Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

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Crystal data 10 11 12 16 Chemical formula C36H34FeN4P2.0.5(CH2Cl2).Fe2OCl6 C28H34FeN4O5P2.4(C2H3N).Fe2Cl6O C18H25Cl2FeN2O2P C22H33Cl2CoN2O4P.0.5(C7H8) Mr 1023.33 1113.00 459.12 596.37 Cell setting, space Orthorhombic, Pccn Monoclinic, C2/c Monoclinic, P21/c Triclinic, P-1 group Temperature (K) 173 (2) 173 (2) 173 (2) 173 (2) 12.7240 (13), 12.3190 (15), 15.5250 (19) 9.1010 (4), 9.1930 (4), 17.5460 (9) 15.3270 (7), 21.8930 (12), 15.4880 (9) a, b, c (Å) 12.6010 (3), 16.6710 (5), 20.3170 (6) α, β, γ (°) 90.00, 110.368 (2), 90.00 90.00, 113.772 (5), 90.00 79.9750 (15), 84.2710 (15), 83.173 (3) V (Å 3 ) 4268.0 (2) 4872.1 (4) 2227.0 (4) 1430.62 (11) Z 4 4 4 2 Dx (Mg m –3 ) 1.593 1.517 1.369 1.384 Radiation type Mo Kα Mo Kα Mo Kα Mo Kα µ (mm –1 ) 1.55 1.32 1.00 0.88 Crystal form, Prism, orange Prism, red Prism, colorless Prism, blue colour Crystal size (mm) 0.12 × 0.10 × 0.10 0.14 × 0.12 × 0.10 0.16 × 0.14 × 0.10 0.14 × 0.12 × 0.08 F(000) 2068 2272 952 624 No. of measured, 9257, 12328, 10818, 10153, independent and 4894, 7114, 6465, 6620, observed 3202 5370 4953 4065 reflections Rint 0.070 0.033 0.029 0.044 θmax (°) 27.5 30.0 30.1 27.8 R[F 2 > 2σ(F 2 )], wR(F 2 0.088, 0.168, 1.15 0.050, 0.090, 1.06 0.057, 0.162, 1.08 0.061, 0.180, 1.01 ), S No. of relections 4894 reflections 7114 reflections 6465 reflections 6620 reflections No. of parameters 247 272 235 302 H-atom treatment Constrained to parent site Constrained to parent site Constrained to parent site Constrained to parent site
6. References 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 K. Ziegler, E. Holzkamp, H. Breil, and H. Martin, Angew. Chem., 1955, 67, 426. G. Natta, Angew. Chem., 1956, 68, 393. G. Wilke, Angew. Chem. Int. Ed., 2003, 42, 5000. J. Skupinska, Chem. Rev., 1991, 91, 613. G. J. P. Britovsek, V. C. Gibson, and D. F. Wass, Angew. Chem., Int. Ed., 1999, 38, 428. S. D. Ittel, L. K. Johnson, and M. Brookhart, Chem. Rev., 2000, 100, 1169. S. Mecking, Angew. Chem. Int. Ed., 2001, 40, 534. B. Rieger, L. Saunders Baugh, S. Kacker, and S. Striegler, in 'Late Transition Metal Polymerization Catalysis', Weinheim, 2003. P. D. Bolton and P. Mountford, Adv. Synth. Catal., 2005, 347, 355. R. Kempe, Chem. Eur. J., 2007, 13, 2764. W. Keim, A. Behr, B. Gruber, B. Hoffmann, F. H. Kowaldt, U. Kürschner, B. Limbäcker, and F. P. Sistig, Organometallics, 1986, 5, 2356. W. Keim, Angew. Chem. Int. Ed., 1990, 29, 235. L. K. Johnson, C. M. Killian, and M. Brookhart, J. Am. Chem. Soc., 1995, 117, 6414. C. M. Killian, D. J. Tempel, L. K. Johnson, and M. Brookhart, J. Am. Chem. Soc., 1996, 118, 11664. L. Deng, T. K. Woo, L. Cavallo, P. M. Margl, and T. Ziegler, J. Am. Chem. Soc., 1997, 119, 6177. D. P. Gates, S. A. Svejda, E. Onate, C. M. Killian, L. K. Johnson, P. S. White, and M. Brookhart, Macromolecules, 2000, 33, 2320. V. C. Gibson and S. K. Spitzmesser, Chem. Rev., 2003, 103, 283. C. M. Killian, L. K. Johnson, and M. Brookhart, Organometallics, 1997, 16, 2005. S. A. Svejda and M. Brookhart, Organometallics, 1999, 18, 65. F. Speiser, P. Braunstein, and L. Saussine, Acc. Chem. Res., 2005, 38, 784. G. J. P. Britovsek, V. C. Gibson, B. S. Kimberley, P. J. Maddox, S. J. McTavish, G. A. Solan, A. J. P. White, and D. J. Williams, Chem. Commun., 1998, 849. B. L. Small, M. Brookhart, and A. M. A. Bennett, J. Am. Chem. Soc., 1998, 120, 4049. G. J. P. Britovsek, M. Bruce, V. C. Gibson, B. S. Kimberley, P. J. Maddox, S. Mastroianni, S. J. McTavish, C. Redshaw, G. A. Solan, S. Strömberg, A. J. P. White, and D. J. Williams, J. Am. Chem. Soc., 1999, 121, 8728. G. J. P. Britovsek, V. C. Gibson, S. K. Spitzmesser, K. P. Tellmann, A. J. P. White, and D. J. Williams, J. Chem. Soc. Dalton Trans., 2002, 1159. T. M. Smit, A. K. Tomov, V. C. Gibson, A. J. P. White, and D. J. Williams, Inorg. Chem., 2004, 43, 6511. B. L. Small and M. Brookhart, J. Am. Chem. Soc., 1998, 120, 7143. G. J. P. Britovsek, S. Mastroianni, G. A. Solan, S. P. D. Baugh, C. Redshaw, V. C. Gibson, A. J. P. White, D. J. Williams, and M. R. J. Elsegood, Chem. Eur. J., 2000, 6, 2221. G. J. P. Britovsek, V. C. Gibson, B. S. Kimberley, S. Mastroianni, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 2001, 1639. K. P. Tellmann, V. C. Gibson, A. J. P. White, and D. J. Williams, Organometallics, 2005, 24, 280. G. J. P. Britovsek, S. P. D. Baugh, O. Hoarau, V. C. Gibson, D. F. Wass, A. J. P. White, and D. J. Williams, Inorg. Chim. Acta, 2003, 345, 279. C. Bianchini, G. Giambastiani, I. G. Rios, G. Mantovani, A. Meli, and A. M. Segarra, Coord. Chem. Rev., 2006, 250, 1391.
Page 1 and 2:
THESE Présentée à l’Universit
Page 3 and 4:
Lisa, Mireia, Anja, Fredy, Shuanmin
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SOMMAIRE Composition du document et
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6. reference 32 Chapitre V Synthesi
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Composition du document et organisa
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Introduction La dynamique économiq
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Introduction La première étape co
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Introduction 26, 68-70 Des mécanis
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R R' P Ni Ph O B(Arf) R = R' = t-Bu
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Introduction Activés par des alkyl
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18 19 20 21 22 23 24 25 26 27 28 29
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88 89 90 91 92 93 94 95 96 97 98 99
Page 25 and 26:
Chapitre I Nickel Complexes with Fu
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Abstract Chapitre I Zwitterionic N,
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R HN O 1 O NH R Ph Ph 3P Ni R N O 2
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Chapitre I As shown in Figure 1, th
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Chapitre I Figure 3. Views of the s
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Chapitre I Figure 6. View of the ar
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Chapitre I with the metal, 51-54 tw
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Chapitre I these conditions, precat
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Chapitre I The precatalyst 13-17 ha
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Chapitre I Table 5. Catalytic Data
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TOF mol C2H4 / mol Ni.h -1 20000 15
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Chapitre I (s, OCH2), 81.27 (s, N
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Chapitre I atoms introduced as fixe
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Chapitre I (51) Tempel, D. J.; Broo
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Abstract Chapitre II The dinuclear
Page 55 and 56:
Chapitre II Other neutral nickel co
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OH 4 O N 4 13 OH N + 2 NiCl 2 + 2 N
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N2-Ni1-Cl1 169.45(12) 89.35(15) N2-
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Table 2. Selected bond distances an
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Chapitre II solubility of 15 in chl
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Chapitre II Table 4. Catalytic Data
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Chapitre II Table 5. Comparative Ca
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mass % of C4 olefins 100 90 80 70 6
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5. Experimental Chapitre II The 1 H
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Chapitre II a dark green powder. Yi
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Chapitre II 17 W. Keim, J. Mol. Cat
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7. Supporting information Table S1.
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Chapitre III Unprecedented Tetranuc
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Abstract Chapitre III Reactions of
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Chapitre III distorted octahedral c
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data for 2a⋅2CH2Cl2: 1.41 and for
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Chapitre III indicate that subtle d
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SUPPORTING INFORMATION FOR Chapitre
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Chapitre III by filtration. The sol
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Chapitre III 4 was prepared followi
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[S- ] 3. Evans method 2 Chapitre II
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Chapitre III Application Constructe
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Chapitre III [S-5] J. K. McCusker,
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Abstract Chapitre IV The P,N-type l
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Chapitre IV Scheme 1. Complexes wit
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12 PPh 2 N O N PPh 2 O N 13 P 14 15
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Chapitre IV Although some nickel co
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Scheme 2. Representation of the squ
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Chapitre IV The analysis of the dif
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Chapitre IV Table 4. Catalytic Data
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mass % of 1-butene 100 90 80 70 60
Page 117 and 118: Chapitre IV Table 6. Catalytic Data
Page 119 and 120: ef Scheme 3. Proposed pathways to e
Page 121 and 122: 4. Conclusion Chapitre IV New P,N l
Page 123 and 124: Chapitre IV SiCH3), 30.25 (s, SiCH2
Page 125 and 126: Chapitre IV 122.3 (s, Py), 122.5 (d
Page 127 and 128: [Ni(µ-Cl)2{(pyridin-2-yl) methanol
Page 129 and 130: Chapitre IV mmol of Ni complex or 1
Page 131 and 132: 6. References (1) Ziegler, K.; Holz
Page 133 and 134: Chapitre IV (44) Bluhm, M. E.; Foll
Page 135 and 136: Chapitre V Synthesis and catalytic
Page 137 and 138: Chapitre V to 16, the IR spectrum o
Page 139 and 140: Chapitre V activated by MAO (Scheme
Page 141 and 142: 2 OH N + PPhCl 2 NEt 3 - (HNEt 3)Cl
Page 143 and 144: Chapitre V Slow diffusion of heptan
Page 145 and 146: Chapitre V Figure 3. ORTEP view of
Page 147 and 148: Chapitre V tridentate ligand but wi
Page 149 and 150: Chapitre V spin system 1) and 3.06
Page 151 and 152: Chapitre V This establishes the coo
Page 153 and 154: TOF (mol C2H4/(mol Ni.h)) 90000 800
Page 155 and 156: % mass of 1-butene 80 70 60 50 40 3
Page 157 and 158: Chapitre V cyclic voltammograms of
Page 159 and 160: Chapitre V A n-BuLi solution (64.0
Page 161 and 162: Chapitre V IR (KBr): 1658 (vs), 147
Page 163 and 164: Chapitre V To a solution of (2-oxaz
Page 165 and 166: Chapitre V Synthesis of [Co{bis(1-(
Page 167: Chapitre V 30 bar working pressure
Page 171 and 172: 67 68 69 70 71 72 73 74 75 76 77 78
Page 173 and 174: Abstract Chapitre VI The β-keto ph
Page 175 and 176: Ph O 3 toluene PPh3 + Ni(COD) 2 + P
Page 177 and 178: Chapitre VI The synthesis of β-ket
Page 179 and 180: Table 1 Selected bond distances (Å
Page 181 and 182: Ph O toluene PR2R' + Ni(COD) 2 + C5
Page 183 and 184: 4. Conclusion Chapitre VI The β-ke
Page 185 and 186: Chapitre VI and the solution was st
Page 187 and 188: Chapitre VI (s, p-C of OC-Ph), 131.
Page 189 and 190: Chapitre VI To a solution of 13.000
Page 191 and 192: Chapitre VI the solvents under redu
Page 193 and 194: Chapitre VI Crystal Structure Deter
Page 195 and 196: 23 F. A. Hicks and M. Brookhart, Or
Page 197 and 198: Chapitre VII Réarrangement type Ar
Page 199 and 200: 1. Introduction Chapitre VII Brookh
Page 201 and 202: N OPPh 2 OPPh 2 + NiCl2(DME) N O Ph
Page 203 and 204: Chapitre VII mécanisme apparenté
Page 205 and 206: [Ni{2,6-bis((diphenylphosphinito)me
Page 207 and 208: Résumé et Conclusion générale
Page 209 and 210: Chapitre II Résumé et conclusion
Page 211 and 212: Résumé et conclusion générale P
Page 213 and 214: Résumé et conclusion générale l
Page 215 and 216: Chapitre VII Résumé et conclusion
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Anthony KERMAGORET - THESES ET MEMOIRES DE L'UDS

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