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Aspen Physical Property System - Physical Property Models

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Where:<br />

The parameter is the mole fraction vector; fcn is a corresponding states<br />

correlation based on the model for vapor and liquid viscosity TRAPP, by the<br />

National Bureau of Standards (NBS, currently NIST) . The model can be used<br />

for both pure components and mixtures. The model should be used for<br />

nonpolar components only.<br />

Parameter<br />

Name/Element<br />

3 Transport <strong>Property</strong> <strong>Models</strong> 267<br />

Symbol Default MDS Lower<br />

Limit<br />

Upper<br />

Limit<br />

MW M i — — 1.0 5000.0 —<br />

Units<br />

TCTRAP T ci TC x 5.0 2000.0 TEMPERATURE<br />

PCTRAP p ci PC x 10 5<br />

10 8<br />

PRESSURE<br />

VCTRAP V ci VC x 0.001 3.5 MOLE-VOLUME<br />

ZCTRAP Z ci ZC x 0.1 1.0 —<br />

OMGRAP � i<br />

References<br />

OMEGA x -0.5 3.0 —<br />

J.F. Ely and H.J.M. Hanley, "Prediction of Transport Properties. 1. Viscosities<br />

of Fluids and Mixtures," Ind. Eng. Chem. Fundam., Vol. 20, (1981), pp. 323–<br />

332.<br />

Twu Liquid Viscosity<br />

The Twu liquid viscosity model is based upon the work of C.H. Twu (1985).<br />

The correlation uses n-alkanes as a reference fluid and is capable of<br />

predicting liquid viscosity for petroleum fractions with normal boiling points up<br />

to 1340 F and API gravity up to -30.<br />

Given the normal boiling point Tb and the specific gravity SG of the system to<br />

be modeled, the Twu model estimates the viscosity of the n-alkane reference<br />

fluid of the same normal boiling point at 100 F and 210 F, and its specific<br />

gravity. These are used to estimates the viscosity of the system to be<br />

modeled at 100 F and at 210 F, and these viscosities are used to estimate the<br />

viscosity at the temperature of interest.

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