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Complete Report - University of New South Wales

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The theory <strong>of</strong> hot carrier absorbers has been extended to include a greater understanding <strong>of</strong><br />

phononic transport and a recognition <strong>of</strong> similarities to the required properties <strong>of</strong> thermoelectric<br />

materials (see “Hot Carrier Absorbers” in Section 5.5 in 2003 Annual <strong>Report</strong>). In particular<br />

the specifi c mechanisms which can slow cooling by enhancing the “phonon bottleneck effect”<br />

in QW and QD superlattices are being identifi ed. Experimental evidence <strong>of</strong> such reduced<br />

cooling in QW superlattices has been identifi ed in the literature. (See section “Hot Carrier<br />

Absorbers” in section 4.5 in 2004 Annual <strong>Report</strong>). This work has been extended further in<br />

2005 with modelling <strong>of</strong> the specifi c phonon mechanisms and quantum dot conditions that<br />

can give an enhanced ‘phonon bottleneck effect’ in QD nanostructured materials.<br />

A.12<br />

Demonstration <strong>of</strong> the quantum confined Stark effect in silicon as the basis <strong>of</strong> a highspeed<br />

silicon modulator).<br />

Devices <strong>of</strong> an appropriate structure were fabricated during 2003, but silicon layers needed<br />

to be thinner to demonstrate this effect. Progress was made in 2004 and 2005 in reducing<br />

the thickness <strong>of</strong> these layers, that are now close to the desired value.<br />

A.13<br />

Evaluation <strong>of</strong> the optical constants <strong>of</strong> quantum confined silicon SOI devices as a<br />

function <strong>of</strong> layer thickness.<br />

Relevant data have been reported in section 5.5 <strong>of</strong> the 2003 Annual <strong>Report</strong> and section 4.6<br />

<strong>of</strong> the 2004 report. Photoluminescence properties have been characterised. Conversion<br />

to optical constants requires accurate knowledge <strong>of</strong> the dimensions <strong>of</strong> the confi ned material.<br />

Measurement <strong>of</strong> these produces some experimental challenges, presently being addressed.<br />

The most accurate method seems to be by identifying photoluminescence features<br />

corresponding to regions differing by the presence <strong>of</strong> one additional atomic plane in the<br />

region under test. However, fi nding an independent technique that is able to confi rm this<br />

interpretation <strong>of</strong> the data has provided a challenge.<br />

Other work quantifying the evidence for QDs and their dimensions is continuing. This includes<br />

analysis <strong>of</strong> HRTEM, high resolution SIMS and synchrotron XRD.<br />

A.14<br />

Improvement <strong>of</strong> light emission efficiency <strong>of</strong> silicon diodes above levels already<br />

demonstrated, to maintain Australian leadership and as a test bed for integrated<br />

devices.<br />

Australia retains leadership in the bulk silicon luminescence fi eld, although efforts during the<br />

last 12 months have concentrated on integrated devices.<br />

A.15<br />

Demonstration <strong>of</strong> high light emission efficiency in silicon LEDs integrated into<br />

microelectronic chips.<br />

Effi ciencies <strong>of</strong> 2x10 -6 have been demonstrated, although further improvements are expected<br />

as devices become thinner.<br />

A.16<br />

Demonstration <strong>of</strong> high speed modulation <strong>of</strong> output <strong>of</strong> silicon light emitting diodes.<br />

Modulation has been demonstrated, but not yet at high speed.<br />

152

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