Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS
Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS
Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS
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Chapitre II<br />
Table 6. Catalytic Data and Distribution of the C6 oligomers for Complexes 13, 14 and 20 in<br />
the Oligomerization of Ethylene with MAO as Cocatalyst a<br />
Quantity of<br />
Complex<br />
(10<br />
Selectivity (mass %)<br />
-5 mol)<br />
MAO<br />
(equiv) 1-hexene<br />
2- and<br />
3-hexene c<br />
C6 from<br />
1-butene d<br />
13 1.05 50 13 60 12 15<br />
C6 from<br />
2-butene e<br />
13 1.05 100 7 56 12 25<br />
13 1.05 200 7 54 12 27<br />
13 e<br />
1.05 200 11 63 13 14<br />
14 4 50 15 59 13 13<br />
14 4 100 5 53 12 30<br />
14 4 200 4 53 12 31<br />
14 1.05 50 16 59 13 12<br />
14 1.05 100 8 58 12 22<br />
14 1.05 200 6 54 12 28<br />
14 e<br />
1.05 200 9 58 12 21<br />
20 1.05 50 17 58 12 13<br />
20 1.05 100 10 58 12 20<br />
20 1.05 200 8 60 12 20<br />
a Conditions: T = 25-30 °C, 10 bar C2H4, 35 min. b Sum of 2-cis-hexene, 2-trans-hexene, 3-cis-hexene and 3trans-hexene.<br />
c Corresponding to 2-ethyl-1-butene. d Sum of 3-methyl-1-pentene, 3-methyl-2-cis-pentene and 3methyl-2-trans-pentene.<br />
e presure 30 bar<br />
14<br />
15<br />
20 50<br />
100<br />
200<br />
40000<br />
35000<br />
30000<br />
25000<br />
20000<br />
15000<br />
10000<br />
5000<br />
0<br />
equiv of MAO<br />
TOF<br />
mol C2H4 / (mol Ni.h)<br />
Fig. 6 Catalytic activities of the complexes 14, 15 and 20 (quantity of complex: 1.05·10 -2<br />
mmol) in the oligomerization of ethylene using MAO as cocatalyst.<br />
17