y. Dusausoy, and J. Protas, C.R. Acad. Sci., Ser. C, 280, 813 (1975).
lxiiJ. Besancon, S. Top, J. Tirouflet, Y. Dusausoy, C. Lecomte, and J. Protas, J. Organomet. Chem., 127, 153 (1977).
lxiiiC. Lecomte, Y. Dusausoy, J. Protas, J. Tirouflet, and A. Dormond, J. Organomet. Chem., 73, 67 (1977).
lxivJ. Besancon, J. Szymoniak, C. Moise, L. Toupet, and B. Trimaille, J. Organomet. Chem., 491, 31 (1995).
lxvS.C. Sutton, M.H. Nantz, and S.R. Parkin, Organometallics, 12, 2248 (1993).
lxviY. Wang, Shan-Sheng Xu, Xiu-Zhong Zhou, Xin-Kai Yao, and Hong-Gen Wang, Huaxue Xuebao (Acta Chim. Sinica) (Chin.) 49, 751 (1991).
lxviiTing-Yu Huang, Chi-Tain Chen, and Han-Mou Gau, J. Organomet. Chem., 489, 63 (1995).
lxviiiYanlong Qian, Jiling Huang, Xiaoping Chen, Guisheng Li, Weichun Chen, Bihua Li, Xianglin Jin, and Qingchuan Yang, Polyhedron, 13, 1105
(1994).
lxixYou-Xian Chen, Peng-Fei Fu, C.L. Stern, and T.J. Marks, Organometallics, 16, 5958 (1997).
lxxA.V. Firth and D.W. Stephan, Inorg. Chem., 37, 4732 (1998).
(continued overleaf )