21.02.2013 Views

Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

6. reference 32<br />

Chapitre V<br />

Synthesis and catalytic studies in the oligomerization of ethylene of Ni(II), Fe(II),<br />

Pd(II) and Co(II) complexes coordinated by new N,P,N Type ligands<br />

1. Introduction 4<br />

2. Results and discussion 6<br />

2.1 Synthesis of the ligands 6<br />

2.2 Synthesis of nickel complexes 7<br />

2.3 Synthesis of the iron complexes 8<br />

2.4 Synthesis of the palladium complexes 14<br />

2.5 Synthesis of the cobalt complexes 15<br />

3. Catalytic oligomerization of ethylene 17<br />

4. Conclusion 22<br />

5. Experimental section 23<br />

6. References 35<br />

Chapitre VI<br />

SHOP-type nickel complexes with alkyl substituents on phosphorus, synthesis<br />

and catalytic ethylene oligomerization<br />

1. Introduction 3<br />

2. Results and discussion 5<br />

2.1 Synthesis of the ylides 5<br />

2.2 Synthesis of the Complexes 6<br />

3. Catalytic oligomerization of ethylene 10<br />

4. Conclusion 12<br />

5. Experimental section 13<br />

6. Reference 23<br />

Chapitre VII<br />

Réarrangement type Arbuzov observé sur un complexe de fer coordiné par des<br />

ligands bis(oxyde-phosphine)pyridine<br />

1. Introduction 3<br />

2. Résultats et discussion 4

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!