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Simple Nature - Light and Matter

Simple Nature - Light and Matter

Simple Nature - Light and Matter

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a dipole moment — they are defined as having the same dipolemoment as the two-charge dipole that would experience the sametorque.)Employing a little more mathematical elegance, we can define adipole moment vector,D = ∑ q i r i ,where r i is the position vector of the charge labeled by the indexi. We can then write the torque in terms of a vector cross product(page 281),τ = D × E .No matter how we notate it, the definition of the dipole momentrequires that we choose point from which we measure all the positionvectors of the charges. However, in the commonly encounteredspecial case where the total charge of the object is zero, the dipolemoment is the same regardless of this choice.Dipole moment of a molecule of NaCl gas example 4⊲ In a molecule of NaCl gas, the center-to-center distance betweenthe two atoms is about 0.6 nm. Assuming that the chlorinecompletely steals one of the sodium’s electrons, compute themagnitude of this molecule’s dipole moment.⊲ The total charge is zero, so it doesn’t matter where we choosethe origin of our coordinate system. For convenience, let’s chooseit to be at one of the atoms, so that the charge on that atomdoesn’t contribute to the dipole moment. The magnitude of thedipole moment is thenD = (6 × 10 −10 m)(e)= (6 × 10 −10 m)(1.6 × 10 −19 C)= 1 × 10 −28 C · mDipole moments as vectors example 5⊲ The horizontal <strong>and</strong> vertical spacing between the charges in thefigure is b. Find the dipole moment.⊲ Let the origin of the coordinate system be at the leftmost charge.n / Example 5.D = ∑ q i r i= (q)(0) + (−q)(bˆx) + (q)(bˆx + bŷ) + (−q)(2bˆx)= −2bqˆx + bqŷ566 Chapter 10 Fields

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