Chapitre IV (24) Sun, W.-H.; Tang, X.; Gao, T.; Wu, B.; Zhang, W.; Ma, H. Organometallics 2004, 23, 5037-5047. (25) Chen, Y.; Wu, G.; Bazan, G. C. Angew. Chem., Int. Ed. 2005, 44, 1108-1112. (26) Speiser, F.; Braunstein, P.; Saussine, L. Inorg. Chem. 2004, 43, 4234-4240. (27) Yang, Q.-Z.; Kermagoret, A.; Agostinho, M.; Siri, O.; Braunstein, P. Organometallics 2006, 25, 5518-5527. (28) Albers, I.; Alvarez, E.; Campora, J.; Maya, C. M.; Palma, P.; Sanchez, L. J.; Passaglia, E. J. Organomet. Chem. 2004, 689, 833-839. (29) van den Beuken, E. K.; Smeets, W. J. J.; Spek, A. L.; Feringa, B. L. Chem. Commun. 1998, 223-224. (30) Guan, Z.; Marshall, W. J. Organometallics 2002, 21, 3580-3586. (31) Bonnet, M. C.; Dahan, F.; Ecke, A.; Keim, W.; Schulz, R. P.; Tkatchenko, I. Chem. Commun. 1994, 615-616. (32) Rachita, M. J.; Huff, R. L.; Bennett, J. L.; Brookhart, M. J. Polym. Sci. Part A: Polym. Chem. 2000, 38, 4627-4640. (33) Daugulis, O.; Brookhart, M.; White, P. S. Organometallics 2002, 21, 5935-5943. (34) Speiser, F.; Braunstein, P.; Saussine, L.; Welter, R. Organometallics 2004, 23, 2613- 2624. (35) Tang, X.; Zhang, D.; Jie, S.; Sun, W.-H.; Chen, J. J. Organomet. Chem. 2005, 690, 3918-3928. (36) Mukherjee, A.; Subramanyam, U.; Puranik, V. G.; Mohandas, T. P.; Sarkar, A. Eur. J. Inorg. Chem. 2005, 1254-1263. (37) Braunstein, P.; Pietsch, J.; Chauvin, Y.; Mercier, S.; Saussine, L.; DeCian, A.; Fischer, J. J. Chem. Soc., Dalton Trans. 1996, 3571-3574. (38) Newkome, G. R. Chem. Rev. 1993, 93, 2067-2089. (39) Zhang, Z.-Z.; Cheng, H. Coord. Chem. Rev. 1996, 147, 1-39. (40) Espinet, P.; Soulantica, K. Coord. Chem. Rev. 1999, 193-195, 499-556. (41) Aucott, S. M.; Clarke, M. L.; Slawin, A. M. Z.; Woollins, J. D. J. Chem. Soc., Dalton Trans. 2001, 972-976. (42) Sun, W.-H.; Li, Z.; Hu, H.; Wu, B.; Yang, H.; Zhu, N.; Leng, X.; Wang, H. New J. Chem. 2002, 26, 1474-1478. (43) Chen, H.-P.; Liu, Y.-H.; Peng, S.-M.; Liu, S.-T. Organometallics 2003, 22, 4893- 4899. 33
Chapitre IV (44) Bluhm, M. E.; Folli, C.; Walter, O.; Döring, M. J. Mol. Catal. A: Chem. 2005, 229, 177-181. (45) Sirbu, D.; Consiglio, G.; Gischig, S. J. Organomet. Chem. 2006, 691, 1143-1150. (46) de Souza, R. F.; Bernardo-Gusmao, K.; Cunha, G. A.; Loup, C.; Leca, F.; Réau, R. J. Catal. 2004, 226, 235-239. (47) Speiser, F.; Braunstein, P.; Saussine, L. Dalton Trans. 2004, 1539-1545. (48) Speiser, F.; Braunstein, P.; Saussine, L. Organometallics 2004, 23, 2633-2640. (49) Speiser, F.; Braunstein, P.; Saussine, L. Organometallics 2004, 23, 2625-2632. (50) Speiser, F.; Braunstein, P.; Saussine, L.; Welter, R. Inorg. Chem. 2004, 43, 1649- 1658. (51) Tolman, C. A. Chem. Rev. 1977, 77, 313-348. (52) Braunstein, P.; Heaton, B. T.; Jacob, C.; Manzi, L.; Morise, X. Dalton Trans. 2003, 1396-1401. (53) Eisch, J. J.; Kovacs, C. A.; Chobe, P.; Boleslawski, M. P. J. Org. Chem. 1987, 52, 4427-4437. (54) Costella, L.; Del Zotto, A.; Mezzetti, A.; Zangrando, E.; Rigo, P. J. Chem. Soc., Dalton Trans. 1993, 3001-3008. (55) Cobas, J. C.; Sardina, F. J. Concepts Magn. Reson. 2003, 19A, 80-96. (56) Van Haaren, R. J.; Druijven, C. J. M.; Van Strijdonck, G. P. F.; Oevering, H.; Reek, J. N. H.; Kamer, P. C. J.; Van Leeuwen, P. W. N. M. J. Chem. Soc. Dalton Trans. 2000, 1549-1554. (57) Uhlig, E.; Maaser, M. Z. Anorg. Allg. Chem. 1966, 344, 205-213. (58) Buckler, S. A. J. Am. Chem. Soc. 1962, 84, 3093-3097. (59) To be published. (60) Jalil, M. A.; Fujinami, S.; Senda, H.; Nishikawa, H. J. Chem. Soc., Dalton Trans. 1999, 1655-1661. (61) Evans, D. F. J. Chem. Soc. (A) 1959, 2003-2005. (62) Deutsch, J. L.; Poling, S. M. J. Chem. Ed. 1969, 46, 167-168. (63) Löliger, J.; Scheffold, R. J. Chem. Ed. 1972, 49, 646-647. (64) Sur, S. K. J. Magn. Res. 1989, 82, 169-173. (65) Venanzi, L. M. J. Chem. Soc. (A) 1958, 719-724. (66) Hayter, R. G.; Humiec, F. S. Inorg. Chem. 1965, 4, 1701-1706. (67) Kermagoret, A.; Pattacini, R.; Vasquez, P. C.; Rogez, G.; Welter, R.; Braunstein, P. Angew. Chem. Int. Ed. 2007, 46, in press. 34
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THESE Présentée à l’Universit
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Lisa, Mireia, Anja, Fredy, Shuanmin
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SOMMAIRE Composition du document et
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6. reference 32 Chapitre V Synthesi
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Composition du document et organisa
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Introduction La dynamique économiq
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Introduction La première étape co
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Introduction 26, 68-70 Des mécanis
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R R' P Ni Ph O B(Arf) R = R' = t-Bu
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Introduction Activés par des alkyl
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18 19 20 21 22 23 24 25 26 27 28 29
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88 89 90 91 92 93 94 95 96 97 98 99
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Chapitre I Nickel Complexes with Fu
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Abstract Chapitre I Zwitterionic N,
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R HN O 1 O NH R Ph Ph 3P Ni R N O 2
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Chapitre I As shown in Figure 1, th
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Chapitre I Figure 3. Views of the s
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Chapitre I Figure 6. View of the ar
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Chapitre I with the metal, 51-54 tw
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Chapitre I these conditions, precat
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Chapitre I The precatalyst 13-17 ha
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Chapitre I Table 5. Catalytic Data
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TOF mol C2H4 / mol Ni.h -1 20000 15
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Chapitre I (s, OCH2), 81.27 (s, N
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Chapitre I atoms introduced as fixe
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Chapitre I (51) Tempel, D. J.; Broo
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Abstract Chapitre II The dinuclear
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Chapitre II Other neutral nickel co
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OH 4 O N 4 13 OH N + 2 NiCl 2 + 2 N
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N2-Ni1-Cl1 169.45(12) 89.35(15) N2-
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Table 2. Selected bond distances an
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Chapitre II solubility of 15 in chl
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Chapitre II Table 4. Catalytic Data
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Chapitre II Table 5. Comparative Ca
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mass % of C4 olefins 100 90 80 70 6
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5. Experimental Chapitre II The 1 H
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Chapitre II a dark green powder. Yi
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Chapitre II 17 W. Keim, J. Mol. Cat
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7. Supporting information Table S1.
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Chapitre III Unprecedented Tetranuc
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- Page 101 and 102: Abstract Chapitre IV The P,N-type l
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- Page 111 and 112: Chapitre IV The analysis of the dif
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4. Conclusion Chapitre VI The β-ke
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Chapitre VI and the solution was st
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Chapitre VI (s, p-C of OC-Ph), 131.
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Chapitre VI To a solution of 13.000
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Chapitre VI the solvents under redu
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Chapitre VI Crystal Structure Deter
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23 F. A. Hicks and M. Brookhart, Or
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Chapitre VII Réarrangement type Ar
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1. Introduction Chapitre VII Brookh
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N OPPh 2 OPPh 2 + NiCl2(DME) N O Ph
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Chapitre VII mécanisme apparenté
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[Ni{2,6-bis((diphenylphosphinito)me
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Résumé et Conclusion générale
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Chapitre II Résumé et conclusion
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Résumé et conclusion générale P
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Résumé et conclusion générale l
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Chapitre VII Résumé et conclusion