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Aspen Physical Property System - Physical Property Models

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Parameter<br />

Name/Element<br />

3 Transport <strong>Property</strong> <strong>Models</strong> 281<br />

Symbol Default MDS Lower<br />

Limit<br />

Upper<br />

Limit<br />

MW M i — — 1.0 5000.0 —<br />

Units<br />

TCTRAP T ci TC x 5.0 2000.0 TEMPERATURE<br />

PCTRAP p ci PC x 10 5<br />

10 8<br />

PRESSURE<br />

VCTRAP V ci VC x 0.001 3.5 MOLE-VOLUME<br />

ZCTRAP Z ci ZC x 0.1 1.0 —<br />

OMGRAP � i<br />

References<br />

OMEGA x -0.5 3.0 —<br />

J.F. Ely and H.J. M. Hanley, "Prediction of Transport Properties. 2. Thermal<br />

Conductivity of Pure Fluids and Mixtures," Ind. Eng. Chem. Fundam., Vol. 22,<br />

(1983), pp. 90–97.<br />

Wassiljewa-Mason-Saxena Mixing Rule<br />

The vapor mixture thermal conductivity at low pressures is calculated from<br />

the pure component values, using the Wassiljewa-Mason-Saxena equation:<br />

Where:<br />

�i *,v = Calculated by the General Pure Component Vapor<br />

Thermal Conductivity model<br />

�i *,v (p = 0) = Obtained from the General Pure Component Vapor<br />

Viscosity model<br />

You must supply parameters for �i *,v (p = 0) and �i *,v .<br />

Parameter<br />

Name/Element<br />

Symbol Default MDS Lower<br />

Limit<br />

Upper<br />

Limit<br />

MW M i — — 1.0 5000.0 —<br />

References<br />

Units<br />

R.C. Reid, J.M. Prausnitz, and B.E. Poling, The Properties of Gases and<br />

Liquids, 4th ed., (New York: McGraw-Hill, 1987), pp. 530–531.<br />

Diffusivity <strong>Models</strong><br />

The <strong>Aspen</strong> <strong>Physical</strong> <strong>Property</strong> <strong>System</strong> has seven built-in diffusivity models. This<br />

section describes the diffusivity models available.

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