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Complete Report - University of New South Wales

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4.3 FIRST GENERATION: WAFER-BASED PROJECTS<br />

4.3.1 High Efficiency Cells<br />

<strong>University</strong> Staff:<br />

A/Pr<strong>of</strong>. Jianhua Zhao (group leader)<br />

Pr<strong>of</strong>. Martin Green<br />

Pr<strong>of</strong>. Stuart Wenham<br />

Research Fellows: Dr. Aihua Wang<br />

Research Assistant: Guangchun Zhang<br />

Technical Staff: Jules Yang<br />

During 2005, a cell effi ciency equalling the world record for n-type silicon cells has been<br />

demonstrated by a new rear emitter PERT cell structure, which was developed by the high<br />

effi ciency group at the Centre. The previous record was set more than a decade ago by<br />

Stanford <strong>University</strong>. This new cell structure is expected to produce further improvements<br />

in cell effi ciency and, importantly, is also suitable for low cost CZ silicon substrates. This<br />

research work is reported below.<br />

4.3.1.1 Rear Emitter PERT Cell Structure on N-type Silicon Substrates<br />

In 2004, a new rear-boron-emitter PERT (passivated emitter, rear totally-diffused) cell<br />

structure on n-type silicon substrates was developed by the high effi ciency cell group in the<br />

Centre. During the initial experiments, these devices demonstrated high cell effi ciencies<br />

close to 22%, and very stable cell performance under one-sun illumination and after long<br />

term storage in nitrogen. Figure 4.3.1.1 shows the structure <strong>of</strong> these n-type rear emitter<br />

PERT (re-PERT) cells.<br />

finger<br />

“inverted” pyramids<br />

Figure 4.3.1.1<br />

Rear boron emitter PERT cell<br />

structure on n-type silicon<br />

substrates<br />

double layer<br />

antireflection<br />

coating<br />

n-silicon<br />

rear contact<br />

oxide<br />

High effi ciency processing methods, similar to those used for PERL (passivated emitter, rear<br />

locally-diffused) cells, are used for processing these n-type re-PERT cells. These processing<br />

methods include lithographically defi ned regular inverted pyramids surface for excellent light<br />

trapping, TCA thermal oxide growth and aluminium anneal for high quality surface passivation,<br />

boron tribromide liquid source boron diffusion producing very low surface damage, lift-<strong>of</strong>f metal<br />

scheme combined with electro-chemical silver plating for minimum contact recombination<br />

and very little metal shading and resistance loss, and double layer antirefl ection coatings to<br />

further minimise the surface refl ection loss.<br />

25

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