2 Homometallic Alkoxides

623
[Pd(OAr)⊲C6H3fCH2NMe2g2-2,6)]
square planar Pd, ArO trans to metallated aryl ring
[Pd(OAr)⊲C6H3fCH2NMe2g2-2,6⊳](HOAr)
square planar Pd, ArO trans to metallated aryl ring,
hydrogen bonded HOAr
[Pd⊲PPh2C6H4CH2NMe2⊳(OAr)Me]
square planar Pd, ArO trans to P
[Pd⊲PPh2C6H4CH2NMe2⊳(OAr)Me](HOAr)
square planar Pd, ArO trans to P, hydrogen bonded
HOAr
cis-[Pd(OAr)Me(dmpe)]
square planar Pd
[(ArO)Pd⊲O2CCF3⊳]
square planar Pd, two molecules
[Pd(OAr) 2].3.73CH2Cl2.H2O
OAr derived from PfC6H2⊲OMe⊳3-2,4,6g3,
trans, square planar PdO2P2
OC6H5 2.12 (2) 125 viii
OC6H5 2.139 (4) 128 viii
OC6H5 2.088 (5) 123 ix
OC6H5 2.103 (2) 122 ix
OC6H5 2.098 (6) 124 x
OC6H2⊲CH2PBut 2⊳2-2,6-Me-4 1.981 (2)
1.987 (2)
(MeO) 3C6H2-P-2-OC6H2⊲OMe⊳2 2.047 (7)
2.047 (8)
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