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Using Polymer Modified Asphalt Emulsions in Surface Treatments A ...

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molecular weights rang<strong>in</strong>g up to 100,000. The adhesion of asphalt to m<strong>in</strong>eral aggregate<br />

particles is also thought to depend on the polar attraction between asphalt particles and<br />

the negatively charged surfaces of most aggregates. Although asphalt is not a polymer<br />

<strong>in</strong> the strict sense of the word, it is regarded as a thermoplastic material because it<br />

becomes soft when heated and hardens upon cool<strong>in</strong>g. With<strong>in</strong> a certa<strong>in</strong> temperature<br />

range, asphalts also exhibit modest viscoelastic properties which can be improved upon<br />

via the addition of polymer modifiers.<br />

2.1.4 <strong>Polymer</strong> <strong>Modified</strong> <strong>Asphalt</strong> (PMA)<br />

In general terms, the addition of polymers to asphalt b<strong>in</strong>ders results <strong>in</strong> the modification<br />

of certa<strong>in</strong> key physical properties <strong>in</strong>clud<strong>in</strong>g the:<br />

• Elasticity;<br />

• Tensile Strength;<br />

• High and Low Temperature Susceptibilities;<br />

• Viscosity; and,<br />

• Adhesion and Cohesion.<br />

Depend<strong>in</strong>g upon the form of modification desired, improvements <strong>in</strong> pavement longevity<br />

can be achieved through the reduction of fatigue and thermal crack<strong>in</strong>g, decreased high<br />

temperature susceptibility (e.g., rutt<strong>in</strong>g and shov<strong>in</strong>g), and enhanced aggregate retention<br />

<strong>in</strong> applications such as chip seals. <strong>Polymer</strong> modifiers are utilized to extend the lower<br />

and/or upper effective temperature operat<strong>in</strong>g ranges of pavements, and to add elastic<br />

components that allow it to recover from load<strong>in</strong>g stress.<br />

A variety of test<strong>in</strong>g techniques and equipment are available which may be used to<br />

evaluate and quantify the performance characteristics of polymer modified b<strong>in</strong>ders and<br />

emulsion residues. A few of the most common of these <strong>in</strong>clude:<br />

• Dynamic Shear Rheometer (DSR) – Used to measure the shear modulus<br />

(resistance and phase angle) of asphalt with<strong>in</strong> <strong>in</strong>termediate to high operational<br />

8

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