25.12.2012 Views

Aspen Physical Property System - Physical Property Models

Aspen Physical Property System - Physical Property Models

Aspen Physical Property System - Physical Property Models

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

Jones-Dole Electrolyte Correction<br />

The Jones-Dole model calculates the correction to the liquid mixture viscosity<br />

of a solvent mixture, due to the presence of electrolytes:<br />

Where:<br />

�solv = Viscosity of the liquid solvent mixture, by default<br />

calculated by the Andrade model<br />

��ca l = Contribution to the viscosity correction due to<br />

apparent electrolyte ca<br />

The parameter �solv can be calculated by different models depending on<br />

option code 3 for MUL2JONS:<br />

Option Code Solvent liquid mixture viscosity<br />

Value<br />

model<br />

0<br />

Andrade liquid mixture viscosity<br />

model (default)<br />

1 Viscosity quadratic mixing rule<br />

2 <strong>Aspen</strong> liquid mixture viscosity<br />

model<br />

The parameter ��ca l can be calculated by three different equations.<br />

If these parameters are available Use this equation<br />

IONMOB and IONMUB Jones-Dole †<br />

IONMUB Breslau-Miller<br />

— Carbonell<br />

† When the concentration of apparent electrolyte exceeds 0.1 M, the Breslau-<br />

Miller equation is used instead.<br />

Jones-Dole<br />

The Jones-Dole equation is:<br />

Where:<br />

xca a<br />

3 Transport <strong>Property</strong> <strong>Models</strong> 263<br />

(1)<br />

= Concentration of apparent electrolyte ca (2)<br />

= Mole fraction of apparent electrolyte ca (3)<br />

Aca = (4)<br />

La = (5)

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!