6. References 1 K. Ziegler, E. Holzkamp, H. Breil and H. Martin, Angew. Chem., 1955, 67, 426. 2 G. Wilke, Angew. Chem. Int. Ed., 2003, 42, 5000. Chapitre VI 3 Late Transition Metal Polymerization Catalysis, ed. B. Rieger, L. Saunders Baugh, S. Kacker and S. Striegler, Wiley -VCH, 2003 4 K. Ziegler, H. G. Gellert, E. Holzkamp and G. Wilke, Brennst.-Chem., 1954, 35, 321. 5 G. J. P. Britovsek, V. C. Gibson and D. F. Wass, Angew. Chem., Int. Ed., 1999, 38, 428. 6 S. Mecking, Angew. Chem. Int. Ed., 2001, 40, 534. 7 L. K. Johnson, C. M. Killian and M. Brookhart, J. Am. Chem. Soc., 1995, 117, 6414. 8 C. M. Killian, D. J. Tempel, L. K. Johnson and M. Brookhart, J. Am. Chem. Soc., 1996, 118, 11664. 9 S. D. Ittel, L. K. Johnson and M. Brookhart, Chem. Rev., 2000, 100, 1169. 10 V. C. Gibson and S. K. Spitzmesser, Chem. Rev., 2003, 103, 283. 11 C. M. Killian, L. K. Johnson and M. Brookhart, Organometallics, 1997, 16, 2005. 12 S. A. Svejda and M. Brookhart, Organometallics, 1999, 18, 65. 13 T. R. Younkin, E. F. Connor, J. I. Henderson, S. K. Friedrich, R. H. Grubbs and D. A. Bansleben, Science, 2000, 287, 460. 14 D. J. Darensbourg, C. G. Ortiz and J. C. Yarbrough, Inorg. Chem., 2003, 42, 6915. 15 Q.-Z. Yang, A. Kermagoret, M. Agostinho, O. Siri and P. Braunstein, Organometallics, 2006, 25, 5518. 16 W.-H. Sun, W. Zhang, T. Gao, X. Tang, L. Chen, Y. Li and X. Jin, J. Organomet. Chem., 2004, 689, 917. 17 F. Speiser, P. Braunstein and L. Saussine, Acc. Chem. Res., 2005, 38, 784. 18 P. Braunstein, Chem. Rev., 2006, 106, 134. 19 C. Wang, S. Friedrich, T. R. Younkin, R. T. Li, R. H. Grubbs, D. A. Bansleben and M. W. Day, Organometallics, 1998, 17, 3149. 20 T. R. Younkin, E. F. Connor, J. I. Henderson, S. K. Friedrich, R. H. Grubbs and D. A. Bansleben, Science, 2000, 288, 1750. 21 M. A. Zuideveld, P. Wehrmann, C. Röhr and S. Mecking, Angew. Chem., Int. Ed., 2004, 43, 869. 22 I. Goettker-Schnetmann, B. Korthals and S. Mecking, J. Am. Chem. Soc., 2006, 128, 7708. 23
23 F. A. Hicks and M. Brookhart, Organometallics, 2001, 20, 3217. 24 F. A. Hicks, J. C. Jenkins and M. Brookhart, Organometallics, 2003, 22, 3533. 25 J. C. Jenkins and M. Brookhart, J. Am. Chem. Soc., 2004, 126, 5827. 26 J. C. Jenkins and M. Brookhart, Organometallics, 2003, 22, 250. Chapitre VI 27 T. Hu, L.-M. Tang, X.-F. Li, Y.-S. Li and N.-H. Hu, Organometallics, 2005, 24, 2628. 28 R. S. Rojas, J.-C. Wasilke, G. Wu, J. W. Ziller and G. C. Bazan, Organometallics, 2005, 24, 5644. 29 M. P. Batten, A. J. Canty, K. J. Cavell, T. Rüther, B. W. Skelton and A. H. White, Inorg. Chim. Acta, 2006, 359, 1710. 30 M. S. W. Chan, L. Deng and T. Ziegler, Organometallics, 2000, 19, 2741. 31 W. Keim, Angew. Chem. Int. Ed., 1990, 29, 235. 32 W. Keim, F. H. Kowaldt, R. Goddard and C. Krüger, Angew. Chem. Int. Ed., 1978, 17, 466. 33 W. Keim, A. Behr, B. Gruber, B. Hoffmann, F. H. Kowaldt, U. Kürschner, B. Limbäcker and F. P. Sistig, Organometallics, 1986, 5, 2356. 34 J. Pietsch, P. Braunstein and Y. Chauvin, New J. Chem., 1998, 22, 467. 35 U. Klabunde and S. D. Ittel, J. Mol. Catal., 1987, 41, 123. 36 U. Klabunde, R. Mühlhaupt, T. Herskowitz, A. H. Janowicz, J. Calabrese and S. D. Ittel, J. Polym. Sci., Polym. Chem., 1987, 25, 1989. 37 W. Keim, New J. Chem., 1987, 11, 531. 38 R. Soula, J. P. Broyer, M. F. Llauro, A. Tomov, R. Spitz, J. Claverie, X. Drujon, J. Malinge and T. Saudemont, Macromolecules, 2001, 8, 2438. 39 W. Keim, J. Mol. Catal., 1989, 52, 19. 40 P. Kuhn, D. Semeril, C. Jeunesse, D. Matt, P. Lutz and R. Welter, Eur. J. Inorg. Chem., 2005, 1477. 41 P. Kuhn, D. Semeril, C. Jeunesse, D. Matt, M. Neuburger and A. Mota, Chem. Eur. J., 2006, 12, 5210. 42 P. Kuhn, D. Semeril, D. Matt, M. J. Chetcuti and P. Lutz, Dalton Trans., 2007, 515. 43 J. Pietsch, P. Braunstein and Y. Chauvin, New J. Chem., 1998, 467. 44 J. Heinicke, M. Koesling, R. Brüll, W. Keim and H. Pritzkow, Eur. J. Inorg. Chem., 2000, 299. 45 J. Heinicke, M. He, A. Dal, H. F. Klein, O. Hetche, W. Keim, U. Flörke and H. J. Haupt, Eur. J. Inorg. Chem., 2000, 431. 24
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THESE Présentée à l’Universit
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Lisa, Mireia, Anja, Fredy, Shuanmin
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SOMMAIRE Composition du document et
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6. reference 32 Chapitre V Synthesi
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Composition du document et organisa
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Introduction La dynamique économiq
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Introduction La première étape co
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Introduction 26, 68-70 Des mécanis
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R R' P Ni Ph O B(Arf) R = R' = t-Bu
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Introduction Activés par des alkyl
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18 19 20 21 22 23 24 25 26 27 28 29
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88 89 90 91 92 93 94 95 96 97 98 99
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Chapitre I Nickel Complexes with Fu
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Abstract Chapitre I Zwitterionic N,
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R HN O 1 O NH R Ph Ph 3P Ni R N O 2
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Chapitre I As shown in Figure 1, th
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Chapitre I Figure 3. Views of the s
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Chapitre I Figure 6. View of the ar
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Chapitre I with the metal, 51-54 tw
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Chapitre I these conditions, precat
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Chapitre I The precatalyst 13-17 ha
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Chapitre I Table 5. Catalytic Data
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TOF mol C2H4 / mol Ni.h -1 20000 15
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Chapitre I (s, OCH2), 81.27 (s, N
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Chapitre I atoms introduced as fixe
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Chapitre I (51) Tempel, D. J.; Broo
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Abstract Chapitre II The dinuclear
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Chapitre II Other neutral nickel co
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OH 4 O N 4 13 OH N + 2 NiCl 2 + 2 N
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N2-Ni1-Cl1 169.45(12) 89.35(15) N2-
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Table 2. Selected bond distances an
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Chapitre II solubility of 15 in chl
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Chapitre II Table 4. Catalytic Data
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Chapitre II Table 5. Comparative Ca
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mass % of C4 olefins 100 90 80 70 6
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5. Experimental Chapitre II The 1 H
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Chapitre II a dark green powder. Yi
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Chapitre II 17 W. Keim, J. Mol. Cat
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7. Supporting information Table S1.
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Chapitre III Unprecedented Tetranuc
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Abstract Chapitre III Reactions of
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Chapitre III distorted octahedral c
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data for 2a⋅2CH2Cl2: 1.41 and for
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Chapitre III indicate that subtle d
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SUPPORTING INFORMATION FOR Chapitre
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Chapitre III by filtration. The sol
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Chapitre III 4 was prepared followi
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[S- ] 3. Evans method 2 Chapitre II
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Chapitre III Application Constructe
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Chapitre III [S-5] J. K. McCusker,
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Abstract Chapitre IV The P,N-type l
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Chapitre IV Scheme 1. Complexes wit
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12 PPh 2 N O N PPh 2 O N 13 P 14 15
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Chapitre IV Although some nickel co
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Scheme 2. Representation of the squ
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Chapitre IV The analysis of the dif
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Chapitre IV Table 4. Catalytic Data
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mass % of 1-butene 100 90 80 70 60
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Chapitre IV Table 6. Catalytic Data
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ef Scheme 3. Proposed pathways to e
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4. Conclusion Chapitre IV New P,N l
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Chapitre IV SiCH3), 30.25 (s, SiCH2
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Chapitre IV 122.3 (s, Py), 122.5 (d
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[Ni(µ-Cl)2{(pyridin-2-yl) methanol
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Chapitre IV mmol of Ni complex or 1
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6. References (1) Ziegler, K.; Holz
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Chapitre IV (44) Bluhm, M. E.; Foll
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Chapitre V Synthesis and catalytic
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Chapitre V to 16, the IR spectrum o
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Chapitre V activated by MAO (Scheme
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2 OH N + PPhCl 2 NEt 3 - (HNEt 3)Cl
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- Page 173 and 174: Abstract Chapitre VI The β-keto ph
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- Page 207 and 208: Résumé et Conclusion générale
- Page 209 and 210: Chapitre II Résumé et conclusion
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- Page 213 and 214: Résumé et conclusion générale l
- Page 215 and 216: Chapitre VII Résumé et conclusion