International Summer School PROGRAM - Laboratoire d'Infochimie ...

INNOVATIVE DEVELOPMENTS ON THE BASIS OF SUPRAMOLECULAR SYSTEMS
A.Yu. Tsivadze
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences,
Leninsky Pr., 31/4, Moscow 119907 Russia, tsiv@phyche.ac.ru
Last years become more and more obvious that for developments of innovative technologies
on the basis of new classes of compounds it is necessary to reveal their features of supramolecular
organization. Many of important electrophysical, optical and sensor properties depend from
peculiarities of such organization. Supramolecular systems on a basis of metal complexes with
macrocyclic ligands possess unique physico-chemical properties allow to develop various unique
materials for the molecular electronics, alternative power industry, chemical technology, separation
of compounds, medicine. For creation of innovative technologies on the basis of the compounds it
is necessary to reveal their supramolecular organization depending on the various factors defining
important properties.
On the basis of the synthesized new classes of macrocyclic compounds are developed:
− electroluminescent materials and organic light-emitting diodes on their basis;
− photorefractive materials;
− electrocatalysts and fuel cells on their basis;
− extraction and sorption technologies for separation of isotopes and processing of radioactive
production wastes.
− organic solar cells.
Innovative problems on a way of application of the results of fundamental researches will be
discussed.