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Aspen Physical Property System - Physical Property Models

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fcn = A correlation based on API Procedures and Figures 11A4.2, 11A4.3,<br />

and 11A4.4 (API Technical Data Book, Petroleum Refining, 1997<br />

edition)<br />

Vm l is obtained from the API liquid volume model.<br />

For real components, the General model is used.<br />

Parameter<br />

Name/Element<br />

252 3 Transport <strong>Property</strong> <strong>Models</strong><br />

Symbol Default MDS Lower<br />

Limit<br />

Upper<br />

Limit<br />

Units<br />

TB T bi — — 4.0 2000.0 TEMPERATURE<br />

API API i — — -60.0 500.0 —<br />

<strong>Aspen</strong> Liquid Mixture Viscosity<br />

The liquid mixture viscosity is calculated by the equation:<br />

Where:<br />

Xi = Mole fraction or weight fraction of component i<br />

kij = Symmetric binary parameter (kij = kji)<br />

lij = Antisymmetric binary parameter (lij = -lji)<br />

The pure component liquid viscosity �i *,l is calculated by the General Pure<br />

Component Liquid Viscosity model.<br />

The binary parameters kij and lij allow accurate representation of complex<br />

liquid mixture viscosity. Both binary parameters default to zero.<br />

Parameter Symbol Default MDS Lower Upper Units<br />

Name/Element<br />

Limit Limit<br />

MUKIJ k ij 0 — -100.0 100.0 —<br />

MULIJ l ij 0 — 100.0 100.0 —<br />

ASTM Liquid Mixture Viscosity<br />

It is generally difficult to predict the viscosity of a mixture of viscous<br />

components. For hydrocarbons, the following weighting method (ASTM †) is<br />

known to give satisfactory results:<br />

Where:<br />

wi = Weight fraction of component i<br />

�m = Absolute viscosity of the mixture (N-sec/sqm)

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