Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

Chapitre V
Figure 2. ORTEP view of the structure of 11 in 11·4MeCN with thermal ellipsoids drawn at
the 50% probability level, symmetry operator for the generation equivalent position: -x, y, -z
+1/2 (′) and –x + 1, y, -z + 1/2 (′′).
Table 2. Selected bond distances and bond angles of 11
Bond distances (Å)
Fe1-P 2.1842(6) C7-P 1.841(2)
Fe1-N1 2.0416(16) P-C11 1.836(2)
Fe1-N2 1.989(2) C11-C12 1.474(3)
N1-C8 1.276(3) C12-N2 1.274(3)
C8-C7 1.486(3) Fe2-O3 1.7600(5)
Bond angles (°)
P-Fe1-N1 82.95(5) N1-Fe1-P′ 170.61(5)
P-Fe1-N1′ 170.61(5) N2-Fe1-N1′ 88.44(7)
P-Fe1-N2 82.40(5) N2-Fe1-N2′ 170.03(7)
P-Fe1-N2′ 98.25(5) N2-Fe1-P′ 98.25(5)
P-Fe1-P′ 96.26(2) N1′-Fe1-N2′ 90.93(7)
N1-Fe1-N1′ 99.33(6) N1′-Fe1-P′ 82.95(5)
N1-Fe1-N2 88.44(7) N2′-Fe1-P′ 82.40(5)
N1-Fe1-N2′ 90.93(7) Fe2-O3-Fe2′′ 162.00(16)
10