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USGS Professional Paper 1697 - Alaska Resources Library

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composition magmatic bodies (with approximate K-Ar ages<br />

of 70 Ma). The first stage consists of grossular-wollastonite<br />

skarn and concentrically zoned, finely banded aggregates with<br />

numerous finely crystalline datolite and druse-like accumulations<br />

of danburite crystals in paleohydrothermal cavities. The<br />

second stage skarn consists predominantly of long, radiated<br />

hedenbergite and andradite with coarsely crystalline datolite,<br />

danburite, quartz, axinite, and calcite. The arcuate nature of<br />

metasomatic mineral zonation in the skarn is interpreted by<br />

Shkolnik and others (2003) as replacement of stromatolite<br />

build-ups in the host Triassic Limestone. The complex layering<br />

are relict biogenic features of the stomatolite-bearing<br />

limestone. An Ar-Ar age for orthoclase indicates an age for the<br />

late-stage skarn assemblage of 57 Ma. The silicate mineralogy<br />

of the early-stage skarn is similar to that in Pb-Zn skarn deposits<br />

in this same region. B isotopic studies indicate a magmatic<br />

source for boron (Ratkin and Watson, 1993). The deposit is<br />

very large and had been mined from 1970’s to present. The<br />

deposit produces more than 90 percent of all borate in Russia.<br />

The Dalnegorsk open-pit mine at the deposit is prospected to<br />

the depth of 1 km.<br />

Clastic sedimentary rocks (Early Cretaceous)<br />

Sedimentary breccia with small fragments of<br />

limestone and chert (Early Cretaceous)<br />

Siliceous shale and siltstone (Triassic, Jurassic,<br />

and Early Cretaceous)<br />

Olistolith of bedded limestone (Triassic)<br />

Datolite-danburite-wollastonitehedenbergite-andradite<br />

skarn<br />

Mafic dike (early Tertiary)<br />

Mafic dike (Cretaceous)<br />

Fault<br />

Contact<br />

Early Late Cretaceous Metallogenic Belts (100 to 84 Ma; figs. 79, 80) 185<br />

<br />

Nikolaevskoe Pb-Zn Skarn Deposit<br />

The Nikolaevskoe Pb-Zn skarn deposit (fig. 86) (Garbuzov<br />

and others, 1987; V.V. Ratkin, this study; Vasilenko and<br />

Valuy, 1998) consists of large, layered ore bodies formed in<br />

a giant olistolith of Triassic limestone that is part of an Early<br />

Cretaceous accretionary-fold complex. The skarn occurs at the<br />

contacts of limestone with hosting siltstone and sandstone and<br />

with overlying felsic volcanic rocks of a Late Cretaceous to<br />

Paleogene post accretionary sequence. Small ore bodies also<br />

occur in limestone blocks in the volcanic rocks that were torn<br />

off the underlying basement. The ore minerals are dominantly<br />

galena and sphalerite that replace an earlier hedenbergite skarn<br />

near the surface, and, at depth, replace a garnet-hedenbergite<br />

skarn. Subordinate ore minerals are chalcopyrite, arsenopyrite,<br />

pyrite, pyrrhotite, fluorite, and Ag-sulfosalts. K-Ar isotopic<br />

studies indicate an age of mineralization between 60 and 80<br />

Ma. A 60 K-Ar Ma isotopic age is obtained for an unmineralized<br />

basalt dike that cuts the deposit, and a K-Ar age of 70-80<br />

Ma is obtained for a mineralized ignimbrite that overlies<br />

the olistolith. The deposit is currently being mined. Average<br />

0 500 m<br />

Figure 85. Dalnegorsk B skarn deposit, Taukha metallogenic belt, Russian Southeast. Schematic geologic<br />

map. Adapted from Nosenko and Chernyshov (1987). See figure 79 and table 4 for location.

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