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Aspen Physical Property System - Physical Property Models

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2 Thermodynamic <strong>Property</strong><br />

<strong>Models</strong><br />

This section describes the available thermodynamic property models in the<br />

<strong>Aspen</strong> <strong>Physical</strong> <strong>Property</strong> <strong>System</strong>. The following table provides a list of<br />

available models, with corresponding <strong>Aspen</strong> <strong>Physical</strong> <strong>Property</strong> <strong>System</strong> model<br />

names. The table provides phase types for which the model can be used and<br />

information on use of the model for pure components and mixtures.<br />

<strong>Aspen</strong> <strong>Physical</strong> <strong>Property</strong> <strong>System</strong> thermodynamic property models include<br />

classical thermodynamic property models, such as activity coefficient models<br />

and equations of state, as well as solids and electrolyte models. The models<br />

are grouped according to the type of property they describe.<br />

Thermodynamic <strong>Property</strong> <strong>Models</strong><br />

Phases: V = Vapor; L = Liquid; S = Solid. An X indicates applicable to Pure or<br />

Mixture.<br />

Equation-of-State <strong>Models</strong><br />

A pure component equation of state model calculates PHIL, PHIV, DHL, DHV,<br />

DGL, DGV, DSL, DSV, VL, and VV. Most mixture equation of state models<br />

calculate PHILMX, PHIVMX, DHLMX, DHVMX, DGLMX, DGVMX, DSLMX,<br />

DSVMX, VLMX, and VVMX. Those marked with * only calculate DHLMX,<br />

DHVMX, DGLMX, DGVMX, DSLMX, DSVMX, VLMX, and VVMX. The alpha<br />

functions and mixing rules are options available in some of the models.<br />

<strong>Property</strong> Model Model Name(s) Phase(s)Pure Mixture<br />

ASME Steam Tables ESH2O0,ESH2O V L X —<br />

BWR-Lee-Starling ESBWR0, ESCSTBWR V L X X<br />

Benedict-Webb-Rubin-Starling ESBWRS, ESBWRS0 V L X X<br />

Hayden-O'Connell ESHOC0,ESHOC V X X<br />

HF equation-of-state ESHF0, ESHF V X X<br />

Ideal Gas ESIG0, ESIG V X X<br />

Lee-Kesler * ESLK V L — X<br />

Lee-Kesler-Plöcker ESLKP0,ESLKP V L X X<br />

NBS/NRC Steam Tables ESSTEAM0,ESSTEAM V L X —<br />

2 Thermodynamic <strong>Property</strong> <strong>Models</strong> 11

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