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Using Polymer Modified Asphalt Emulsions in Surface Treatments A ...

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and contam<strong>in</strong>ation were substantially greater than were found dur<strong>in</strong>g asphalt emulsion<br />

residue trials. It is hypothesized that this performance differential between modified<br />

asphalt b<strong>in</strong>ders may be due to the evaporation of water from the former, which provides<br />

a better barrier to oxidation, and hence ag<strong>in</strong>g (52). Therefore, it is suggested that<br />

modified asphalt emulsion storage and handl<strong>in</strong>g protocols should focus primarily on<br />

prevent<strong>in</strong>g excessive water loss and phase separation rather than on ag<strong>in</strong>g-related<br />

problems (53).<br />

2.4 Performance<br />

2.4.1 Performance Criteria<br />

The performance enhanc<strong>in</strong>g characteristics of polymer additives are generally twofold -<br />

offer<strong>in</strong>g <strong>in</strong>creased resistance to permanent forms of deformation such as rutt<strong>in</strong>g and<br />

shov<strong>in</strong>g (high temperature susceptibility); and provid<strong>in</strong>g improved durability with respect<br />

to the formation of load-associated types of pavement distress (i.e., fatigue crack<strong>in</strong>g).<br />

<strong>Polymer</strong>s can also afford additional benefits by reduc<strong>in</strong>g the formation of non-load<br />

associated cracks caused by roadway brittleness which often occurs <strong>in</strong> pavements that<br />

become excessively stiff and hard at low temperatures. In this regard, properly modified<br />

asphalts demonstrate improved temperature susceptibility characteristics by rema<strong>in</strong><strong>in</strong>g<br />

flexible at low temperatures, while reta<strong>in</strong><strong>in</strong>g sufficient stiffness at high temperatures to<br />

resist permanent deformation.<br />

Some <strong>in</strong>itiatives have been undertaken to develop a “Superpave-like” specification for<br />

surface applied asphalt emulsions. At present, ASTM D977-05 Standard Specification<br />

for Emulsified <strong>Asphalt</strong> utilizes some aspects of Superpave <strong>in</strong> its test<strong>in</strong>g and<br />

characterization protocols. Hazlett (1996) asserts that many of the Superpave<br />

performance criteria, such as rutt<strong>in</strong>g resistance, thermal crack<strong>in</strong>g, and RTFO ag<strong>in</strong>g, are<br />

not applicable to surface applied treatments (55). Moreover, while some forms of<br />

Superpave test<strong>in</strong>g could be extrapolated to polymer-modified emulsified asphalts,<br />

certa<strong>in</strong> specification limits may not be appropriate for pavement surface conditions.<br />

However, Clyne et al (2003) utilized Superpave specifications to test polymer<br />

modified asphalt emulsion residue for cold <strong>in</strong>-place recycl<strong>in</strong>g applications, <strong>in</strong> a manner<br />

similar to that of asphalt b<strong>in</strong>der (56). Comparisons of result<strong>in</strong>g data trends from<br />

41

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