2 Homometallic Alkoxides

547
[⊲ArO⊳2Ti⊲ 2-ButNDCC4Et4CPh2O⊳] 2-iminoacyl within metallacycle ring
[Ti(OAr) 2⊲NCPhCHPhNCH2Ph⊳]
2,5-diaza-1-titanacyclopent-2-ene
[Ti(OAr) 2fButNC⊲CH2Ph⊳DC⊲CH2Ph⊳Nxyg] xy D 2,6-xylyl folded 2,5-diazacyclopentene ring
[Ti(OAr) 2fOC⊲CH2Ph⊳DC⊲CH2Ph⊳NButg] folded 2-oxa-5-azacyclopentene ring.
[Ti(OAr) 2fPhNC⊲CH2SiMe3⊳DC⊲C⊲CH2SiMe3⊳DNPh)NPhg]
folded 2,5-diazacyclopentene ring
[fTi(OAr) 2⊲CH2CHMeCMe2⊳g2⊲ 2-O⊳]
tetrahedral Ti linked by oxo bridge
[Ti⊲OC6H3But-CMe2CH2⊳⊲OAr⊳⊲CH2SiMe3⊳⊲py⊳] tbp Ti
[Ti(OAr) 2⊲ 2-ButNDCCH2Ph⊳⊲CH2Ph⊳] mono- 2 -iminoacyl
[Ti(OAr) 2⊲ 2 -PhNDCCH2SiMe3⊳⊲CH2SiMe3⊳]
mono- 2 -iminoacyl
OC6H3Ph2-2,6 1.818 (4)
1.896 (4)
OC6H3Ph2-2,6 1.816 (2)
1.829 (2)
OC6H3Pri 2-2,6 1.845 (4)
1.790 (4)
OC6H3Pri 2-2,6 1.792 (3)
1.814 (3)
OC6H3Ph2-2,6 1.856 (7)
1.811 (7)
OC6H3Ph2-2,6 1.793 (3)
1.795 (2)
OC6H3But 2-2,6 OC6H3But-CMe2CH2 OC6H3Pr
1.850 (4)
1.810 (4)
i 2-2,6 1.816 (3)
1.811 (3)
OC6H3Pri 2-2,6 1.850 (4)
1.821 (4)
xliii J.E. Hill, P.E. Fanwick, and I.P. Rothwell, Organometallics, 9, 2211 (1990).
xliv J.E. Hill, G. Balaich, P.E. Fanwick, and I.P. Rothwell, Organometallics, 12, 2911 (1993).
xlv J.E. Hill, P.E. Fanwick, and I.P. Rothwell, Organometallics, 10, 15 (1991).
xlvi M.G. Thorn, J.E. Hill, S.A. Waratuke, E.S. Johnson, P.E. Fanwick, and I.P. Rothwell, J. Am. Chem. Soc., 119, 8630 (1997).
xlvii G.J. Balaich, P.E. Fanwick, and I.P. Rothwell, Organometallics, 13, 4117 (1994).
xlviii J.E. Hill, G.J. Balaich, P.E. Fanwick, and I.P. Rothwell, Organometallics, 10, 3428 (1991).
xlix J.E. Hill, P.E. Fanwick, and I.P. Rothwell, Organometallics, 11, 1771 (1992).
l M.G. Thorn, J.E. Hill, S.A. Waratuke, E.S. Johnson, P.E. Fanwick, and I.P. Rothwell, J. Am. Chem. Soc., 119, 8630 (1997).
li L.R. Chamberlain, L.D. Durfee, P.E. Fanwick, L.M. Kobriger, S.L. Latesky, A.K. McMullen, B.D. Steffey, I.P. Rothwell, K. Folting, and
J.C. Huffman, J. Am. Chem. Soc., 109, 6068 (1987).
lii S.L. Latesky, A.K. McMullen, I.P. Rothwell, and J.C. Huffman, J. Am. Chem. Soc., 107, 5981 (1985).
liii L.R. Chamberlain, L.D. Durfee, P.E. Fanwick, L. Kobriger, S.L. Latesky, A.K. McMullen, I.P. Rothwell, K. Folting, J.C. Huffman, W.E. Streib,
and R. Wang, J. Am. Chem. Soc., 109, 390 (1987).
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