Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

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Table 7. Crystallographic Data for Complexes 18 and 22 18 22 Chapitre IV _________________________________________________________________________ Chemical formula C38H36Cl4N2Ni2P2 C14H24Cl2NNiOP Mr 841.85 382.92 Cell setting, space group Monoclinic, C2/c Monoclinic, P21/n Temperature (K) 173 (2) 173 (2) a (Å) 20.4250 (8) 8.8770 (3) b (Å) 15.5080 (7) 17.1160 (6) c (Å) 11.9040 (6) 12.0180 (5) β (°) 103.913 (2) 102.7270 (12) V (Å 3 ) 3660.0 (3) 1781.14 (11) Z 4 4 Dx (Mg m –3 ) 1.528 1.428 Radiation Mo-Kα Mo-Kα F(000) 1728 800 µ (mm –1 ) 1.44 1.47 Crystal size (mm) 0.12 × 0.03 × 0.02 0.12 × 0.10 × 0.08 No. of measured, indept 9382, 5331, 3826 7317, 4076, 3133 and obsd reflect. Criterion for obsd reflect. I > 2σ(I) I > 2σ(I) Rint 0.078 0.064 θmax (°) 30.0 27.5 data set (h; k; l) -28/28; -19/21; -16/16 -11/11; -22/20; -15/15 R[F 2 > 2σ(F 2 )], wR(F 2 ), S 0.096, 0.116, 1.21 0.083, 0.117, 1.19 No. of relections 5331 4076 No. of parameters 218 181 _________________________________________________________________________ 31
6. References (1) Ziegler, K.; Holzkamp, E.; Breil, H.; Martin, H. Angew. Chem. 1955, 67, 426. (2) Wilke, G. Angew. Chem. Int. Ed. 2003, 42, 5000-5008. (3) Bolton, P. D.; Mountford, P. Adv. Synth. Catal. 2005, 347, 355-366. (4) Böhm, L. L. Angew. Chem. Int. Ed. 2003, 42, 5010-5030. Chapitre IV (5) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428- 447. (6) Mecking, S. Angew. Chem. Int. Ed. 2001, 40, 534-540. (7) Rieger, B.; Saunders Baugh, L.; Kacker, S.; Striegler, S., Eds. Late Transition Metal Polymerization Catalysis; Wiley -VCH: Weinheim, 2003. (8) Speiser, F.; Braunstein, P.; Saussine, L. Acc. Chem. Res. 2005, 38, 784-793. (9) Bianchini, C.; Giambastiani, G.; Rios, I. G.; Mantovani, G.; Meli, A.; Segarra, A. M. Coord. Chem. Rev. 2006, 250, 1391-1418. (10) Ziegler, K.; Gellert, H. G.; Holzkamp, E.; Wilke, G. Brennst.-Chem. 1954, 35, 321. (11) Keim, W.; Behr, A.; Gruber, B.; Hoffmann, B.; Kowaldt, F. H.; Kürschner, U.; Limbäcker, B.; Sistig, F. P. Organometallics 1986, 5, 2356-2359. (12) Keim, W. Angew. Chem. Int. Ed. 1990, 29, 235-244. (13) Heinicke, J.; He, M.; Dal, A.; Klein, H. F.; Hetche, O.; Keim, W.; Flörke, U.; Haupt, H. J. Eur. J. Inorg. Chem. 2000, 431-440. (14) Heinicke, J.; Köhler, M.; Peulecke, N.; He, M.; Kindermann, M. K.; Keim, W.; Fink, G. Chem. Eur. J. 2003, 9, 6093-6107. (15) Braunstein, P.; Chauvin, Y.; Mercier, S.; Saussine, L. C. R. Chimie 2005, 8, 31-38. (16) Kuhn, P.; Semeril, D.; Jeunesse, C.; Matt, D.; Lutz, P.; Welter, R. Eur. J. Inorg. Chem. 2005, 1477-1481. (17) Malinoski, J. M.; Brookhart, M. Organometallics 2003, 22, 5324-5335. (18) Kuhn, P.; Semeril, D.; Matt, D.; Chetcuti, M. J.; Lutz, P. Dalton Trans. 2007, 515- 528. (19) Ittel, S. D.; Johnson, L. K.; Brookhart, M. Chem. Rev. 2000, 100, 1169-1203. (20) Killian, C. M.; Johnson, L. K.; Brookhart, M. Organometallics 1997, 16, 2005-2007. (21) Svejda, S. A.; Brookhart, M. Organometallics 1999, 18, 65-74. (22) Younkin, T. R.; Connor, E. F.; Henderson, J. I.; Friedrich, S. K.; Grubbs, R. H.; Bansleben, D. A. Science 2000, 287, 460-462. (23) Jenkins, J. C.; Brookhart, M. Organometallics 2003, 22, 250-256. 32
Page 1 and 2:
THESE Présentée à l’Universit
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Lisa, Mireia, Anja, Fredy, Shuanmin
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SOMMAIRE Composition du document et
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6. reference 32 Chapitre V Synthesi
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Composition du document et organisa
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Introduction La dynamique économiq
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Introduction La première étape co
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Introduction 26, 68-70 Des mécanis
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R R' P Ni Ph O B(Arf) R = R' = t-Bu
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Introduction Activés par des alkyl
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18 19 20 21 22 23 24 25 26 27 28 29
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88 89 90 91 92 93 94 95 96 97 98 99
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Chapitre I Nickel Complexes with Fu
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Abstract Chapitre I Zwitterionic N,
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R HN O 1 O NH R Ph Ph 3P Ni R N O 2
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Chapitre I As shown in Figure 1, th
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Chapitre I Figure 3. Views of the s
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Chapitre I Figure 6. View of the ar
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Chapitre I with the metal, 51-54 tw
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Chapitre I these conditions, precat
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Chapitre I The precatalyst 13-17 ha
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Chapitre I Table 5. Catalytic Data
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TOF mol C2H4 / mol Ni.h -1 20000 15
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Chapitre I (s, OCH2), 81.27 (s, N
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Chapitre I atoms introduced as fixe
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Chapitre I (51) Tempel, D. J.; Broo
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Abstract Chapitre II The dinuclear
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Chapitre II Other neutral nickel co
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OH 4 O N 4 13 OH N + 2 NiCl 2 + 2 N
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N2-Ni1-Cl1 169.45(12) 89.35(15) N2-
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Table 2. Selected bond distances an
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Chapitre II solubility of 15 in chl
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Chapitre II Table 4. Catalytic Data
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Chapitre II Table 5. Comparative Ca
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mass % of C4 olefins 100 90 80 70 6
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5. Experimental Chapitre II The 1 H
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Chapitre II a dark green powder. Yi
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Chapitre II 17 W. Keim, J. Mol. Cat
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7. Supporting information Table S1.
Page 79 and 80: Chapitre III Unprecedented Tetranuc
Page 81 and 82: Abstract Chapitre III Reactions of
Page 83 and 84: Chapitre III distorted octahedral c
Page 85 and 86: data for 2a⋅2CH2Cl2: 1.41 and for
Page 87 and 88: Chapitre III indicate that subtle d
Page 89 and 90: SUPPORTING INFORMATION FOR Chapitre
Page 91 and 92: Chapitre III by filtration. The sol
Page 93 and 94: Chapitre III 4 was prepared followi
Page 95 and 96: [S- ] 3. Evans method 2 Chapitre II
Page 97 and 98: Chapitre III Application Constructe
Page 99 and 100: Chapitre III [S-5] J. K. McCusker,
Page 101 and 102: Abstract Chapitre IV The P,N-type l
Page 103 and 104: Chapitre IV Scheme 1. Complexes wit
Page 105 and 106: 12 PPh 2 N O N PPh 2 O N 13 P 14 15
Page 107 and 108: Chapitre IV Although some nickel co
Page 109 and 110: Scheme 2. Representation of the squ
Page 111 and 112: Chapitre IV The analysis of the dif
Page 113 and 114: Chapitre IV Table 4. Catalytic Data
Page 115 and 116: mass % of 1-butene 100 90 80 70 60
Page 117 and 118: Chapitre IV Table 6. Catalytic Data
Page 119 and 120: ef Scheme 3. Proposed pathways to e
Page 121 and 122: 4. Conclusion Chapitre IV New P,N l
Page 123 and 124: Chapitre IV SiCH3), 30.25 (s, SiCH2
Page 125 and 126: Chapitre IV 122.3 (s, Py), 122.5 (d
Page 127 and 128: [Ni(µ-Cl)2{(pyridin-2-yl) methanol
Page 129: Chapitre IV mmol of Ni complex or 1
Page 133 and 134: Chapitre IV (44) Bluhm, M. E.; Foll
Page 135 and 136: Chapitre V Synthesis and catalytic
Page 137 and 138: Chapitre V to 16, the IR spectrum o
Page 139 and 140: Chapitre V activated by MAO (Scheme
Page 141 and 142: 2 OH N + PPhCl 2 NEt 3 - (HNEt 3)Cl
Page 143 and 144: Chapitre V Slow diffusion of heptan
Page 145 and 146: Chapitre V Figure 3. ORTEP view of
Page 147 and 148: Chapitre V tridentate ligand but wi
Page 149 and 150: Chapitre V spin system 1) and 3.06
Page 151 and 152: Chapitre V This establishes the coo
Page 153 and 154: TOF (mol C2H4/(mol Ni.h)) 90000 800
Page 155 and 156: % mass of 1-butene 80 70 60 50 40 3
Page 157 and 158: Chapitre V cyclic voltammograms of
Page 159 and 160: Chapitre V A n-BuLi solution (64.0
Page 161 and 162: Chapitre V IR (KBr): 1658 (vs), 147
Page 163 and 164: Chapitre V To a solution of (2-oxaz
Page 165 and 166: Chapitre V Synthesis of [Co{bis(1-(
Page 167 and 168: Chapitre V 30 bar working pressure
Page 169 and 170: 6. References 1 2 3 4 5 6 7 8 9 10
Page 171 and 172: 67 68 69 70 71 72 73 74 75 76 77 78
Page 173 and 174: Abstract Chapitre VI The β-keto ph
Page 175 and 176: Ph O 3 toluene PPh3 + Ni(COD) 2 + P
Page 177 and 178: Chapitre VI The synthesis of β-ket
Page 179 and 180: Table 1 Selected bond distances (Å
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Ph O toluene PR2R' + Ni(COD) 2 + C5
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4. Conclusion Chapitre VI The β-ke
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Chapitre VI and the solution was st
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Chapitre VI (s, p-C of OC-Ph), 131.
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Chapitre VI To a solution of 13.000
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Chapitre VI the solvents under redu
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Chapitre VI Crystal Structure Deter
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23 F. A. Hicks and M. Brookhart, Or
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Chapitre VII Réarrangement type Ar
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1. Introduction Chapitre VII Brookh
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N OPPh 2 OPPh 2 + NiCl2(DME) N O Ph
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Chapitre VII mécanisme apparenté
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[Ni{2,6-bis((diphenylphosphinito)me
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Résumé et Conclusion générale
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Chapitre II Résumé et conclusion
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Résumé et conclusion générale P
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Résumé et conclusion générale l
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Chapitre VII Résumé et conclusion
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Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

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