Using Polymer Modified Asphalt Emulsions in Surface Treatments A ...
Using Polymer Modified Asphalt Emulsions in Surface Treatments A ...
Using Polymer Modified Asphalt Emulsions in Surface Treatments A ...
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2.2.3 Synthetic Rubber and Latex<br />
Synthetic latex is a thermoset elastomer which consists of a mixture of polymer particles<br />
dispersed <strong>in</strong> water. Commonly used varieties of synthetic latex rubber <strong>in</strong>clude styrenebutad<strong>in</strong>e<br />
rubber (SBR, a random copolymer), polychloroprene (Neoprene), and<br />
polybutadiene (PB). Common uses of latex modified asphalt emulsions <strong>in</strong>clude<br />
microsurfac<strong>in</strong>gs, chip seals, and slurry seals. Lubbers and Watson (2005) note that the<br />
handl<strong>in</strong>g and blend<strong>in</strong>g of SBR latex is particularly versatile, and is amenable to a variety<br />
of pre- and post-modification methodologies (4). When sufficient quantities of synthetic<br />
latex are added to compatible asphalts, the cured mixture is commonly characterized by<br />
the existence of a cont<strong>in</strong>uous polymer network which envelops the bitumen particles<br />
(see Figure 4). Benefits of properly blended latex polymers <strong>in</strong>cluded improved stone<br />
retention, <strong>in</strong>creased skid-resistance, and improved low temperature performance (i.e.,<br />
less brittleness, better elasticity).<br />
Like NRL, when SBR latex is uniformly dispersed <strong>in</strong> the emulsion dur<strong>in</strong>g blend<strong>in</strong>g, it<br />
forms elastic lattices with<strong>in</strong> the bitum<strong>in</strong>ous cement when cured. More specifically, as<br />
water with<strong>in</strong> an applied emulsion evaporates, droplets conta<strong>in</strong><strong>in</strong>g SBR coalesce along<br />
the surfaces of asphalt particles, which results <strong>in</strong> the formation of a cont<strong>in</strong>uous,<br />
honeycombed polymer network which extends throughout the b<strong>in</strong>der (12). In this way,<br />
SBR particles form “welds” between asphalt particles, which results <strong>in</strong> an <strong>in</strong>crease <strong>in</strong><br />
tensile strength, stone retention, and resistance to crack<strong>in</strong>g (12) (13). SBR<br />
modification of asphalt emulsions may be accomplished by co-mill<strong>in</strong>g at the colloid mill,<br />
post-blend<strong>in</strong>g after emulsification, or by mix<strong>in</strong>g at the application site through the<br />
distributor (a field variation of the post-blend<strong>in</strong>g method) (13). SBR compatibility with<br />
the asphalt used should be verified to ensure the success of s<strong>in</strong>gle-stage mix<strong>in</strong>g<br />
methods.<br />
Takamura (2001) has demonstrated the benefits of perform<strong>in</strong>g SBR modification of<br />
asphalt emulsions and microsurfac<strong>in</strong>g mixes, <strong>in</strong> which significant <strong>in</strong>creases <strong>in</strong> rutt<strong>in</strong>g<br />
resistance were observed with <strong>in</strong>creas<strong>in</strong>g polymer content (14). Takamura notes that<br />
as cur<strong>in</strong>g time lengthens, the benefits of <strong>in</strong>creased polymer content become more<br />
14