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Basic Research Needs for Geosciences - Energetics Meetings and ...

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PRIORITY RESEARCH DIRECTION: TRANSPORT PROPERTIES AND IN SITU CHARACTERIZATIONOF FLUID TRAPPING, ISOLATION, AND IMMOBILIZATIONto our ability to successfully engineer a manmade repository <strong>for</strong> energy waste. We currently havelimited underst<strong>and</strong>ing of how trapping mechanisms operate under in situ conditions. Our abilityto detect <strong>and</strong> characterize the dominant mechanisms within a given reservoir at depth is similarlylimited.Interfacial <strong>and</strong> surface properties of fluids in fine-grained <strong>and</strong> fractured mediaInterfacial tension between fluid phases <strong>and</strong> surface tension between fluid <strong>and</strong> solid are thefundamental <strong>for</strong>ces that control the flow of multiphase fluids through porous media. As pore sizedecreases, the radius of curvature of fluid interfaces decreases, causing interfacial <strong>for</strong>ces to riseto levels that are a significant fraction (ranging from > 10% to several times) of the gravitational<strong>for</strong>ces that drive fluid flow. When the surface <strong>for</strong>ces are greater than the gravitational <strong>for</strong>ces,fluids can be trapped in porous media.Interfacial <strong>and</strong> surface tension of multicomponent fluids is rarely measured, <strong>and</strong> is one of thepoorly predicted physical parameters in currently available simulators of thermochemical <strong>and</strong>physical properties of fluid mixtures <strong>and</strong> fluid-rock properties. In addition, interfacial processesare dramatically impacted by abiotic <strong>and</strong> biologically mediated chemical reactions. Also, thekinetics of many mineral-fluid <strong>and</strong> fluid-fluid reactions are slow, making examination of theirimpacts on interfacial properties exceedingly difficult.Conductivity of faults <strong>and</strong> fracturesIt is critically important to be able to predict whether faults or other local crosscuttingheterogeneities (e.g., clastic dikes, etc.) conduct or retain fluids as a function of fluid pressure,phase state, <strong>and</strong> chemical composition. Furthermore we need to be able to predict the impacts ofanthropogenic perturbations on the conductivity of these structures to buoyant fluids (see Figure43). Presently available wellbore-based characterization tools are either poorly suited orcompletely inadequate <strong>for</strong> characterizing these effects. Fault gouge properties <strong>and</strong> complex 3Dfracture networks in natural systems are very difficult, or even impossible, to reproduce in alaboratory setting, making field measurements a critical but expensive <strong>and</strong> time-consumingaspect of this research. Finally, the typically slow rate of fluid migration in these structuresmakes conducting measurements in a timely manner challenging, even under favorableconditions.In situ measurement of fluid-rock interactions in fine-grained mediaLow-permeability media (barriers to flow) are elements that define the pathways of fluidmigration at the basin scale in many subsurface settings. Fine-grained rocks, low permeabilitysalt or anhydrite, <strong>and</strong> faults with gouge are examples of barriers. These featurescompartmentalize pressure, trap buoyant fluids, <strong>and</strong> isolate compositionally different fluids. Theper<strong>for</strong>mance of these barriers in the presence of multicomponent fluids is complex, because theactive sealing mechanism varies with fluid composition <strong>and</strong> pressure, <strong>and</strong> geochemical <strong>and</strong> stresschanges can alter the properties of the seal.<strong>Basic</strong> <strong>Research</strong> <strong>Needs</strong> <strong>for</strong> <strong>Geosciences</strong>: Facilitating 21 st Century Energy Systems 133

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