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Using Polymer Modified Asphalt Emulsions in Surface Treatments A ...

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• <strong>Polymer</strong>/<strong>Asphalt</strong> Compatibility and Stability Dur<strong>in</strong>g Ag<strong>in</strong>g: It is<br />

known that certa<strong>in</strong> polymer/asphalt blends are <strong>in</strong>compatible, such<br />

that the polymer will tend to separate or loose its elastic network<br />

over time. For modified HMA b<strong>in</strong>ders, such unstable systems are<br />

typically elim<strong>in</strong>ated by specify<strong>in</strong>g heat stability tests such as the<br />

Long-Term <strong>Asphalt</strong> Stability (LAST) test or the Separation Test.<br />

Because there is no heated storage of emulsion residue, experts<br />

reject these methods as performance <strong>in</strong>dicators. Another good<br />

<strong>in</strong>dication of compatibility comes from various microscopic methods<br />

such as fluorescence or scann<strong>in</strong>g electron microscopy. Aga<strong>in</strong>,<br />

experts suggest such methods are useful to the formulator, but<br />

should not be adopted for specifications. As another data gap, a<br />

method is needed to <strong>in</strong>sure polymer network stability under the<br />

conditions experienced by ag<strong>in</strong>g emulsion residues on the<br />

pavement surface.<br />

2. PME residues should not be exposed to elevated temperatures dur<strong>in</strong>g<br />

recovery or sample preparation. Any procedure requir<strong>in</strong>g cur<strong>in</strong>g or<br />

reheat<strong>in</strong>g temperatures above 60ºC (140°F) must be validated by show<strong>in</strong>g<br />

performance properties comparable to those from Forced Draft Oven<br />

Residues.<br />

3. M<strong>in</strong>imize the quantity of residue needed for performance test<strong>in</strong>g, ideally<br />

complet<strong>in</strong>g all residue tests with the recovered b<strong>in</strong>der from a s<strong>in</strong>gle<br />

silicone mold as cured <strong>in</strong> the Forced Draft Oven Recovery Method.<br />

4. M<strong>in</strong>imize equipment costs and test<strong>in</strong>g time, us<strong>in</strong>g common tools wherever<br />

possible. Survey comments and AEMA discussions emphasized the<br />

concern that there are many small companies supply<strong>in</strong>g emulsion from<br />

one or two plants, and those facilities only manufacture approximately 10-<br />

20% of volumes shipped by ref<strong>in</strong>eries or liquid asphalt term<strong>in</strong>als supply<strong>in</strong>g<br />

84

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