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Thermonicolet Omnic Software User's Guide 6.1 (PDF) - Charles E ...

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Specifying the number<br />

of levels of zero filling<br />

Zero Filling determines the number of levels of zero filling used when the data are<br />

Fourier transformed. Zero filling improves the line shape of a spectrum by adding<br />

data points between collected data points. Sharp features become smoother and<br />

more like typical peaks when zero filling is used.<br />

Because data points are added, the transform takes longer. Zero filling does not<br />

increase the “true” resolution of the data, however, since that is determined by the<br />

number of data points collected.<br />

The available settings of Zero Filling are described in the following table.<br />

Setting<br />

None<br />

Description<br />

No zero filling is done.<br />

1 Level One data point is added between each data point.<br />

2 Levels This setting adds three points between each data point to better<br />

define band shapes.<br />

Set Zero Filling to None for normal work.<br />

Collect your sample and background spectra using the same number of levels of<br />

zero filling.<br />

If band shapes are cut off, set Zero Filling to 1 Level or 2 Levels instead of None.<br />

Selecting the apodization type<br />

The Apodization parameter determines the type of apodization that is used before<br />

the interferogram is Fourier transformed. Apodization removes peak side lobes<br />

that can occur because the interferogram is not an infinite set of data. The<br />

apodization types described in the following table are available. Collect your<br />

sample and background spectra using the same apodization type.<br />

Setting<br />

Happ-Genzel<br />

Triangular<br />

Description<br />

This is the best choice for most applications. It suppresses<br />

side lobes more effectively than the triangular type and with<br />

less reduction in resolution than that type. (It results in more<br />

reduction in resolution than the boxcar type.) Use this type<br />

if you are measuring condensed-phase samples.<br />

Mathematically weights interferogram data to reduce<br />

ringing effects (side lobes), resulting in lower resolution<br />

than that obtained with the boxcar and Happ-Genzel types.<br />

Some ringing will usually be present with this type. This<br />

setting is normally used only to reproduce the results of<br />

other experiments that used it.<br />

2 Levels This setting adds three points between each data point to<br />

better define band shapes.<br />

(continued on next page)<br />

OMNIC User’s <strong>Guide</strong> 137

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