Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

SOMMAIRE
Composition du document et organisation de la bibliographie 1
INTRODUCTION GENERALE 2
Références 12
Chapitre I
Nickel Complexes with Functional Zwitterionic N,O-Benzoquinonemonoimine-
type Ligands: Synthesis, Structures and Catalytic Oligomerization of Ethylene
1. Introduction 4
2. Results and discussion 5
3. Catalytic Oligomerization of ethylene 12
(i) Influence of the donor function in the arm 14
(ii) Influence of the ligand coordinating arm 15
(iii) Influence of the coordination geometry of the metal 15
(iv) Influence of the Cocatalyst 16
(v) Lifetime of the Catalyst 16
4. Conclusion 16
5. Experimental section 22
6. References 25
Chapitre II
Synthesis of Nickel Complexes with Bidentate N,O Type ligands and Application
in the Catalytic Oligomerization of Ethylene
1. Introduction 3
2. Results and discussion 5
3. Catalytic Oligomerization of ethylene 11
3.1 Use of AlEtCl2 as cocatalyst 11
3.2 Use of MAO as cocatalyst 15
4. Conclusion 19