Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

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Chapitre I (19) Zhang, D.; Jin, G.-X.; Hu, N.-H. Eur. J. Inorg. Chem. 2003, 1570-1576. (20) Li, X.-F.; Li, Y.-S. J. Polym. Sci., A 2002, 40, 2680-2685. (21) Pickel, M.; Casper, T.; Rahm, A.; Dambouwy, C.; Chen, P. Helv. Chim. Acta 2002, 85, 4337-4352. (22) Novak, B. M.; Tian, G.; Nodono, M.; Boyle, P. Polym. Mat. Sci. Eng. 2002, 86, 326-327. (23) Younkin, T. R.; Connor, E. F.; Henderson, J. I.; Friedrich, S. K.; Grubbs, R. H.; Bansleben, D. A. Science 2000, 287, 460-462. (24) Younkin, T. R.; Connor, E. F.; Henderson, J. I.; Friedrich, S. K.; Grubbs, R. H.; Bansleben, D. A. Science 2000, 288, 1750-1751. (25) Wang, C.; Friedrich, S.; Younkin, T. R.; Li, R. T.; Grubbs, R. H.; Bansleben, D. A.; Day, M. W. Organometallics 1998, 17, 3149-3151. (26) Jenkins, J. C.; Brookhart, M. Organometallics 2003, 22, 250-256. (27) Hicks, F. A.; Jenkins, J. C.; Brookhart, M. Organometallics 2003, 22, 3533- 3545. (28) Brookhart, M.; Jenkins, J. C.; Zhang, L. Abstracts of Papers, 227th ACS National Meeting, Anaheim, CA, United States, March 28-April 1, 2004 2004, POLY-325. (29) Sun, W.-H.; Zhang, W.; Gao, T.; Tang, X.; Chen, L.; Li, Y.; Jin, X. J. Organomet. Chem. 2004, 689, 917-929. (30) Wang, L.; Sun, W.-H.; Han, L.; Yang, H.; Hu, Y.; Jin, X. J. Organomet. Chem. 2002, 658, 62-70. (31) Qian, Y.; Zhao, W.; Huang, J. Inorg. Chem. Commun. 2004, 7, 459-461. (32) Chen, Y.; Wu, G.; Bazan, G. C. Angew. Chem., Int. Ed. 2005, 44, 1108-1112. (33) Kim, I.; Kwak, C. H.; Kim, J. S.; Ha, C.-S. Appl. Catal., A 2005, 287, 98-107. (34) Speiser, F.; Braunstein, P.; Saussine, L. Inorg. Chem. 2004, 43, 4234-4240. (35) Richeter, S.; Jeandon, C.; Ruppert, R.; Callot, H. J. Chem. Commun. 2001, 91- 92. (36) Richeter, S.; Jeandon, C.; Gisselbrecht, J.-P.; Ruppert, R.; Callot, H. J. J. Am. Chem. Soc. 2002, 124, 6168-6179. (37) Moriuchi, T.; Watanabe, T.; Ikeda, I.; Ogawa, A.; Hirao, T. Eur. J. Inorg. Chem. 2001, 277-287. (38) Elduque, A.; Aguilera, F.; Lahoz, F. J.; Lopez, J. A.; Oro, L. A.; Pinillos, M. T. Inorg. Chim. Acta 1998, 274, 15-23. (39) Kühlwein, F.; Polborn, K.; Beck, W. Z. Anorg. Allg. Chem. 1997, 623, 1931- 1944. (40) Zhang, D.; Jin, G.-X. Organometallics 2003, 22, 2851-2854. (41) Braunstein, P.; Siri, O.; Taquet, J.-p.; Rohmer, M.-M.; Bénard, M.; Welter, R. J. Am. Chem. Soc. 2003, 125, 12246-12256. (42) Taquet, J.-p.; Siri, O.; Braunstein, P.; Welter, R. Inorg. Chem. 2004, 43, 6944- 6953. (43) Braunstein, P.; Naud, F. Angew. Chem., Int. Ed. 2001, 40, 680-699. (44) Rieger, B.; Saunders Baugh, L.; Kacker, S.; Striegler, S., Eds. Late Transition Metal Polymerization Catalysis; Wiley -VCH: Weinheim, 2003. (45) Yang, Q.-Z.; Siri, O.; Braunstein, P. Chem. Eur. J. 2005, 11, 7237-7246. (46) Yang, Q.-Z.; Siri, O.; Braunstein, P. Chem.Commun. 2005, 2660-2662. (47) Holleman, A. F.; Wiberg, E. Holleman-Wiberg Lehrbuch der Anorganischen Chemie, 91.-100. Auflage, Walter de Gruyter, Berlin 1985, 1152-1156. (48) Siri, O.; Braunstein, P. Chem. Commun. 2002, 208-209. (49) Knudsen, R. D. Prep.-Am. Chem. Soc., Div. Petrol. Chem. 1989, 572-576. (50) Commereuc, D.; Chauvin, Y.; Leger, G.; Gaillard, J. Rev. Inst. Fr. Pét. 1982, 37, 639-649. 26
Chapitre I (51) Tempel, D. J.; Brookhart, M. Organometallics 1998, 17, 2290-2296. (52) Svejda, S. A.; Brookhart, M. Organometallics 1999, 18, 65-74. (53) Gottfried, A. C.; Brookhart, M. Macromolecules 2003, 36, 3085-3100. (54) Zhao, W.; Qian, Y.; Huang, J.; Duan, J. J. Organometal. Chem. 2004, 689, 2614-2623. (55) Zhang, J.; Gao, H.; Ke, Z.; Bao, F.; Zhu, F.; Wu, Q. J. Mol. Catal. A: Chem. 2005, 231, 27-34. (56) Kappa CCD Operation Manual; Nonius BV, Delft, The Nederlands, 1997. (57) Sheldrick, G. M.: SHELXL97, Program for the refinement of crystal structures, University of Göttingen, Germany, 1997. 27
Page 1 and 2: THESE Présentée à l’Universit
Page 3 and 4: Lisa, Mireia, Anja, Fredy, Shuanmin
Page 5 and 6: SOMMAIRE Composition du document et
Page 7 and 8: 6. reference 32 Chapitre V Synthesi
Page 9 and 10: Composition du document et organisa
Page 11 and 12: Introduction La dynamique économiq
Page 13 and 14: Introduction La première étape co
Page 15 and 16: Introduction 26, 68-70 Des mécanis
Page 17 and 18: R R' P Ni Ph O B(Arf) R = R' = t-Bu
Page 19 and 20: Introduction Activés par des alkyl
Page 21 and 22: 18 19 20 21 22 23 24 25 26 27 28 29
Page 23 and 24: 88 89 90 91 92 93 94 95 96 97 98 99
Page 25 and 26: Chapitre I Nickel Complexes with Fu
Page 27 and 28: Abstract Chapitre I Zwitterionic N,
Page 29 and 30: R HN O 1 O NH R Ph Ph 3P Ni R N O 2
Page 31 and 32: Chapitre I As shown in Figure 1, th
Page 33 and 34: Chapitre I Figure 3. Views of the s
Page 35 and 36: Chapitre I Figure 6. View of the ar
Page 37 and 38: Chapitre I with the metal, 51-54 tw
Page 39 and 40: Chapitre I these conditions, precat
Page 41 and 42: Chapitre I The precatalyst 13-17 ha
Page 43 and 44: Chapitre I Table 5. Catalytic Data
Page 45 and 46: TOF mol C2H4 / mol Ni.h -1 20000 15
Page 47 and 48: Chapitre I (s, OCH2), 81.27 (s, N
Page 49: Chapitre I atoms introduced as fixe
Page 53 and 54: Abstract Chapitre II The dinuclear
Page 55 and 56: Chapitre II Other neutral nickel co
Page 57 and 58: OH 4 O N 4 13 OH N + 2 NiCl 2 + 2 N
Page 59 and 60: N2-Ni1-Cl1 169.45(12) 89.35(15) N2-
Page 61 and 62: Table 2. Selected bond distances an
Page 63 and 64: Chapitre II solubility of 15 in chl
Page 65 and 66: Chapitre II Table 4. Catalytic Data
Page 67 and 68: Chapitre II Table 5. Comparative Ca
Page 69 and 70: mass % of C4 olefins 100 90 80 70 6
Page 71 and 72: 5. Experimental Chapitre II The 1 H
Page 73 and 74: Chapitre II a dark green powder. Yi
Page 75 and 76: Chapitre II 17 W. Keim, J. Mol. Cat
Page 77 and 78: 7. Supporting information Table S1.
Page 79 and 80: Chapitre III Unprecedented Tetranuc
Page 81 and 82: Abstract Chapitre III Reactions of
Page 83 and 84: Chapitre III distorted octahedral c
Page 85 and 86: data for 2a⋅2CH2Cl2: 1.41 and for
Page 87 and 88: Chapitre III indicate that subtle d
Page 89 and 90: SUPPORTING INFORMATION FOR Chapitre
Page 91 and 92: Chapitre III by filtration. The sol
Page 93 and 94: Chapitre III 4 was prepared followi
Page 95 and 96: [S- ] 3. Evans method 2 Chapitre II
Page 97 and 98: Chapitre III Application Constructe
Page 99 and 100: Chapitre III [S-5] J. K. McCusker,
Page 101 and 102:
Abstract Chapitre IV The P,N-type l
Page 103 and 104:
Chapitre IV Scheme 1. Complexes wit
Page 105 and 106:
12 PPh 2 N O N PPh 2 O N 13 P 14 15
Page 107 and 108:
Chapitre IV Although some nickel co
Page 109 and 110:
Scheme 2. Representation of the squ
Page 111 and 112:
Chapitre IV The analysis of the dif
Page 113 and 114:
Chapitre IV Table 4. Catalytic Data
Page 115 and 116:
mass % of 1-butene 100 90 80 70 60
Page 117 and 118:
Chapitre IV Table 6. Catalytic Data
Page 119 and 120:
ef Scheme 3. Proposed pathways to e
Page 121 and 122:
4. Conclusion Chapitre IV New P,N l
Page 123 and 124:
Chapitre IV SiCH3), 30.25 (s, SiCH2
Page 125 and 126:
Chapitre IV 122.3 (s, Py), 122.5 (d
Page 127 and 128:
[Ni(µ-Cl)2{(pyridin-2-yl) methanol
Page 129 and 130:
Chapitre IV mmol of Ni complex or 1
Page 131 and 132:
6. References (1) Ziegler, K.; Holz
Page 133 and 134:
Chapitre IV (44) Bluhm, M. E.; Foll
Page 135 and 136:
Chapitre V Synthesis and catalytic
Page 137 and 138:
Chapitre V to 16, the IR spectrum o
Page 139 and 140:
Chapitre V activated by MAO (Scheme
Page 141 and 142:
2 OH N + PPhCl 2 NEt 3 - (HNEt 3)Cl
Page 143 and 144:
Chapitre V Slow diffusion of heptan
Page 145 and 146:
Chapitre V Figure 3. ORTEP view of
Page 147 and 148:
Chapitre V tridentate ligand but wi
Page 149 and 150:
Chapitre V spin system 1) and 3.06
Page 151 and 152:
Chapitre V This establishes the coo
Page 153 and 154:
TOF (mol C2H4/(mol Ni.h)) 90000 800
Page 155 and 156:
% mass of 1-butene 80 70 60 50 40 3
Page 157 and 158:
Chapitre V cyclic voltammograms of
Page 159 and 160:
Chapitre V A n-BuLi solution (64.0
Page 161 and 162:
Chapitre V IR (KBr): 1658 (vs), 147
Page 163 and 164:
Chapitre V To a solution of (2-oxaz
Page 165 and 166:
Chapitre V Synthesis of [Co{bis(1-(
Page 167 and 168:
Chapitre V 30 bar working pressure
Page 169 and 170:
6. References 1 2 3 4 5 6 7 8 9 10
Page 171 and 172:
67 68 69 70 71 72 73 74 75 76 77 78
Page 173 and 174:
Abstract Chapitre VI The β-keto ph
Page 175 and 176:
Ph O 3 toluene PPh3 + Ni(COD) 2 + P
Page 177 and 178:
Chapitre VI The synthesis of β-ket
Page 179 and 180:
Table 1 Selected bond distances (Å
Page 181 and 182:
Ph O toluene PR2R' + Ni(COD) 2 + C5
Page 183 and 184:
4. Conclusion Chapitre VI The β-ke
Page 185 and 186:
Chapitre VI and the solution was st
Page 187 and 188:
Chapitre VI (s, p-C of OC-Ph), 131.
Page 189 and 190:
Chapitre VI To a solution of 13.000
Page 191 and 192:
Chapitre VI the solvents under redu
Page 193 and 194:
Chapitre VI Crystal Structure Deter
Page 195 and 196:
23 F. A. Hicks and M. Brookhart, Or
Page 197 and 198:
Chapitre VII Réarrangement type Ar
Page 199 and 200:
1. Introduction Chapitre VII Brookh
Page 201 and 202:
N OPPh 2 OPPh 2 + NiCl2(DME) N O Ph
Page 203 and 204:
Chapitre VII mécanisme apparenté
Page 205 and 206:
[Ni{2,6-bis((diphenylphosphinito)me
Page 207 and 208:
Résumé et Conclusion générale
Page 209 and 210:
Chapitre II Résumé et conclusion
Page 211 and 212:
Résumé et conclusion générale P
Page 213 and 214:
Résumé et conclusion générale l
Page 215 and 216:
Chapitre VII Résumé et conclusion
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Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

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