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Asbestos Fibers and Other Elongate Mineral Particles: State of the ...

Asbestos Fibers and Other Elongate Mineral Particles: State of the ...

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Table 1. Definitions <strong>of</strong> general mineralogical terms (Continued)<br />

144<br />

Glossary <strong>of</strong> Geology, 5th ed.<br />

[American Geological<br />

Institute 2005] Leake et al. [1997] NIOSH [1990a]<br />

Dictionary <strong>of</strong> Mining,<br />

<strong>Mineral</strong>, <strong>and</strong> Related<br />

Terms [U.S. Bureau<br />

<strong>of</strong> Mines 1996]<br />

[Note: Footnotes identify <strong>the</strong> Primary<br />

Source Citation for <strong>the</strong> definition]<br />

Term<br />

a generic term for a large group <strong>of</strong><br />

white or colorless (sometimes tinted<br />

red or yellow by impurities) hydrous<br />

aluminosilicate minerals that have<br />

an open framework structure <strong>of</strong><br />

interconnected (Si,Al)O4 tetrahedra with<br />

exchangeable cations <strong>and</strong> H2O molecules<br />

in structural cavities. They have a ratio<br />

<strong>of</strong> (Al + Si) to nonhydrous oxygen <strong>of</strong> 1:2,<br />

<strong>and</strong> are characterized by <strong>the</strong>ir easy <strong>and</strong><br />

reversible loss <strong>of</strong> water <strong>of</strong> hydration <strong>and</strong><br />

by <strong>the</strong>ir ready fusion <strong>and</strong> swelling when<br />

strongly heated under <strong>the</strong> blowpipe.<br />

Zeolites have long been known to occur as<br />

well formed crystals in cavities in basalt.<br />

Of more significance is <strong>the</strong>ir occurrence<br />

as authigenic minerals in <strong>the</strong> sediments<br />

<strong>of</strong> saline lades <strong>and</strong> <strong>the</strong> deep sea <strong>and</strong> esp.<br />

in beds <strong>of</strong> tuff. They form “during <strong>and</strong><br />

after burial, generally by reaction <strong>of</strong><br />

pore waters with solid aluminosilicate<br />

materials (e.g., volcanic glass, feldspar,<br />

biogenic silica, <strong>and</strong> clay minerals).” 8<br />

Zeolite 1. A generic term for class <strong>of</strong><br />

hydrated silicates <strong>of</strong> aluminum<br />

<strong>and</strong> ei<strong>the</strong>r sodium or calcium<br />

or both, <strong>of</strong> <strong>the</strong> type Na2O. Al •<br />

2O3.nSiO2 xH2O. The term<br />

originally described a group <strong>of</strong><br />

naturally occurring minerals.<br />

The natural zeolites are analcite,<br />

chabazite, heul<strong>and</strong>ite, natrolite,<br />

stilbite, <strong>and</strong> thomsonite.<br />

Artificial zeolites are made<br />

in a variety <strong>of</strong> forms, ranging<br />

from gelatinous to porous <strong>and</strong><br />

s<strong>and</strong>like, <strong>and</strong> are used as gas<br />

adsorbents <strong>and</strong> drying agents<br />

as well as water s<strong>of</strong>teners. Both<br />

natural <strong>and</strong> artificial zeolites<br />

are used extensively for water<br />

s<strong>of</strong>tening. The term zeolite now<br />

includes such diverse groups<br />

<strong>of</strong> compounds as sulfonated<br />

organics or basic resins, which<br />

act in a similar manner to effect<br />

ei<strong>the</strong>r cation or anion exchange.<br />

See footnotes at end <strong>of</strong> table. (Continued)<br />

NIOSH CIB 62 • <strong>Asbestos</strong>

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