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Using Polymer Modified Asphalt Emulsions in Surface Treatments A ...

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<strong>in</strong> the literature on the use of polymerized asphalt emulsions on trails and park<strong>in</strong>g lots<br />

as noted previously.<br />

3.2.2 Task 2B. Identify<strong>in</strong>g and Specify<strong>in</strong>g <strong>Polymer</strong> Percentages<br />

Experience has shown that specify<strong>in</strong>g polymer percentage does not necessarily result<br />

<strong>in</strong> the expected performance because of differences <strong>in</strong> compatibilities between asphalt<br />

and polymers from different sources. Moreover, feedback received from <strong>in</strong>dustry<br />

participants at the St. Louis meet<strong>in</strong>g <strong>in</strong> 2006 clearly <strong>in</strong>dicates that suppliers view<br />

polymer quantity specifications as a practice which serves to <strong>in</strong>hibit <strong>in</strong>novation – a<br />

problem which can be remedied with the adoption of appropriate performance<br />

specifications.<br />

Thus, performance test<strong>in</strong>g rather than recipe specifications should result <strong>in</strong> the longest<br />

last<strong>in</strong>g, most cost-effective treatments, by afford<strong>in</strong>g suppliers the opportunity to<br />

prescribe the polymer types, formulation methods, and mix design flexibility to meet<br />

agency and end-user requirements. Specific methods which are currently under<br />

consideration are discussed elsewhere <strong>in</strong> this report. Because of the importance of<br />

uniformity and compatibility to performance, it is recommended that the polymer not be<br />

post-blended with the asphalt emulsion <strong>in</strong> the field, particularly s<strong>in</strong>ce both SHA and<br />

<strong>in</strong>dustry stakeholders have openly discouraged this practice.<br />

Low temperature recovery of asphalt emulsion residues will simulate emulsion cur<strong>in</strong>g<br />

much more effectively than current recovery methods which are performed at<br />

temperatures that are far higher than these products will ever experience <strong>in</strong> the field.<br />

The high temperatures associated with currently used recovery methods have been<br />

shown to change the residue rheological properties, as the modulus is usually cut <strong>in</strong> half<br />

by heat<strong>in</strong>g the sample to 350º C, as opposed to us<strong>in</strong>g a low temperature Forced Draft<br />

Oven Method. Also, phase angles from high temperature distillation suggest that<br />

heat<strong>in</strong>g can cause cross-l<strong>in</strong>k<strong>in</strong>g and damage to polymer additives. Therefore, it is<br />

recommended that a low-temperature method be adopted which is more representative<br />

of field cur<strong>in</strong>g conditions. Several such methods are under <strong>in</strong>vestigation by various<br />

107

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